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激光熔覆ZrB2-SiC增強(qiáng)Cu基復(fù)合涂層的微觀結(jié)構(gòu)與摩擦學(xué)性能
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燕山大學(xué) 亞穩(wěn)材料制備技術(shù)與科學(xué)國(guó)家重點(diǎn)實(shí)驗(yàn)室

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河北省自然科學(xué)基金項(xiàng)目E2017203298


Microstructure and tribological properties of laser cladding ZrB2-SiC reinforced Cu matrix composite coating
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State Key Laboratory of Metastable Materials Science & Technology, Yanshan University

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    摘要:

    為了提高銅表面的強(qiáng)度和耐磨性,以復(fù)合粉末(Zr、Si、Ni包B4C、Cu)為原料,采用激光輔助原位合成技術(shù),在純銅基體表面制備了ZrB2-SiC/Cu復(fù)合涂層。通過(guò)XRD、SEM和TEM分析了復(fù)合涂層的表面形貌、微觀結(jié)構(gòu)、相組成和界面結(jié)合,并測(cè)試了不同增強(qiáng)相含量熔覆層的硬度和摩擦學(xué)性能。結(jié)果表明:通過(guò)設(shè)計(jì)的原位化學(xué)反應(yīng)成功在銅基體內(nèi)合成了微米級(jí)針狀ZrB2和納米級(jí)顆粒狀SiC。增強(qiáng)相均與基體形成了清潔、無(wú)雜相的界面。兩種不同維度與尺寸的增強(qiáng)體,通過(guò)多種強(qiáng)化機(jī)制,顯著改善了復(fù)合涂層的力學(xué)性能;通過(guò)調(diào)整激光工藝參數(shù)可實(shí)現(xiàn)增強(qiáng)體尺寸的控制,隨著增強(qiáng)相含量的提高,復(fù)合涂層的平均硬度和耐磨損性逐漸增加。當(dāng)增強(qiáng)相含量為30 wt%時(shí),復(fù)合涂層的平均硬度為309 HV0.2,約為純銅的5.6倍。30 wt%涂層的載流磨損率與含量為10 wt%的涂層相比,降低了約80%。較高含量的復(fù)合涂層表現(xiàn)出優(yōu)異的摩擦學(xué)性能。

    Abstract:

    In order to improve the strength and wear resistance of the copper, ZrB2-SiC/Cu composite coating was prepared on the surface of a copper substrate by laser cladding with the raw materials of Zr, Si, Ni-B4C, Cu composite powders. The surface morphology, microstructure, phase composition and interface combination of the composite coating were analyzed by OM, XRD, SEM and TEM, And the hardness and wear resistance of coatings with different reinforcement phase content were tested. The results showed that the micron-sized needle-like ZrB2 and nano-sized granular SiC were successfully synthesized in the copper matrix by the designed in-situ synthesis reaction. A clean and impurity-free interface formed between the reinforcements and the copper matrix. Mechanical properties of the composite coating were improved by two reinforcements with different dimensions and sizes through a variety of strengthening mechanisms. The size of the reinforcement could be controlled by adjusting the laser process parameters, with the content of the reinforcements increased, the average hardness and wear resistance of the composite coating gradually increased. The average hardness of the composite coating with the reinforcing phase content of 30 wt% was 309 HV0.2, which was about 5.6 times that of pure copper. The current-carrying wear rate of the 30 wt% composite coating was about 80% lower than that of the 10 wt% coating. The higher content of the composite coating showed excellent current-carrying wear resistance.

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趙月紅,戰(zhàn)再吉,呂相哲,曹海要.激光熔覆ZrB2-SiC增強(qiáng)Cu基復(fù)合涂層的微觀結(jié)構(gòu)與摩擦學(xué)性能[J].稀有金屬材料與工程,2023,52(1):267~273.[Zhao Yuehong, Zhan Zaiji, Lv Xiangzhe, Cao Haiyao. Microstructure and tribological properties of laser cladding ZrB2-SiC reinforced Cu matrix composite coating[J]. Rare Metal Materials and Engineering,2023,52(1):267~273.]
DOI:10.12442/j. issn.1002-185X.20211056

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歷史
  • 收稿日期:2021-11-30
  • 最后修改日期:2022-01-28
  • 錄用日期:2022-02-09
  • 在線(xiàn)發(fā)布日期: 2023-02-13
  • 出版日期: 2023-02-08