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二次急冷淬火成形SAF2507雙相不銹鋼螺旋槳在SRB+IOB海水中的腐蝕行為
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作者單位:

1.集美大學(xué) 海洋裝備與機(jī)械工程學(xué)院;2.江蘇大學(xué) 材料科學(xué)與工程學(xué)院

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中圖分類(lèi)號(hào):

TG172,8; TG 142.71

基金項(xiàng)目:

國(guó)家自然科學(xué)基金項(xiàng)目,福建省科技計(jì)劃引導(dǎo)性(重點(diǎn))項(xiàng)目,福建省自然科學(xué)基金項(xiàng)目


Corrosion Behaviors of SAF2507 DSS Propeller blade in SRB+IOB Seawater by Secondary quench Stamping
Author:
Affiliation:

1.School of Marine Equipment and Mechanical Engineering ,Jimei University;2.School of Materiai Science and Engineering,Jiangsu University

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    摘要:

    為了研究SAF2507雙相不銹鋼(SAF2507 DSS)螺旋槳葉片在含硫酸鹽還原菌( SRB)和鐵氧化菌(IOB)海水中的耐腐蝕性能,提出一種二次急冷淬火成形技術(shù)來(lái)成形SAF2507 DSS螺旋槳葉片。同時(shí)根據(jù)螺旋槳葉片在不同二次急冷淬火成形溫度下析出相的類(lèi)型和析出規(guī)律,研究螺旋槳葉片在含SRB和IOB海水中的腐蝕性能。結(jié)果表明,當(dāng)二次急冷淬火成形溫度在700℃時(shí),螺旋槳葉片表面析出少量的χ相;達(dá)到850℃時(shí),χ相停止析出并完全轉(zhuǎn)化成σ相,析出的σ相達(dá)到最大值;超過(guò)850℃時(shí),析出的σ相開(kāi)始急劇減少,到950℃時(shí)僅有少量的σ相析出。螺旋槳葉片在不同二次急冷淬火成形溫度下,腐蝕電流密度、交流阻抗等電化學(xué)性能變化規(guī)律與螺旋槳葉片表層χ相和σ相的析出規(guī)律、以及χ相和σ相自身的耐腐蝕特征相吻合。二次急冷淬火成形溫度在750℃-1050℃之間,螺旋槳葉片的耐腐蝕性能隨熱成形溫度的升高呈增強(qiáng)—降低—增強(qiáng)規(guī)律變化,850℃時(shí)螺旋槳葉片的耐腐蝕性能最差。螺旋槳葉片二次急冷淬火成形后富Fe的表面特征,在SRB+IOB的作用下,螺旋槳葉片表面鈍化膜被破壞,導(dǎo)致耐腐蝕性能降低。

    Abstract:

    In order to study the corrosion resistance of the SAF2507 duplex stainless steel (SAF2507 DSS) propeller blades in seawater containing sulfate-reducing bacteria (SRB) and iron oxidizing bacteria (IOB), a secondary quench stamping technology was proposed to stamping SAF2507 DSS propeller blades.The corrosion behavior of propeller blades in seawater containing SRB and IOB was studied according to the precipitated phases types and precipitation laws of the propeller blades at different secondary quench stamping temperatures.The results showed that when the secondary quench stamping temperature was 700℃,a small amount of χ phases was precipitated on the surface of the propeller blades;and when it reached 850℃, the χ phases is completely converted to the σ phases, and the precipitation of σ phases reach the peak value,and at 950 ° C only a small number of σ phases are precipitated.The variation laws of the corrosion current density,Ac impedance and other electrochemical properties of propeller blades at different secondary quench stamping temperatures was consistent with that of χ phases and σ phases in the surface layer of propeller blades and the corrosion resistance characteristics of χ phases and σ phases themselves.When the secondary quench stamping temperature was between 750 ° C and 1050 ° C, the corrosion resistance of propeller blades changes in the rule of "enhancement - reduction - enhancement" with the increase of the secondary quench stamping temperature, and the corrosion resistance of propeller blades was the worst at 850 ° C in seawater containing SRB and IOB.For the surface characteristics of the rich Fe on the surface layer of propeller blade after secondary quench stamping, the surface passivation film of propeller blade was damaged in seawater containing SRB and IO, which leads to the decrease of corrosion resistance.

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郭幼丹,程曉農(nóng).二次急冷淬火成形SAF2507雙相不銹鋼螺旋槳在SRB+IOB海水中的腐蝕行為[J].稀有金屬材料與工程,2022,51(6):2258~2266.[GUO Youdan, Cheng Xiaonon. Corrosion Behaviors of SAF2507 DSS Propeller blade in SRB+IOB Seawater by Secondary quench Stamping[J]. Rare Metal Materials and Engineering,2022,51(6):2258~2266.]
DOI:10.12442/j. issn.1002-185X.20210462

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  • 收稿日期:2021-05-23
  • 最后修改日期:2021-07-18
  • 錄用日期:2021-08-05
  • 在線(xiàn)發(fā)布日期: 2022-07-06
  • 出版日期: 2022-06-29