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離子轟擊對(duì)致密T區(qū)結(jié)構(gòu)Cr薄膜殘余應(yīng)力的影響
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大連理工大學(xué)材料科學(xué)與工程學(xué)院表面工程實(shí)驗(yàn)室

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國家重點(diǎn)基礎(chǔ)研究發(fā)展計(jì)劃(2018YFA0704603),國家自然科學(xué)基金(51601029, U21B2078),中央高?;究蒲袠I(yè)務(wù)費(fèi)專項(xiàng)資金(DUT19JC52)


Intrinsic residual stress inducing by the ion bombardment in dense T-zone Cr thin films
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School of Materials Science and Engineering,Dalian University of Technology

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    摘要:

    對(duì)于能量沉積技術(shù),離子轟擊是獨(dú)立于晶粒尺寸之外影響殘余應(yīng)力的重要因素,沉積束流能量和通量是決定殘余應(yīng)力演化的關(guān)鍵參數(shù)。本文分別采用高功率調(diào)制脈沖磁控濺射 (Modulated Pulsed Power magnetron sputtering, MPPMS) 和高功率深振蕩磁控濺射 (Deep Oscillation magnetron sputtering, DOMS) 控制沉積Cr薄膜的束流能量和通量,在相近的平均功率下調(diào)節(jié)微脈沖參數(shù)對(duì)峰值電流和峰值電壓進(jìn)行控制,進(jìn)而實(shí)現(xiàn)離子轟擊對(duì)本征殘余應(yīng)力控制。MPPMS和DOMS沉積的Cr薄膜厚度分別控制在 0.1、0.2、0.5、1.0、1.5 和 3.0 μm,并對(duì)殘余應(yīng)力進(jìn)行對(duì)比研究。所有沉積的Cr薄膜均呈現(xiàn) Cr(110) 擇優(yōu)取向,且形成了晶粒尺寸相當(dāng)?shù)闹旅躎區(qū)結(jié)構(gòu)。較之MPPMS,DOMS沉積Cr薄膜更呈現(xiàn)殘余壓應(yīng)力特征。當(dāng)Cr薄膜小于0.5 μm時(shí),DOMS沉積Cr薄膜的殘余應(yīng)力表現(xiàn)出較高的壓應(yīng)力;進(jìn)一步增加膜厚,殘余應(yīng)力逐漸受殘余拉應(yīng)力控制。在薄膜生長(zhǎng)過程中,離子轟擊在薄膜生長(zhǎng)初期對(duì)殘余應(yīng)力貢獻(xiàn)不大,當(dāng)薄膜生長(zhǎng)較厚時(shí),離子能量對(duì)薄膜殘余應(yīng)力影響明顯。離子能量是影響殘余壓應(yīng)力形成的重要因素,高能量離子轟擊有利于殘余壓應(yīng)力的形成和控制。

    Abstract:

    For energetic deposition, ion bombardment was an important factor independent of grain size for influencing the residual stress, and the energy and flux were critical parameters to determine the residual stress evolution. In this work, Modulated Pulsed Power magnetron sputtering (MPPMS) and Deep Oscillation magnetron sputtering (DOMS) were employed to control the energy and flux to modulate the ion bombardment for intrinsic stress generation under similar average power. The films thickness was selected at 0.1, 0.2, 0.5, 1.0, 1.5 and 3.0 μm to give a comparative study of the intrinsic part of residual stress. All Cr coatings were textured along Cr(110) preferred orientation with dense T-zone columnar microstructure of equivalent grain size. Compared with MPPMS, Cr thin films deposited by DOMS showed a compressive residual stress tendency. When the Cr thin films were under 0.5 μm, Cr thin films deposited by DOMS showed higher compressive residual stress. Further increasing the film thickness, the compressive residual stress first showed a sudden decrease in a sharp slope, and then turn to relative slow decrease and gradually turn to show tensile stress. In the film continuous growing process, the ion bombardment showed limited effect in the early growth stage, but high bombardment effect will directly influence the grain size. At early growth stage, ion bombardment showed limited contribution to residual stress formation. For thick Cr thin films, energy of the bombardment ions relied on residual stress. Ion energy was an important factor influencing the formation of compressive residual stress, and ion bombardment with high energy assisted the generation and control of compressive residual stress.

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李玉閣,趙宜妮,屈亞哲,冷云杉,雷明凱.離子轟擊對(duì)致密T區(qū)結(jié)構(gòu)Cr薄膜殘余應(yīng)力的影響[J].稀有金屬材料與工程,2023,52(2):737~744.[Li Yuge, Zhao Yini, Qu Yazhe, Leng Yunshan, Lei Mingkai. Intrinsic residual stress inducing by the ion bombardment in dense T-zone Cr thin films[J]. Rare Metal Materials and Engineering,2023,52(2):737~744.]
DOI:10.12442/j. issn.1002-185X.20220086

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  • 收稿日期:2022-01-27
  • 最后修改日期:2022-03-21
  • 錄用日期:2022-03-28
  • 在線發(fā)布日期: 2023-03-09
  • 出版日期: 2023-02-28