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摻雜La2O3對CDPF催化性能的影響
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1.同濟大學汽車學院;2.中國汽車技術研究中心有限公司

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移動源污染排放控制技術國家工程實驗室開放基金資助(項目號NELMS2020A02)


Effect of La2O3 doping on the catalytic performance of CDPF
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1.School of Automotive Studies,Tongji University;2.China Automotive Technology Research Center Co Ltd

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    摘要:

    本文在CDPF催化劑上,通過摻雜10、20和30 g/L不同濃度的La2O3的助劑制備了不同的CDPF樣品,采用XRD、XPS、H2-TPR等表征方法以及活性評價技術,研究摻雜不同濃度La2O3的CDPF載體表面催化劑的理化特性和催化活性的關系。結果表明:隨著La2O3的摻雜濃度的增加,樣品的結晶度先增加再減??;樣品表面的Pt原子濃度先降低再升高;樣品對CO的氧化活性呈下降趨勢;樣品對C3H8的特征溫度T10和T50均呈先增加再降低,然后再增加的趨勢;樣品對NO2產率的T10呈增加趨勢。

    Abstract:

    In this paper, different CDPF samples were prepared on the CDPF catalyst by doping with 10, 20 and 30 g/L of different concentrations of La2O3additives. Using XRD, XPS, H2-TPR and other characterization methods and activity evaluation techniques, the relationship between the physicochemical characteristics and catalytic activity of the CDPF carrier surface catalyst doped with different concentrations of La2O3was studied. The results show that as the La2O3 doping concentration increases, the crystallinity of the sample first increases and then decreases; the Pt atomic concentration on the surface of the sample first decreases and then increases; the oxidation activity of the sample to CO shows a downward trend; The characteristic temperature T10 and T50 of the samples for C3H8 both increased first and then decreased, and then increased again; the T10 of the samples for NO2generation rate showed an increasing tendency.

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樓狄明,樓國康,張允華,房亮,馮謙.摻雜La2O3對CDPF催化性能的影響[J].稀有金屬材料與工程,2022,51(12):4689~4696.[Lou Diming, Lou Guokang, Zhang Yunhua, Fang Liang, Feng Qian. Effect of La2O3 doping on the catalytic performance of CDPF[J]. Rare Metal Materials and Engineering,2022,51(12):4689~4696.]
DOI:10.12442/j. issn.1002-185X.20210970

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  • 收稿日期:2021-11-09
  • 最后修改日期:2022-04-22
  • 錄用日期:2022-06-14
  • 在線發(fā)布日期: 2023-01-19
  • 出版日期: 2022-12-30