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多元稀土硼化物L(fēng)a1-xEuxB6納米粉末的制備及光學(xué)性能研究
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湖南稀土金屬材料研究院有限責(zé)任公司

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湖南省科技創(chuàng)新計(jì)劃項(xiàng)目(2017TP1031)


Fabrication and Optical Properties of Nanocrystalline Multi Rare Earth Hexaborides La1-xEuxB6 powders
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    摘要:

    本研究首次采用鈣熱還原-酸浸法(CTR&AL)成功制備了La1-xEuxB6納米粉末,系統(tǒng)研究了Eu摻雜對(duì)La1-xEuxB6結(jié)構(gòu)、光學(xué)性能的影響規(guī)律及作用機(jī)理。XRD、FE-SEM及TEM分析結(jié)果確認(rèn)納米La1-xEuxB6為CsCl型簡(jiǎn)單立方單相結(jié)構(gòu),結(jié)晶性良好,粉末顆粒具有立方形貌,平均晶粒尺度為40 nm。光吸收結(jié)果表明隨著Eu含量的增加,納米La1-xEuxB6透射光波長(zhǎng)從595 nm增大至825 nm,產(chǎn)生“紅移”現(xiàn)象,且Eu摻雜引起LaB6近紅外區(qū)吸收光譜的增強(qiáng)與展寬。第一性原理計(jì)算結(jié)果揭示了Eu摻雜引起LaB6近費(fèi)米能級(jí)能帶局域性加強(qiáng),導(dǎo)帶中的傳導(dǎo)電子數(shù)量減少,進(jìn)而導(dǎo)致其等離激元共振頻率能量降低,定性解釋了納米La1-xEuxB6透射光波長(zhǎng)連續(xù)可調(diào)諧性。

    Abstract:

    In this study, nanocrystalline La1-xEuxB6 powders were successfully fabricated using a novel calcium thermal reduction and acid leaching technique (CTR&AL) for the first time, and the effect of Eu-doping on the structure and optical properties of La1-xEuxB6 and the mechanism were also systematically investigated. The XRD, FE-SEM and TEM analyses all confirm that the nanocrystalline La1-xEuxB6 exhibits a single-phase CsCl-type cubic structure, good crystallinity and a cubic morphological characterization with an average grain size of 40 nm. The results of optical absorption show that the transmission light wavelength of nanocrystalline La1-xEuxB6 shifts from 595 nm to 825 nm with increasing Eu-doping content, indicating a "red shift" phenomenon of transmission light. And the Eu doping causes the enhancement and broadening of absorption spectrum of LaB6 in the near-infrared region. Furthermore, the first principle calculations reveal that the Eu-doping strengthens the localization of energy bands at near Fermi level of LaB6 and reduces the number of conduction electrons in the conduction band, which in turn decreases its plasmon resonance frequency energy, which qualitatively explains the continuous tunable characteristic of La1-xEuxB6 transmission light.

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趙瑞山,黃美松,劉華,楊露輝,羅天縱,郭利平,劉維.多元稀土硼化物L(fēng)a1-xEuxB6納米粉末的制備及光學(xué)性能研究[J].稀有金屬材料與工程,2023,52(1):153~159.[Zhao Ruishan, Huang Meisong, Liu Hua, Yang Luhui, Luo Tianzong, Guo Liping, Liu Wei. Fabrication and Optical Properties of Nanocrystalline Multi Rare Earth Hexaborides La1-xEuxB6 powders[J]. Rare Metal Materials and Engineering,2023,52(1):153~159.]
DOI:10.12442/j. issn.1002-185X.20211096

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  • 收稿日期:2021-12-10
  • 最后修改日期:2022-01-27
  • 錄用日期:2022-02-09
  • 在線發(fā)布日期: 2023-02-13
  • 出版日期: 2023-02-08