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Zr-702鋯板TIG焊接接頭硫酸環(huán)境腐蝕性能研究
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1.西安理工大學(xué) 材料科學(xué)與工程學(xué)院;2.西安交通大學(xué) 材料科學(xué)與工程學(xué)院;3.西安優(yōu)耐特容器制造有限公司

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國家自然科學(xué)基金(51974243),西安市科技計劃項目(先進制造業(yè)技術(shù)攻關(guān)項目21XJZZ0057)


Study on Corrosion Behavior of Zr-702 zirconium plate TIG welded joint in sulfuric acid environment
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Xi’an United Pressure Vessel CO., Ltd.

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    摘要:

    采用99.999%高純Ar作為保護氣體進行Zr-702鋯板的TIG焊接實驗,采用靜態(tài)等溫失重法,研究了Zr-702焊接接頭在250 ℃,15%(ω)硫酸介質(zhì)中浸泡時長對其腐蝕性能的影響,探究其腐蝕機理。研究結(jié)果表明:在相同溫度與濃度,不同浸泡時長的硫酸介質(zhì)中,焊接接頭的腐蝕速率均大于母材的腐蝕速率,當浸泡時長為2天時,焊接接頭與母材均具有良好的耐腐蝕性能;當浸泡時長大幅增加至180天時,焊接接頭與母材腐蝕速率均有明顯升高,浸泡時長對焊接接頭與母材的腐蝕速率影響較大;通過對浸泡時長為180天的試樣進行成分組織性能表征分析可知,焊接接頭焊縫區(qū)和熱影響區(qū)均析出大量氫化鋯,母材或母材區(qū)氫化鋯數(shù)量相對較少;Zr-702的母材在硫酸介質(zhì)中的腐蝕為均勻腐蝕和氫腐蝕共同作用,焊接接頭因各區(qū)存在明顯組織梯度而存在電位差,故其腐蝕為電偶腐蝕和氫脆聯(lián)合作用的局部腐蝕。

    Abstract:

    TIG welding experiment of Zr-702 zirconium plate was carried out with 99.999% high purity Ar as shielding gas. The Zr-702 welding joint was studied at 250%, 15%(ω) by static isothermal weight loss method. Influences of soaking time in sulphuric acid medium on its corrosion performance and explore its corrosion mechanism. The results show that the corrosion rate of welded joint is higher than that of base metal in the same temperature and concentration and different soaking time in sulfuric acid medium. When soaking time is 2 days, both welded joint and base metal have good corrosion resistance. The corrosion rate of welded joint and base metal increases significantly when the soaking time increases to 180 days, and the corrosion rate of welded joint and base metal is greatly affected by the soaking time. According to the characterization and analysis of composition, structure and properties of 180-day soaked samples, a large amount of zirconium hydride was precipitated in weld zone and heat-affected zone of weld joint, and the amount of zirconium hydride in base metal or base metal zone was relatively small. The corrosion of Zr-702 base metal in sulphuric acid medium is the combination of uniform corrosion and hydrogen corrosion. Potential difference exists in weld joint due to obvious structural gradient in each zone. Therefore, its corrosion is the local corrosion combined by galvanic corrosion and hydrogen brittleness.

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李寧,張敏,牛靖,葉建林. Zr-702鋯板TIG焊接接頭硫酸環(huán)境腐蝕性能研究[J].稀有金屬材料與工程,2022,51(12):4618~4623.[lining, zhangmin, niujing, yejianlin. Study on Corrosion Behavior of Zr-702 zirconium plate TIG welded joint in sulfuric acid environment[J]. Rare Metal Materials and Engineering,2022,51(12):4618~4623.]
DOI:10.12442/j. issn.1002-185X.20220415

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  • 收稿日期:2022-05-11
  • 最后修改日期:2022-09-29
  • 錄用日期:2022-10-08
  • 在線發(fā)布日期: 2023-01-19
  • 出版日期: 2022-12-30