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稀土元素La對金屬表面粉末滲鋅層組織結構和性能的影響
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北京科技大學工程技術研究院

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國家十三五重點研發(fā)計劃項目(項目號2017YFB0304602)


Effect of the rare earth element La on the structure and properties of the powder sheladizing layer on the metal surface
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Institute of Engineering Technology, University of Science and Technology Beijing

Fund Project:

National Key R&D Program of China (2017YFB0304602)

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    摘要:

    金屬結構件表面經(jīng)粉末滲鋅后具有良好的耐腐蝕性能、滲鋅層與基體的結合強度高等優(yōu)點,但滲層結構及質量有待進一步提高。本文在金屬結構件表面滲鋅處理的滲鋅劑中加入不同摻雜量的稀土元素La(質量分數(shù)分別為0 %,1.3 %,2.7 %,4.0 %,5.3 %),采用SEM觀察表面形貌、XRD測定物相以及占比情況、激光共聚焦掃描顯微鏡(CLSM)生成超高分辨率的3D表面形貌圖像以評估表面粗糙度特性、納米壓痕(Nano Indenter G200)研究滲層的硬度評估其機械性能。結果表明,滲鋅劑中添加4.0 %稀土元素La可以更好地改善滲層的微觀結構、增加滲層中柱狀致密的δ相使?jié)B層組織細化且致密、減少凹坑裂紋等缺陷的產生、提高滲層的均勻性,滲層在厚度方向上硬度有所提高,并且硬度分布更加均勻。通過測量材料開路電位(OCP)、極化曲線(Tafel)和電化學阻抗譜(EIS)表明添加4.0%的La元素形成的滲層耐腐蝕性能更好。

    Abstract:

    Powder sherardizing has the advantages of good corrosion resistance, high bonding strength with the matrix, and low melting point of the material. However, improving the quality of the powder zinc layer and optimizing the performance of powder zinc layer are still the aspects that need to be studied. In this paper, different doping amounts of rare earth element La (mass fractions of 0%, 1.3%, 2.7%, 4.0%, 5.3%) were added to the sherardizing agent for surface sherardizing treatment of metal structural parts. Use SEM to observe surface morphology, XRD to determine phase and proportion, confocal laser scanning microscope (CLSM) to generate ultra-high resolution 3D surface morphology images to evaluate surface roughness characteristics, nanoindentation (Nano Indenter G200) study the hardness of the powder zinc layer to evaluate its mechanical properties.The results show that adding 4.0% rare earth element La to the sherardizing agent can better improve the microstructure of the infiltrated layer, increase the columnar and compact δ phase in the permeable layer to make the structure of the layer fine and compact, and reduce the occurrence of defects such as pits and cracks, thereby improving the uniformity of the layer. The hardness of the layer in the thickness direction is improved, and the hardness distribution is more uniform.By measuring the open circuit potential (OCP), polarization curve (Tafel) and electrochemical impedance spectroscopy (EIS) of the material, it is shown that the corrosion resistance of the layer formed by adding 4.0% La element is better.

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辛江萍,胡水平,張思遠,張業(yè)飛,陳俊.稀土元素La對金屬表面粉末滲鋅層組織結構和性能的影響 [J].稀有金屬材料與工程,2022,51(5):1887~1895.[Xinjiangping, Huishuiping, Zhangsiyuan, Zhangyefei, Chenjun. Effect of the rare earth element La on the structure and properties of the powder sheladizing layer on the metal surface[J]. Rare Metal Materials and Engineering,2022,51(5):1887~1895.]
DOI:10.12442/j. issn.1002-185X.20210437

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  • 收稿日期:2021-05-17
  • 最后修改日期:2021-08-12
  • 錄用日期:2021-08-26
  • 在線發(fā)布日期: 2022-06-09
  • 出版日期: 2022-05-30