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釩摻雜Cd0.9Mn0.1Te晶體生長(zhǎng)與深能級(jí)缺陷研究
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長(zhǎng)安大學(xué) 材料科學(xué)與工程學(xué)院

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中圖分類(lèi)號(hào):

TG145; TN304; O77+1; O782+.1

基金項(xiàng)目:

陜西省重點(diǎn)研發(fā)計(jì)劃﹣國(guó)際科技合作項(xiàng)目:編號(hào)2020KWZ-008


Growth and Deep Level Defects of V-doped Cd0.9Mn0.1Te Crystal
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1.School of Materials Science and Engineering,Chang''an University,Xi''an 710061;2.China

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    摘要:

    CdMnTe(碲錳鎘)材料作為新一代的半導(dǎo)體材料,在核輻射探測(cè)領(lǐng)域具有很高的應(yīng)用價(jià)值。本文采用Te溶液垂直布里奇曼法生長(zhǎng)Cd0.9Mn0.1Te: V晶體,研究其光電性能及深能級(jí)缺陷的分布。紫外-可見(jiàn)-近紅外光譜分析表明晶錠中部和尾部的禁帶寬度分別為1.602 eV和1.598 eV。光致發(fā)光譜中,晶體的(D0,X)峰形尖銳,半峰寬較小,表明缺陷或雜質(zhì)含量低,晶體質(zhì)量好。室溫I-V測(cè)試晶錠中部和尾部晶體電阻率分別為2.85×1010 Ω?cm和9.54×109 Ω?cm,漏電流分別為3 nA和8.5 nA?;魻枩y(cè)試表明晶體導(dǎo)電類(lèi)型為n型。通過(guò)熱激電流譜研究了Cd0.9Mn0.1Te: V晶體中缺陷的能級(jí)和濃度,其中晶錠中部和尾部樣品中源于Te反位(Te2+ Cd)的深施主能級(jí)(EDD)的值分別為0.90 eV和0.812 eV。并且深施主能級(jí)EDD使費(fèi)米能級(jí)位于禁帶中央,從而使晶體呈現(xiàn)高電阻率。

    Abstract:

    As a new generation of semiconductor materials, CdMnTe material has high application value in the field of nuclear radiation detection. In this paper, Te solution vertical Bridgman method was used to grow Cd0.9Mn0.1Te: V crystal to study the optical and electrical properties and the distribution of deep-level defects of the Cd0.9Mn0.1Te: V crystal. UV-VIS-NIR spectroscopy analysis shows that the band gap in the middle and tail of the ingot is 1.602 eV and 1.598 eV. The photoluminescence spectral analysis shows that the (D0,X) peak of the crystal is sharp and the half-width is small, indicating that the defect or impurity content is low and the crystal quality is superior. The room temperature I-V test, shows that the resistivities of the middle and tail crystals are 2.85×1010 Ω?cm and 9.54×109 Ω?cm, and leakage currents 3 nA and 8.5 nA, respectively. The Hall test shows that the conductivity type of the crystal is n-type. The energy of the trap peak and the defect concentration in the Cd0.9Mn0.1Te: V crystal are studied by heat induced current spectroscopy. The values of the deep donor levels (EDD) derived from the Te2+ Cd in the middle and tail samples of the ingot are 0.90 eV and 0.812 eV, respectively. Does the deep donor level EDD make the Fermi level in the center of the forbidden band and thus to present a high resistivity.

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游思偉,艾濤,欒麗君.釩摻雜Cd0.9Mn0.1Te晶體生長(zhǎng)與深能級(jí)缺陷研究[J].稀有金屬材料與工程,2022,51(5):1873~1878.[You Siwei, Ai Tao, Luan Lijun. Growth and Deep Level Defects of V-doped Cd0.9Mn0.1Te Crystal[J]. Rare Metal Materials and Engineering,2022,51(5):1873~1878.]
DOI:10.12442/j. issn.1002-185X.20210486

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  • 收稿日期:2021-06-02
  • 最后修改日期:2021-09-26
  • 錄用日期:2021-09-27
  • 在線發(fā)布日期: 2022-06-09
  • 出版日期: 2022-05-30