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納米鋁溶膠雜化有機(jī)硅耐火阻燃涂層的制備及性能
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上海大學(xué)理學(xué)院納米中心

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中圖分類號(hào):

TQ637

基金項(xiàng)目:

上海市科委項(xiàng)目(項(xiàng)目號(hào)20dz1201102)


Preparation and Properties of Nano-Aluminium Sol Hybrid Silicone Refractory Flame Retardant Coating
Author:
Affiliation:

1.Colloge of Sciences,Research Center of Nano Science Technology,Shanghai University,Shang Hai 200444;2.China;3.Colloge of Sciences,Research Center of Nano Science Technology,Shanghai University,Shang Hai 200444

Fund Project:

Shanghai Municipal Science and Technology Commission Project

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    摘要:

    本文以納米鋁溶膠為無(wú)機(jī)組份(ALS),甲基三乙氧基硅烷(MTES)和苯基三乙氧基硅烷(PhTES)為有機(jī)前驅(qū)體,通過(guò)溶膠凝膠法制備了納米鋁溶膠雜化甲基三乙氧基硅烷(ALS/MTES)、納米鋁溶膠雜化苯基三乙氧基硅烷(ALS/PhTES)和納米鋁溶膠雜化甲基三乙氧基硅烷及苯基三乙氧基硅烷(ALS/MTES/PhTES)三種有機(jī)/無(wú)機(jī)雜化耐火阻燃涂層。對(duì)涂層的柔韌性測(cè)試表明,含苯基硅烷的ALS/PhTES和ALS/MTES/PhTES涂層的柔韌性優(yōu)于ALS/MTES 涂層,說(shuō)明PhTES的引入可提升涂層柔韌性。對(duì)涂層熱穩(wěn)定性測(cè)試表明,ALS/ MTES / PhTES涂層的Tg最高,為205.78℃,900℃時(shí)剩余質(zhì)量為72.57%,說(shuō)明PhTES的加入可提高涂層熱穩(wěn)定性。SEM照片顯示,涂層表面均勻致密且無(wú)明顯相界面。另外,XRD測(cè)試表明,涂層耐火阻燃機(jī)理歸因于鋁溶膠受熱分解、Si-O-Si無(wú)規(guī)解聚和側(cè)鏈烷基分解。

    Abstract:

    In this paper, three kinds of organic/inorganic hybrid flame retardant coatings were prepared by sol-gel method using water-based nano-aluminum sol as the inorganic component (ALS), methyltriethoxysilane (MTES) and phenyltriethoxysilane (PhTES) as the organic precursors. The three kinds of coatings are nano-aluminum sol hybrid methyltriethoxysilane (ALS/MTES), nano-aluminum sol hybrid phenyltriethoxysilane (ALS/PhTES), and nano-aluminum sol hybrid methyltriethoxysilane and phenyltriethoxysilane (ALS/MTES/PhTES). The flexibility test of the coatings showed that the flexibility of ALS / PhTES and ALS / MTES / PhTES coatings containing phenylsilane were better than that of ALS / MTES coatings, indicating that the addition of PhTES could improve the flexibility of the coating. The thermal stability test of the coatings illustrate that the Tg of ALS/MTES/PhTES coating is 205.78°C, which is the highest, besides, the residual mass reaches 72.57% when the temperature is 900 °C. It illustrates that the addition of PhTES promotes the thermal stability of the coating in some extent. The SEM figure of the samples show that the surface of coating is uniform, dense and without obvious phase interface. Otherwise, the XRD test results of the coating before and after ablation show that its mechanism of fire-resistant is attributed to the decomposition of boehmite (AlO(OH)), random depolymerization of the main chain Si-O-Si in coating and the decomposition of side chain alkyl.

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郭玉婷,杭建忠,王媛,李園園,孫小英,施利毅.納米鋁溶膠雜化有機(jī)硅耐火阻燃涂層的制備及性能[J].稀有金屬材料與工程,2023,52(1):160~166.[Guo Yuting, Hang Jianzhong, Wang Yuan, Li Yuanyuan, Sun Xiaoying, Shi Liyi. Preparation and Properties of Nano-Aluminium Sol Hybrid Silicone Refractory Flame Retardant Coating[J]. Rare Metal Materials and Engineering,2023,52(1):160~166.]
DOI:10.12442/j. issn.1002-185X.20211086

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  • 收稿日期:2021-12-08
  • 最后修改日期:2022-02-21
  • 錄用日期:2022-03-07
  • 在線發(fā)布日期: 2023-02-13
  • 出版日期: 2023-02-08