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鋰離子電池富鎳正極基礎(chǔ)科學(xué)問(wèn)題:關(guān)鍵元素?fù)诫s及其作用機(jī)理
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1.成都理工大學(xué) 材料與化學(xué)化工學(xué)院;2.宜賓鋰寶新材料有限公司

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國(guó)家自然科學(xué)基金青年(21805018)


Basic scientific problems of nickel rich cathode materials for Li-ion battery: key element substitution and its mechanism
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School of Materials,Chemistry and Chemical Engineering,Chengdu University of Technology

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    摘要:

    富鎳層狀氧化物因其相對(duì)較高的比容量成為高能量密度鋰離子電池的首選正極,進(jìn)一步提高Ni含量,材料特性趨向于LiNiO2,電化學(xué)和結(jié)構(gòu)穩(wěn)定性惡化。晶格元素?fù)诫s是提升LiNiO2穩(wěn)定性的有效策略。厘清LiNiO2正極材料結(jié)構(gòu)并明晰摻雜元素對(duì)其影響及規(guī)律,對(duì)開(kāi)發(fā)Ni含量大于90%的富鎳正極材料具有重要意義。本文首先介紹了LiNiO2材料結(jié)構(gòu)及面臨的穩(wěn)定性問(wèn)題。然后綜述了Co、Mn、Al、Mg、Ti、Zr、W等典型摻雜元素對(duì)LiNiO2的影響及規(guī)律,并討論了陰離子和多元素?fù)诫s以及有潛力的摻雜元素。本文旨在對(duì)LiNiO2摻雜提供一個(gè)新的視角,以期使用更有效的摻雜方案開(kāi)發(fā)可用于動(dòng)力電池的高容量穩(wěn)定的富鎳正極材料。

    Abstract:

    Nickel-rich layered oxides have become the preferred cathodes for high-energy-density Li-ion batteries due to their relatively high specific capacity, further increasing the Ni content, the material properties tend to be LiNiO2, and the electrochemical and structural stability deteriorate. Lattice element doping is an effective strategy to improve the stability of LiNiO2. Clarifying the structure of LiNiO2 cathode material and clarifying the influence and regularity of doping elements on it is of great significance for the development of nickel-rich cathode materials with Ni content greater than 90%. In this paper, the structure of LiNiO2 material and the stability problems it faces are firstly introduced. Then, the influences and laws of typical doping elements such as Co, Mn, Al, Mg, Ti, Zr, and W on LiNiO2 are reviewed, and anionic and multi-element doping and potential doping elements are discussed. This paper aims to provide a new perspective on LiNiO2 doping with a view to developing high-capacity stable Ni-rich cathode materials for power batteries using more efficient doping schemes.

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鄧中莉,呂卓赟,范未峰,張燕輝,左美華,向偉.鋰離子電池富鎳正極基礎(chǔ)科學(xué)問(wèn)題:關(guān)鍵元素?fù)诫s及其作用機(jī)理[J].稀有金屬材料與工程,2023,52(3):1143~1154.[Deng Zhongli, Lv Zhuoyun, Fan Weifeng, Zhang Yanhui, Zuo MeiHua, Xiang Wei. Basic scientific problems of nickel rich cathode materials for Li-ion battery: key element substitution and its mechanism[J]. Rare Metal Materials and Engineering,2023,52(3):1143~1154.]
DOI:10.12442/j. issn.1002-185X.20220117

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  • 收稿日期:2022-02-17
  • 最后修改日期:2022-05-04
  • 錄用日期:2022-06-16
  • 在線(xiàn)發(fā)布日期: 2023-04-07
  • 出版日期: 2023-03-24