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超音速激光沉積制備7075/Al2O3復(fù)合涂層的顯微組織及性能研究
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1.西安建筑科技大學(xué)冶金工程學(xué)院;2.空軍工程大學(xué)航空等離子體動力學(xué)國家級重點實驗室

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綜合研究科學(xué)研究基金(KJ20211A03××)


Microstructure and Properties of 7075/Al2O3 Composite Coatings Prepared by Supersonic Laser Deposition
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1.School of Metallurgical Engineering, Xi ''an University of Architecture and Technology;2.Science and Technology on Plasma Dynamics Laboratory, Air Force Engineering University

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    摘要:

    超音速激光沉積是將超音速冷噴涂和激光輻照加熱有機結(jié)合的一種新型復(fù)合材料表面處理技術(shù),具有可制備硬質(zhì)金屬復(fù)合涂層、沉積效率高等優(yōu)點。本文利用超音速激光沉積技術(shù)在7B04鋁合金基體上制備硬質(zhì)鋁合金7075與陶瓷顆粒Al2O3的復(fù)合涂層,系統(tǒng)研究激光功率對涂層的沉積特性和力學(xué)性能的影響規(guī)律。采用場發(fā)射電子顯微鏡(SEM)、能譜分析儀(EDS)、X射線衍射儀(XRD)和顯微硬度計等儀器,對涂層的顯微組織、相成分和顯微硬度進行表征分析,結(jié)果表明:隨著激光功率的增加,涂層的厚度、致密度、沉積效率、硬度以及涂層中Al2O3顆粒的分散性和相對沉積效率逐漸增加。當(dāng)激光功率為600W時,涂層的沉積厚度達(dá)1543μm,孔隙率為0.05%,涂層中Al2O3粉末顆粒的相對沉積效率達(dá)到峰值65%,硬度達(dá)到195HV。當(dāng)激光功率提升至900W時,涂層的厚度、沉積效率增速放緩,孔隙率顯著增加,涂層發(fā)生氧化相變,Al2O3粉末的相對沉積效率和涂層的硬度下降明顯。因而,適當(dāng)激光輻照的引入有利于提高鋁合金顆粒在沉積過程中的塑性變形能力,顯著改善涂層的質(zhì)量。然而,當(dāng)激光功率過高時,鋁合金顆粒的軟化現(xiàn)象加劇,且易發(fā)生氧化相變,導(dǎo)致涂層的質(zhì)量下降。

    Abstract:

    Supersonic laser deposition is an innovative surface treatment technology, which combines supersonic cold spray technology and laser irradiation heating technology. It has the advantages of preparing hard metal composite coating with high deposition efficiency. In this paper, composite coatings of hard 7075 Al alloy and Al2O3 ceramic particles were prepared on 7B04 Al alloy substrate by supersonic laser deposition technology. The effect of laser power on the deposition characteristics and mechanical properties of coatings was systematically studied. The microstructure, phase composition and microhardness of the coating were characterized and analyzed by field emission electron microscope (SEM), energy dispersive analyzer (EDS), X-ray diffractometer (XRD) and microhardness tester. The results showed that with the increase of laser power, the thickness, density, deposition efficiency, and the dispersion uniformity & deposited amount of Al2O3 particles in the coating were increased. When the laser power was 600W, the coating thickness reaches to 1543μm, the coating porosity is only 0.05%, the relative deposition efficiency of Al2O3 particles is 65%, and the coating hardness rises to 195HV. However, when the laser power was enhanced to 900W, the thickness and deposition efficiency of the coating slowed down, and the porosity increased significantly. The oxidation of coating materials was found, and the relative deposition efficiency of Al2O3 particles and the coating hardness decreased significantly. In summary, the appropriate amount of laser input is beneficial to improve the plastic deformation of aluminum alloy particles, resulting in significant enhancement of coating quality, while the excessive laser input leads to softening of aluminum alloy particles and even oxidation of powder materials, which deteriorate the quality of deposited coatings.

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王強,李楠,周留成,牛文娟,胡寧.超音速激光沉積制備7075/Al2O3復(fù)合涂層的顯微組織及性能研究[J].稀有金屬材料與工程,2023,52(4):1403~1409.[wangqiang, Li Nan, Zhou Liu Cheng, Niu Wenjuan, Hu Ning. Microstructure and Properties of 7075/Al2O3 Composite Coatings Prepared by Supersonic Laser Deposition[J]. Rare Metal Materials and Engineering,2023,52(4):1403~1409.]
DOI:10.12442/j. issn.1002-185X.20220283

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  • 收稿日期:2022-04-07
  • 最后修改日期:2022-08-26
  • 錄用日期:2022-09-14
  • 在線發(fā)布日期: 2023-05-01
  • 出版日期: 2023-04-25