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醫(yī)用鎂合金微弧氧化涂層制備及降解行為研究進展
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1.教育部現(xiàn)代冶金技術重點實驗室;2.北京科技大學

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河北省自然科學基金(E2020209153)、河北省省屬高校基本科研業(yè)務費(JYG2019001)、唐山市科學技術研究與發(fā)展計劃(20130205b)、新金屬材料國家重點實驗室開放基金(2020-Z12)


Research Progress on Preparation and Degradation Behavior of Micro-arc Oxidation Coatings of Medical Magnesium Alloys
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financial support of the Science and Technology Projram of Hebei (E2020209153); Basic Scientifc Research Business Expenses of the Universities in Hebei Province (JYG2019001); Science and Technology Project of Tangshan (20130205b); State Key Lab of Advanced Metals and Materials (2020-Z12)

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    摘要:

    近年來,鎂合金作為“可降解醫(yī)用金屬材料”越來越受到研究人員的親睞。然而,鎂合金的腐蝕降解較快導致的力學衰減顯著、材料與骨愈合的適配性減弱是當前限制其臨床應用的瓶頸性問題。微弧氧化作為一種有效的減緩鎂合金降解速率措施,具有工藝簡單、成膜效率高、膜層整體綜合性能指標好等優(yōu)點,實現(xiàn)了降解速度可調(diào)控與改善生物相容性雙重功能。本文主要從微弧氧化涂層形成機制及膜層降解機理出發(fā),綜述了生物醫(yī)用鎂合金微弧氧化涂層研究進展;詳細闡述了微弧氧化涂層鎂合金的膜層形成/破裂機制;系統(tǒng)地歸納了微弧氧化工藝參數(shù)和涂層降解性能、生物相容性的本質(zhì)聯(lián)系;揭示了自封孔型氧化膜的生長機制、封孔物質(zhì)的沉積過程及其保留在微孔內(nèi)的原因;概述了復合表面處理技術的膜層物相特征及仿生溶液環(huán)境下降解行為規(guī)律。最后,展望了醫(yī)用鎂合金微弧氧化涂層的未來發(fā)展方向。

    Abstract:

    In recent years, magnesium alloy as a "degradable medical metal material" is more and more favored by researchers. However, the rapid corrosion degradation of magnesium alloys leads to significant mechanical attenuation and weakened suitability of the materials for bone healing, which is a bottleneck limiting its clinical application at present. As an effective measure to slow down the degradation rate of magnesium alloys, micro-arc oxidation has the advantages of simple process, high film forming efficiency and good overall performance index of the film, and realizes the dual functions of regulating the degradation rate and improving biocompatibility. The research progress of micro-arc oxidation coatings on biomedical magnesium alloys was reviewed. The essential relationship between micro-arc oxidation process parameters and biocompatibility of coating degradation performance was systematically summarized. The formation/rupture mechanism of micro-arc oxidation coating magnesium alloy was described in detail. The growth mechanism of the self-sealing porous oxide film the deposition process of the porous material and the reason of its retention in the micro-pores were revealed. The phase characteristics of composite surface treatment film and its degradation behavior in bionic solution environment were summarized. Finally, the future development direction of micro-arc oxidation coating for medical magnesium alloy was prospected.

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張源,鄭瑞寧,田亞強,鄭小平,王艷麗,陳連生.醫(yī)用鎂合金微弧氧化涂層制備及降解行為研究進展[J].稀有金屬材料與工程,2023,52(1):374~387.[Zhang Yuan, Zheng Ruining, Tian Yaqiang, Zheng Xiaoping, Wang Yanli, Chen Liansheng. Research Progress on Preparation and Degradation Behavior of Micro-arc Oxidation Coatings of Medical Magnesium Alloys[J]. Rare Metal Materials and Engineering,2023,52(1):374~387.]
DOI:10.12442/j. issn.1002-185X.20210928

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  • 收稿日期:2021-10-25
  • 最后修改日期:2022-01-05
  • 錄用日期:2022-01-29
  • 在線發(fā)布日期: 2023-02-13
  • 出版日期: 2023-02-08