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深冷處理對(duì)冷軋銅合金組織與性能的影響
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1.南昌工程學(xué)院;2.中冶長(zhǎng)天國(guó)際工程有限責(zé)任公司;3.江西省科學(xué)院;4.中南大學(xué)

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TG156.93

基金項(xiàng)目:

國(guó)家自然科學(xué)基金(51861025);江西省自然科學(xué)基金(20202ACBL20087,20192BAB206001)


Influence of a deep cryogenic treatment on the microstructure and properties of a cold rolled Cu-based alloy
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    摘要:

    采用掃描電子顯微鏡、透射電子顯微鏡、X射線衍射儀、萬(wàn)能試驗(yàn)機(jī)及電阻率測(cè)試儀等研究了深冷處理對(duì)冷軋Cu-1.34Ni-1.02Co-0.61Si合金組織和性能的影響。深冷處理使30 %壓下率冷軋合金顯微組織細(xì)化和均勻化,并且隨著深冷處理時(shí)間增加,細(xì)化和均勻化程度不斷提高。深冷處理促使固溶Ni、Co和Si等原子不斷從銅基體中析出,在合金晶粒內(nèi)和晶界處形成尺寸為0.1?m~1?m之間的細(xì)小彌散球形和長(zhǎng)條形第二相顆粒。冷軋前后合金的抗拉強(qiáng)度、電導(dǎo)率和延伸率均隨著深冷處理時(shí)間延長(zhǎng)而增加,并在約36 h后趨于穩(wěn)定。深冷處理48 h后,冷軋前后合金的抗拉強(qiáng)度、電導(dǎo)率和延伸率分別增加了5.4 %和4.4 %、6.7 %和8.0 %、及13.2 %和18.7 %。冷軋后合金的抗拉強(qiáng)度高于冷軋前;而冷軋后的電導(dǎo)率和延伸率低于冷軋前,但差距均隨著深冷處理時(shí)間增加而縮小。經(jīng)深冷處理合金拉伸斷口的韌窩數(shù)量和深度比未經(jīng)深冷處理合金大,且分布更加均勻。

    Abstract:

    The influence of deep cryogenic treatments (DCT) on the microstructure and properties of a cold rolled Cu-1.34Ni-1.02Co-0.61Si alloy was investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), an X-ray diffractometer (XRD), a mechanical testing machine and a low resistance tester. The DCT refined and homogenized the microstructure of the alloy after cold rolling at 30 % reduction. The grain refinement of the alloy became more obvious and the microstructure distribution became more uniform with increasing DCT time. The DCT promoted the precipitation of the solid solution elements Ni, Co and Si from the Cu matrix to form many fine and evenly distributed 0.1?m~1?m spherical and strip second phase particles in the grain and grain boundary. The tensile strength, conductivity and elongation of the alloy before and after cold rolling at 30 % reduction increased with increasing DCT time, and tended to be stable at about 36 h. After DCT for 48 h, the tensile strength, conductivity and elongation of the alloy before and after cold rolling increased by 5.4% and 4.4%, 6.7% and 8.0%, 13.2% and 18.7% respectively. The tensile strength of the alloy after cold rolling was higher than that before cold rolling. The conductivity and elongation of the alloy after cold rolling was lower than that before cold rolling. However, the both differences decreased with increasing DCT time. The dimple quantity and depth of the alloy with DCT were larger, and the dimple distribution was more uniform than those without DCT.

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劉克明,盛曉春,李小龍,金瑩,李沐林,沈智,付凱,周海濤.深冷處理對(duì)冷軋銅合金組織與性能的影響[J].稀有金屬材料與工程,2023,52(1):215~221.[Keming Liu, Xiaochun Sheng, Xiaolong Li, Ying JIn, Mulin Li, Zhi Shen, Kai Fu, Haitao Zhou. Influence of a deep cryogenic treatment on the microstructure and properties of a cold rolled Cu-based alloy[J]. Rare Metal Materials and Engineering,2023,52(1):215~221.]
DOI:10.12442/j. issn.1002-185X.20220200

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  • 收稿日期:2022-03-14
  • 最后修改日期:2022-09-09
  • 錄用日期:2022-09-27
  • 在線發(fā)布日期: 2023-02-13
  • 出版日期: 2023-02-08