2相,尺寸在10~100 nm范圍內(nèi),隨Cr含量增加,第二相的數(shù)量增加,但尺寸無明顯變化。添加適量的Cr能促進氧化膜中柱狀晶的生長并延緩柱狀晶向等軸晶的轉(zhuǎn)變,從而改善Zr-0.3Nb合金的耐腐蝕性能。當Zr-0.3Nb合金中添加0.5 wt.%的Cr時,耐腐蝕性能較好,這可能是因為Zr-0.3Nb-0.5Cr合金的氧化膜較為致密,且在氧化膜/基體界面處存在亞氧化層,可以延緩氧化膜的顯微組織演化,提高合金的耐腐蝕性能。"/>

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Cr對Zr-0.3Nb合金顯微組織及在400 ℃/10.3 MPa過熱蒸汽中腐蝕行為的影響
作者:
作者單位:

1.上海大學(xué)材料研究所;2.上海大學(xué)微結(jié)構(gòu)重點實驗室

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國家自然科學(xué)基金資助(項目號No. 52001192和51901123)


Effect of Cr on microstructure and corrosion behavior of Zr-0.3Nb alloy in 400 ℃/10.3 MPa superheated steam
Author:
Affiliation:

1.Institute of Materials,Shanghai University,Shanghai;2.Laboratory for Microstructures,Shanghai University,Shanghai

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    摘要:

    通過制備Zr-0.3Nb-xCr(x=0.2, 0.5, 1.0 wt.%)合金,并在高壓釜中進行400 ℃/10.3 MPa過熱蒸汽腐蝕實驗,利用SEM和TEM表征和分析合金基體及氧化膜截面顯微組織,研究了Cr對Zr-0.3Nb合金顯微組織及在400 ℃/10.3 MPa過熱蒸汽中腐蝕行為的影響。結(jié)果表明,Zr-0.3Nb-xCr合金中的第二相主要為面心立方和密排六方的ZrCr2相,尺寸在10~100 nm范圍內(nèi),隨Cr含量增加,第二相的數(shù)量增加,但尺寸無明顯變化。添加適量的Cr能促進氧化膜中柱狀晶的生長并延緩柱狀晶向等軸晶的轉(zhuǎn)變,從而改善Zr-0.3Nb合金的耐腐蝕性能。當Zr-0.3Nb合金中添加0.5 wt.%的Cr時,耐腐蝕性能較好,這可能是因為Zr-0.3Nb-0.5Cr合金的氧化膜較為致密,且在氧化膜/基體界面處存在亞氧化層,可以延緩氧化膜的顯微組織演化,提高合金的耐腐蝕性能。

    Abstract:

    Zr-0.3Nb-xCr (x=0.2, 0.5, 1.0 wt.%) alloys were prepared and corroded in 400 ℃/10.3 MPa superheated steam in an autoclave, and the microstructures of the alloy matrix and oxide film were characterized using SEM and TEM, in order to investigate the effect of Cr on the microstructure and corrosion behavior of Zr-0.3Nb alloy. It was found that the second phase particles in the Zr-0.3Nb-xCr alloys were face centered cubic and hexagonal close-packed ZrCr2 phase with a size in a range of 10~100 nm. By increasing the Cr content, the size of second phase particles was nearly unchanged, but their number was increased. Appropriate Cr addition to the Zr-0.3Nb alloy could promote the growth of columnar crystals in the oxide film and delay the transformation from columnar crystals to equiaxed crystals, thereby improving the corrosion resistance of the Zr-0.3Nb alloy. The corrosion resistance was relatively better when 0.5 wt.% Cr was added to the Zr-0.3Nb alloy. This may be due to the compact oxide film and the presence of a sub-oxide layer at the oxide/metal interface, which could delay the microstructure evolution of the oxide film and thus improve the corrosion resistance of the Zr-0.3Nb-0.5Cr alloy.

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張弛,范周洋,林曉冬,彭麗婷,梁雪,李毅豐,陳文霞,彭劍超,李強. Cr對Zr-0.3Nb合金顯微組織及在400 ℃/10.3 MPa過熱蒸汽中腐蝕行為的影響[J].稀有金屬材料與工程,2023,52(5):1915~1924.[ZHANG Chi, FAN Zhouyang, Lin Xiaodong, Peng Liting, Liang Xue, Li Yifeng, Chen Wenxia, Peng Jianchao, Li Qiang. Effect of Cr on microstructure and corrosion behavior of Zr-0.3Nb alloy in 400 ℃/10.3 MPa superheated steam[J]. Rare Metal Materials and Engineering,2023,52(5):1915~1924.]
DOI:10.12442/j. issn.1002-185X.20220281

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  • 收稿日期:2022-04-07
  • 最后修改日期:2022-07-03
  • 錄用日期:2022-07-12
  • 在線發(fā)布日期: 2023-06-08
  • 出版日期: 2023-05-29