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預(yù)拉伸形變對Mg-Zn-Sr-Zr-Mn合金降解行為的影響
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華北理工大學(xué)冶金與能源學(xué)院

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河北省自然科學(xué)基金(E2020209153)、河北省省屬高校基本科研業(yè)務(wù)費(fèi)(JYG2019001)、唐山市科學(xué)技術(shù)研究與發(fā)展計(jì)劃(20130205b)、新金屬材料國家重點(diǎn)實(shí)驗(yàn)室開放基金(2020-Z12)


Effect of pre-stretching deformation on degradation of Mg-Zn-Sr-Zr-Mn alloy
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    摘要:

    鎂合金具有優(yōu)異的生物相容性和獨(dú)特降解性,但其在生理環(huán)境中的耐蝕性能較差,嚴(yán)重制約了其在臨床應(yīng)用中的發(fā)展。本文使用預(yù)拉伸工藝制備Mg-Zn-Sr-Zr-Mn新型鎂合金,通過XRD(X-ray Diffraction)、OM(Optical Microscopy)和SEM(Scanning Electron Microscopy)探究預(yù)拉伸形變量與顯微組織、腐蝕速率和膜層形貌間的關(guān)系。結(jié)果表明:隨預(yù)拉伸形變量的增大(2%、4%、6%),合金晶粒尺寸被逐漸拉長,孿晶數(shù)目逐漸增多,析出相離散程度逐漸增大。4%預(yù)拉伸合金由于適量孿晶的出現(xiàn)及析出相離散程度的增大,增加了電偶腐蝕形核點(diǎn)位,加速了合金表面均勻氧化產(chǎn)物的快速產(chǎn)生,增大了合金極化電阻阻值(729.4 Ω·cm-2);三種預(yù)拉伸合金電化學(xué)(0.39→0.25→0.74 mm·y-1)及失重速率(2.85→1.83→5.88 mm·y-1)均呈現(xiàn)先降低后升高的趨勢。4%預(yù)拉伸合金具有較高的耐蝕性證明適當(dāng)?shù)念A(yù)拉伸變形提高界面析出相的連續(xù)性,阻礙腐蝕進(jìn)程,對合金腐蝕性能起到積極作用。而當(dāng)預(yù)拉伸形變量繼續(xù)增加,產(chǎn)生大量位錯,創(chuàng)造氫擴(kuò)散路徑,有利于氫富集,導(dǎo)致合金耐蝕性下降。此外,適當(dāng)?shù)念A(yù)拉伸形變通過改變殘余應(yīng)力的重新分布,提高腐蝕均勻性,同時提高膜層致密性與連續(xù)性,延緩腐蝕進(jìn)程。

    Abstract:

    Magnesium alloys own excellent biocompatibilities and unique degradation characteristics. However, the poor corrosion resistance in physiological environment seriously restricted its development in clinical applications. In this study, Mg-Zn-Sr-Zr-Mn alloys were prepared by pre-tensile process. XRD (X-ray diffraction), OM (optical microscopy) and SEM (scanning electron microscopy) were used to investigate the relationship between the pre-tensile type variables and the microstructure, corrosion rate and film layer morphology. The results showed that with the increase deformation of pre-stretching, the grain sizes were gradually elongated, the numbers of twins were increased, and the dispersion degrees of precipitated phases were gradually increased. The corrosion rate of the three pre-stretching alloys in electrochemical (0.39→0.25 →0.74mm·y-1) and weight-loss (2.85→1.83→5.88mm·y-1) were both decreased firstly and then increased. Therein, the 4% pre-stretching alloy has high corrosion resistance, which indicated that appropriate pre-tensile deformation could improve the continuity of the precipitated phase at the interface, hinder the corrosion process, and play a positive role in the corrosion properties of the alloys. However, when the pre-tensile deformation continues to increase, a large number of dislocations will be generated and hydrogen diffusion path will be created, which was conducive to hydrogen enrichment and leads to the decrease of corrosion resistance. Moreover, appropriate pre-tensile deformation could improve the corrosion uniformity, densification and continuity of the film-layer, and delay the corrosion process by changing the redistribution of residual-stress.

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張?jiān)?鄭瑞寧,田亞強(qiáng),鄭亞琪,趙冠璋,鄭小平,陳連生.預(yù)拉伸形變對Mg-Zn-Sr-Zr-Mn合金降解行為的影響[J].稀有金屬材料與工程,2023,52(3):1045~1054.[ZHANG Yuan, ZHENG Ruining, TIAN Yaqiang, ZHENG Yaqi, ZHAO Guanzhang, ZHENG Xiaoping, CHEN Liansheng. Effect of pre-stretching deformation on degradation of Mg-Zn-Sr-Zr-Mn alloy[J]. Rare Metal Materials and Engineering,2023,52(3):1045~1054.]
DOI:10.12442/j. issn.1002-185X.20220101

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  • 收稿日期:2022-02-09
  • 最后修改日期:2022-03-22
  • 錄用日期:2022-04-25
  • 在線發(fā)布日期: 2023-04-07
  • 出版日期: 2023-03-24