2O4涂層;面比電阻;抗氧化性;結(jié)合性能"/> 2O4尖晶石涂層作為固體氧化物燃料電池的金屬連接體表面涂層的性能,使用溶膠-凝膠法制備出純凈的前驅(qū)體粉末,再使用電泳沉積方法制備出致密的MnCo2O4尖晶石涂層,利用SEM、EDS和XRD等表征手段觀察分析MnCo2O4尖晶石涂層的相結(jié)構(gòu)和微觀組織形貌。采用“四探針?lè)ā睖y(cè)量MnCo2O4尖晶石涂層800℃氧化200h前后的面比電阻使用拉拔法完成不同界面粗糙度下的涂層結(jié)合強(qiáng)度測(cè)試,并用有限元仿真加以驗(yàn)證。結(jié)果顯示,MnCo2O4尖晶石涂層結(jié)構(gòu)均勻,致密度較好。相較于AISI430不銹鋼基體來(lái)說(shuō),在800℃空氣中氧化200h,抗氧化性提高了接近3倍。且中溫面比電阻小于SOFC金屬連接體規(guī)定的極限值。此外,基體表面粗糙度可以有效的增加涂層與基體的機(jī)械咬合作用,但同時(shí)也會(huì)導(dǎo)致應(yīng)力集中,出現(xiàn)缺陷,從而降低了結(jié)合強(qiáng)度。"/>

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AISI430鐵素體不銹鋼表面制備MnCo2O4涂層特性及內(nèi)應(yīng)力研究
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昆明理工大學(xué)材料科學(xué)與工程學(xué)院、云南昆明

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)52161014 與 51665022)


Study on the characteristics and internal stress of MnCo2O4 coatings prepared on the surface of AISI430 ferritic stainless steel
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Faculty of Materials Science and Engineering,Kunming University of Science and Technology

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    為了探究MnCo2O4尖晶石涂層作為固體氧化物燃料電池的金屬連接體表面涂層的性能,使用溶膠-凝膠法制備出純凈的前驅(qū)體粉末,再使用電泳沉積方法制備出致密的MnCo2O4尖晶石涂層,利用SEM、EDS和XRD等表征手段觀察分析MnCo2O4尖晶石涂層的相結(jié)構(gòu)和微觀組織形貌。采用“四探針?lè)ā睖y(cè)量MnCo2O4尖晶石涂層800℃氧化200h前后的面比電阻使用拉拔法完成不同界面粗糙度下的涂層結(jié)合強(qiáng)度測(cè)試,并用有限元仿真加以驗(yàn)證。結(jié)果顯示,MnCo2O4尖晶石涂層結(jié)構(gòu)均勻,致密度較好。相較于AISI430不銹鋼基體來(lái)說(shuō),在800℃空氣中氧化200h,抗氧化性提高了接近3倍。且中溫面比電阻小于SOFC金屬連接體規(guī)定的極限值。此外,基體表面粗糙度可以有效的增加涂層與基體的機(jī)械咬合作用,但同時(shí)也會(huì)導(dǎo)致應(yīng)力集中,出現(xiàn)缺陷,從而降低了結(jié)合強(qiáng)度。

    Abstract:

    In order to investigate the performance of MnCo2O4 spinel coating as a metal linker surface coating for solid oxide fuel cells, pure precursor powder was prepared by sol-gel method, and then dense MnCo2O4 spinel coating was prepared by electrophoretic deposition method. The four-probe method was used to measure the surface specific resistance of MnCo2O4 spinel coatings before and after oxidation at 800°C for 200 h. The bond strength of the coatings was tested at different interface roughnesses using the pull-out method and verified using finite element simulations. The results show that the MnCo2O4 spinel coating has a homogeneous structure and good densities. Compared to the AISI430 stainless steel substrate, oxidation at 800°C in air for 200h increases the oxidation resistance by nearly three times. And the specific resistance at the medium temperature surface is less than the limit value specified for SOFC metal connectors. In addition, the surface roughness of the substrate can effectively increase the mechanical bite between the coating and the substrate, but at the same time it can also lead to stress concentration and defects, which reduce the bond strength.

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衛(wèi)書(shū)超,李明宇,詹肇麟. AISI430鐵素體不銹鋼表面制備MnCo2O4涂層特性及內(nèi)應(yīng)力研究[J].稀有金屬材料與工程,2022,51(12):4697~4704.[Wei ShuChao, Li MingYu, Zhan ZhaoLin. Study on the characteristics and internal stress of MnCo2O4 coatings prepared on the surface of AISI430 ferritic stainless steel[J]. Rare Metal Materials and Engineering,2022,51(12):4697~4704.]
DOI:10.12442/j. issn.1002-185X.20211050

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  • 收稿日期:2021-11-29
  • 最后修改日期:2022-01-28
  • 錄用日期:2022-03-07
  • 在線(xiàn)發(fā)布日期: 2023-01-19
  • 出版日期: 2022-12-30