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外加壓應(yīng)力對Ti-35421合金鈍化膜損傷修復(fù)影響的原位電化學(xué)研究
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南京工業(yè)大學(xué)材料科學(xué)與工程學(xué)院/新材料研究院

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國家自然科學(xué)基金重點項目(51931008),深海技術(shù)科學(xué)太湖實驗室課題,江蘇省重點研發(fā)計劃(BE2019119)


Effects of compressive stresses on the breakdown and self-healing of the surface passivation films on Ti-35421 alloy by in-situ electrochemical monitoring
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College of Materials Science and Engineering/Tech Institute for Advanced Materials, Nanjing Tech University, Nanjing

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    摘要:

    以Ti-35421(Ti-3Al-5Mo-4Cr-2Zr-1Fe)合金為研究對象,采用自制的鈍化膜損傷修復(fù)原位電化學(xué)測試裝置研究了模擬深海靜水壓力對Ti-35421合金鈍化膜破裂損傷和自修復(fù)的原位電化學(xué)行為。Ti-35421合金在3.5% NaCl溶液中的鈍化平臺為-0.27~0.01 V。在-0.13 V鈍化電壓條件下極化并進行劃痕實驗,無壓應(yīng)力作用時破損鈍化膜發(fā)生快速修復(fù)。壓應(yīng)力增大導(dǎo)致原子間結(jié)合力降低,金屬溶解速度增加,再鈍化減緩,在原位電化學(xué)上表現(xiàn)為電壓下降、電流上升,電壓、電流回復(fù)時間增長,自修復(fù)能力減弱。再鈍化過程中的暫態(tài)階段鈍化膜生長符合線性高場模型。觀察劃痕形貌發(fā)現(xiàn)壓應(yīng)力下劃痕槽中出現(xiàn)微裂紋,說明較高壓應(yīng)力損傷作用下在劃痕槽近表面產(chǎn)生應(yīng)力集中,對合金產(chǎn)生的傷害部分不可修復(fù)。鈍化膜破損加劇和自修復(fù)能力減弱是殘余應(yīng)力與環(huán)境腐蝕共同作用的結(jié)果。

    Abstract:

    The effects of compressive stresses on the breakdown and self-healing of the surface passivation films on Ti-35421 (Ti-3Al-5Mo-4Cr-2Zr-1Fe) alloy after damaging by the Al2O3 ceramic needles have been investigated on a self-made scratching tester by using the in-situ electrochemical monitoring. The passivation potential of Ti-35421 alloy in 3.5% NaCl solution is determined to be -0.27~0.01 V. Without the compressive stress, the potential recovers to the initial leverl shortly. When the scratching experiments carry out under the passivation polarization of -0.13 V, the increase of compressive stress leads to the decrease of the atomic binding forces, the increase of metallic dissolution rates, and the slow down of repassivation rates. In-situ electrochemical data show that the potential drops and the currents rise, and the self-healing duration times become longer. The growth and sel-healing of the passive films in the transient stage basically conform to the linear high-field model. Observation of scratch morphology shows that the scratching generates the higher residual stresses at the bottom of the grooves. It is found that microcracks appear in the scratch grooves under the compressive stresses basing on the scratch morphology, indicating that the damages of the scratches under high compressive stresses are partialy unrecoverable, which results from the synergetic effects of the residual stresses and environmental corrosion.

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李嘉偉,渠佳慧,淡振華,常輝,周廉.外加壓應(yīng)力對Ti-35421合金鈍化膜損傷修復(fù)影響的原位電化學(xué)研究[J].稀有金屬材料與工程,2023,52(4):1419~1425.[Li Jiawei, Qu Jiahui, Dan Zhenhua, Chang Hui, Zhou Lian. Effects of compressive stresses on the breakdown and self-healing of the surface passivation films on Ti-35421 alloy by in-situ electrochemical monitoring[J]. Rare Metal Materials and Engineering,2023,52(4):1419~1425.]
DOI:10.12442/j. issn.1002-185X.20220286

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  • 收稿日期:2022-04-07
  • 最后修改日期:2022-06-23
  • 錄用日期:2022-07-12
  • 在線發(fā)布日期: 2023-05-01
  • 出版日期: 2023-04-25