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一種高Al+Ti鎳基高溫合金在雙相區(qū)和單相區(qū)的熱塑性變形行為
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遼寧科技大學(xué)

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國家自然科學(xué)基金資助(項(xiàng)目號51904146)


Hot deformation behavior of a nickel-base superalloy with high Al and Ti contents in dual-phase and single-phase ranges
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University of Science and Technology Liaoning

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    摘要:

    高Al、Ti含量鎳基變形高溫合金開坯塑性的嚴(yán)重惡化已經(jīng)成為制約其廣泛應(yīng)用的瓶頸。這類合金的熱塑性特征受γ′析出相的顯著影響,但以往關(guān)于γ′對其熱變形行為影響的研究均未考慮晶界強(qiáng)化元素的干擾。本文制備了一種不含C、B、Zr等晶界強(qiáng)化元素的高Al+Ti鎳基變形高溫合金鑄錠并對其進(jìn)行了充分的均勻化處理,重點(diǎn)研究了該合金在1060℃(γ/γ′雙相區(qū))和1170℃(γ單相區(qū))的塑性變形行為。結(jié)果表明,γ單相區(qū)的變形抗力遠(yuǎn)小于γ/γ′雙相區(qū),且γ單相區(qū)的熱塑性明顯更好。有趣的是在γ單相區(qū)的流變曲線上出現(xiàn)了明顯的屈服降現(xiàn)象,而在γ/γ′雙相區(qū)并未出現(xiàn)。這可能由于在γ單相區(qū)有更多Al、Ti被釋放,這些以溶質(zhì)形式存在的Al、Ti能有效阻礙位錯移動并最終將其鎖定。在γ/γ′雙相區(qū)和γ單相區(qū)開裂的模式均為沿晶開裂,說明在熱加工過程中這類合金的晶界是最薄弱環(huán)節(jié)。當(dāng)對數(shù)應(yīng)變達(dá)到0.36時在γ/γ′雙相區(qū)和γ單相區(qū)均已發(fā)生不連續(xù)動態(tài)再結(jié)晶(DDRX),且隨著應(yīng)變的增大DRX晶粒數(shù)量明顯增多,但晶粒尺寸無明顯變化。由于一次γ′對晶界具有釘扎作用,γ單相區(qū)的DRX晶粒尺寸明顯大于γ/γ′雙相區(qū),但前者DRX晶粒的顆粒密度明顯更小。總之,γ單相區(qū)變形抗力明顯更低且熱塑性更好的主要原因是,其DRX晶粒的快速長大會迅速降低原始晶界附近的位錯密度。

    Abstract:

    The severe deterioration of thermal plasticity for nickel-base wrought superalloys with high Al and Ti contents during cogging has become the bottleneck for their wide application, and their thermal plasticity can be significantly affected by the γ′ precipitation. However, previous studies about the role of γ′ on hot deformation behaviors of such alloys did not consider the interference of grain boundary strengthening elements. In this paper, a high Al+Ti nickel-base superalloy ingot without adding grain boundary strengthening elements C, B and Zr was prepared and fully homogenized. Afterwards, the hot deformation behaviors of this as-homogenized ingot at 1060 ℃ (γ/γ′ dual-phase range) and 1170 ℃ (γ single-phase range) were investigated. The results show that, the deformation resistance in γ single-phase range is much lower than that in γ/γ′ dual-phase range, and the plasticity of γ single-phase range is much better. Interestingly, in γ single-phase range a typical yield drop phenomenon appeared, while no such phenomenon appeared in γ/γ′ dual-phase range. This may be because the release of more Al and Ti solutes in γ single-phase range hinders the movement of dynamic dislocations and finally locks them. Both the γ single-phase and γ/γ′ dual-phase ranges showed intergranular cracking, which indicates that initial grain boundaries are the weakest link in hot working process of such alloys. When the logarithmic strain reaches 0.36, discontinuous dynamic recrystallization (DDRX) has occurred in both the γ single-phase and γ/γ′ dual-phase ranges, and with the increase of strain the number of DRX grains increases significantly, but the DRX grain size has no obvious change. Owing to the pinning effect of γ′ to grain boundaries, the DRX grain size in γ single-phase range is much greater than that in the γ/γ′ dual phase range, but the number density of DRX grains in the γ single-phase range is much smaller. The main reason for the lower deformation resistance and better thermal plasticity in the γ single-phase range is that the rapid growth of DRX grains rapidly can reduce the dislocation density near the initial grain boundary.

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趙廣迪,武金江.一種高Al+Ti鎳基高溫合金在雙相區(qū)和單相區(qū)的熱塑性變形行為[J].稀有金屬材料與工程,2023,52(2):630~638.[Zhao Guangdi, Wu Jinjiang. Hot deformation behavior of a nickel-base superalloy with high Al and Ti contents in dual-phase and single-phase ranges[J]. Rare Metal Materials and Engineering,2023,52(2):630~638.]
DOI:10.12442/j. issn.1002-185X.20220048

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  • 收稿日期:2022-01-17
  • 最后修改日期:2022-03-02
  • 錄用日期:2022-03-28
  • 在線發(fā)布日期: 2023-03-09
  • 出版日期: 2023-02-28