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燒結助劑對固體氧化物電池的質(zhì)子導體電解質(zhì)燒結性能和電導率影響的研究進展
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作者單位:

1.深圳大學;2.哈爾濱工業(yè)大學(深圳);3.中國科學院寧波材料技術與工程研究所

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國家自然科學基金(52072247); 寧波市科技創(chuàng)新2025重大專項(2018B100489); 深圳市基礎研究項目(JCYJ20170817110358231); 中國博士后科學基金(2021M692209)


Research Advances in the Effect of Additives on the Sinterability and Conductivity of Proton-conducting Electrolyte for Solid Oxide Cells
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1.Shenzhen University;2.Ningbo Institute of Material Technology Engineering,Chinese Academy of Sciences,Ningbo

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    摘要:

    質(zhì)子導體氧化物在600 °C下具有較高的質(zhì)子導電性,在應用于開發(fā)低成本、耐用的中低溫固體氧化物電池方面具有顯著的優(yōu)勢。目前,BaZr1-xYxO3-δ (BZY),BaCe0.7-xZrxY0.2O3-δ (BCZY)和BaCe0.7-xZrxY0.1Yb0.1O3-δ (BCZYYb)等基于Ba、Ce、Zr、Y和Yb的ABO3型鈣鈦礦結構的質(zhì)子導體電解質(zhì)材料具有最優(yōu)異的電化學性能。但是這些材料的燒結性能,電導性能和穩(wěn)定性難以兼得,從而嚴重限制了它們的應用。為了在較低的燒結溫度下獲得具有高導電率和長期穩(wěn)定的致密的電解質(zhì),最常用的方法是在質(zhì)子導體氧化物中添加燒結助劑。而最近報道的研究論文中,燒結助劑對質(zhì)子導體導電性的影響存在較大的差異。所以本綜述全面討論了近年來燒結助劑改性的質(zhì)子導電氧化物的研究進展,并詳細總結了不同燒結助劑對質(zhì)子導電氧化物相對密度、晶粒生長、燒結行為、體電導率和晶界電導率的影響,進而提出一些潛在的研究思路。

    Abstract:

    Proton-conducting oxides show high proton conductivity operating below 600 °C, which offers a significant advantage in developing low cost and durable solid oxide cells (SOCs) at intermediate-to-low temperature. The ABO3 perovskites based on Ba, Ce, Zr, Y, and Yb are state-of-the-art proton conductors such as BaZr1-xYxO3-δ (BZY), BaCe0.7-xZrxY0.2O3-δ (BCZY), and BaCe0.7-xZrxY0.1Yb0.1O3-δ (BCZYYb). However, it is very difficult for these materials to balance the sinterability, conductivity and stability. To achieve dense electrolyte with high conductivity and long-term stability at the low sintering temperature, one of the most common approach is adding sintering aids in the fabrication processing of proton-conducting oxides. In recent researches, the effect of sintering additives on the electrical conductivity of proton conductors are still in the arguments. This review provides a comprehensive discussion of recent research developments on sintering additives modified proton conducting oxide. Moreover, we summary in detail the influence of different sintering additives on the relative density, grain growth, sintering behavior, and bulk and boundary conductivity of proton conducting oxides, as well as pointing out the potential research directions.

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劉志軍,陶有堃,王建新,邵靜.燒結助劑對固體氧化物電池的質(zhì)子導體電解質(zhì)燒結性能和電導率影響的研究進展[J].稀有金屬材料與工程,2022,51(6):2288~2301.[Liu Zhijun, Tao Youkun, Wang Jianxin, Shao Jing. Research Advances in the Effect of Additives on the Sinterability and Conductivity of Proton-conducting Electrolyte for Solid Oxide Cells[J]. Rare Metal Materials and Engineering,2022,51(6):2288~2301.]
DOI:10.12442/j. issn.1002-185X.20210479

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  • 收稿日期:2021-06-01
  • 最后修改日期:2021-07-09
  • 錄用日期:2021-08-05
  • 在線發(fā)布日期: 2022-07-06
  • 出版日期: 2022-06-29