25 m/s以上時非晶含量明顯提升,當(dāng)v<25 m/s時初始磁化曲線表現(xiàn)為一步磁化過程,退磁曲線的方形度較好;當(dāng)v>25 m/s時向兩步磁化轉(zhuǎn)變,退磁曲線出現(xiàn)明顯塌腰;在v=25 m/s時取得最佳磁性能,分別為Br=0.91T,μ0Hcj=1.70 T,(BH)max=108.22 kJ/m3。對快淬薄帶進(jìn)行適當(dāng)?shù)木Щ嘶鹛幚砗?,快淬帶中的非晶含量顯著減少,v≤25 m/s的快淬薄帶的磁性能有所改善;v>25 m/s時退磁曲線塌腰消失,矯頑力大幅提升,方形度明顯改善;在v=35 m/s制備的快淬薄帶取得最高矯頑力,μ0Hcj = 2.10 T;v=30 m/s時取得最佳磁性能,分別為Br=0.91T,μ0Hcj=1.82 T,(BH)max=141.61 kJ/m3??齑惚蚊惭睾穸确较蜃兓?,熱處理前其貼輥面一側(cè)以非晶及細(xì)晶為主,自由面晶粒較大;熱處理后貼輥面一側(cè)的非晶含量顯著減少。"/>

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快淬速度及熱處理對Nd26Pr3FebalCo4Ga0.42B0.92快淬薄帶微觀結(jié)構(gòu)和磁性的影響
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鋼鐵研究總院功能材料研究所

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國家自然科學(xué)基金資助(項目號51771055);寧波市科技創(chuàng)新2025重大專項資助(項目號2019B10093)


Effects of melt-spunning speed and heat treatment on the magnetic properties and microstructure of Nd26Pr3FebalCo4Ga0.42B0.92 melt-spun ribbons.
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Central Iron Steel Research Institute

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    研究了快淬速度(v=15、20、25、30和35 m/s)和熱處理對熔體快淬法制備的成分為Nd26Pr3FebalCo4Ga0.42B0.92的快淬薄帶的微觀結(jié)構(gòu)和磁性能的影響。v<25m/s 時,薄帶自由面具有明顯的取向,c軸垂直于薄帶表面;隨著快淬速度的提升,取向度明顯降低。提高快淬速度可以細(xì)化晶粒,提升至v>25 m/s以上時非晶含量明顯提升,當(dāng)v<25 m/s時初始磁化曲線表現(xiàn)為一步磁化過程,退磁曲線的方形度較好;當(dāng)v>25 m/s時向兩步磁化轉(zhuǎn)變,退磁曲線出現(xiàn)明顯塌腰;在v=25 m/s時取得最佳磁性能,分別為Br=0.91T,μ0Hcj=1.70 T,(BH)max=108.22 kJ/m3。對快淬薄帶進(jìn)行適當(dāng)?shù)木Щ嘶鹛幚砗?,快淬帶中的非晶含量顯著減少,v≤25 m/s的快淬薄帶的磁性能有所改善;v>25 m/s時退磁曲線塌腰消失,矯頑力大幅提升,方形度明顯改善;在v=35 m/s制備的快淬薄帶取得最高矯頑力,μ0Hcj = 2.10 T;v=30 m/s時取得最佳磁性能,分別為Br=0.91T,μ0Hcj=1.82 T,(BH)max=141.61 kJ/m3??齑惚蚊惭睾穸确较蜃兓?,熱處理前其貼輥面一側(cè)以非晶及細(xì)晶為主,自由面晶粒較大;熱處理后貼輥面一側(cè)的非晶含量顯著減少。

    Abstract:

    The effects of melt-spinning speed(v=15,20,25,30 and 35 m/s, respectively) and heat-treatment process on the magnetic properties and microstructure of melt-spun Nd26Pr3FebalCo4Ga0.42B0.92 ribbons were investigated. The ribbons show an obvious orientation when the speed v is less than 25m/s in the free side,which c-axis is perpendicular to the strip surface;the orientation decreases with the increase of melt-spinning speed. The grain can be refined by increasing the melt-spinning speed,when v < 25 m/s, the amorphous content increases obviously, the initial magnetization shows a one-step magnetization process,which demagnetization curve have good squareness;When v > 25 m / s, the initial magnetization changes to two-step magnetization process, and the demagnetization curve collapses obviously; The best magnetic properties are obtained when v=25 m/s,Br=0.91T,μ0Hcj=1.70 T,(BH)max=108.22 kJ/m3, After optimum crystallization annealing treatment, the amorphous content reduce significantly;all of the magnetic properties of ribbons have improved,the v>25 m/s imporve obviously, squareness and coercivity improve remarkable.The ribbon prepared at v=35m/s get the highest coercivity, μ0Hcj=2.10 T.The best magnetic properties are obtained when v=30 m/s,Br=0.91T,μ0Hcj=1.82 T,(BH)max=141.65 kJ/m3,The microstructure changes along with the thickness direction.The wheel side is composed of amorphous and fine grains,the free side is composed by larger grains.After the heat-treatment,the amorphous is reduced significantly.

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苑子凱,郭朝暉,王俊明,鐘雨江,柳帥,朱明剛.快淬速度及熱處理對Nd26Pr3FebalCo4Ga0.42B0.92快淬薄帶微觀結(jié)構(gòu)和磁性的影響[J].稀有金屬材料與工程,2022,51(6):2273~2279.[YUAN Zikai, GUO Zhaohui, WANG Junming, ZHONG Yujiang, LIU Shuai, ZHU Minggang. Effects of melt-spunning speed and heat treatment on the magnetic properties and microstructure of Nd26Pr3FebalCo4Ga0.42B0.92 melt-spun ribbons.[J]. Rare Metal Materials and Engineering,2022,51(6):2273~2279.]
DOI:10.12442/j. issn.1002-185X.20210877

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  • 收稿日期:2021-10-10
  • 最后修改日期:2022-01-02
  • 錄用日期:2022-01-29
  • 在線發(fā)布日期: 2022-07-06
  • 出版日期: 2022-06-29