-1增加到0.9 g·L-1,膜層的疏水性和硬度隨之提高。通過SEM/EDS和XPS表征,驗(yàn)證了石墨烯在Cu-GR膜層中的均勻分散以及Cu-GR復(fù)合材料的組成。利用動(dòng)電位極化曲線和電化學(xué)阻抗譜(EIS)研究了Cu-GR復(fù)合鍍層的電化學(xué)性能。結(jié)果表明,石墨烯的加入使膜層的電化學(xué)性能更加穩(wěn)定、耐蝕性得到提高。當(dāng)電沉積液中石墨烯添加濃度為0.3 g·L-1時(shí),獲得的Cu-GR復(fù)合包覆層在NdFeB基體上表現(xiàn)出最優(yōu)的綜合保護(hù)效果。"/>

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燒結(jié)NdFeB表面銅-石墨烯復(fù)合膜的制備與表征
作者:
作者單位:

1.浙江工業(yè)大學(xué) 材料科學(xué)與工程學(xué)院 磁電功能材料研究所,浙江 杭州 310014;2.浙江工業(yè)大學(xué) 機(jī)械工程學(xué)院,浙江 杭州 310000;3.安徽大地熊新材料股份有限公司,安徽 合肥 231500

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通訊作者:

中圖分類號(hào):

基金項(xiàng)目:

國(guó)家自然科學(xué)基金項(xiàng)目(52101235); 浙江省科技廳重點(diǎn)研發(fā)項(xiàng)目(2021C01172)


Preparation and Characterization of Copper-Graphene Com-posite Films on Sintered NdFeB Surface
Author:
Affiliation:

1.Research Center of Magnetic and Electronic Materials, College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China;2.College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310000, China;3.State Key Laboratory of Rare Earth Permanent Magnet Materials, Earth-Panda Advance Magnetic Material Co., Ltd, Hefei 231500, China

Fund Project:

National Natural Science Foundation of China (51871201); Key R&D Project of Zhejiang Provincial Department of Science and Technology (2021C01172)

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    摘要:

    采用電沉積銅-石墨烯(Cu-GR)復(fù)合膜的方法對(duì)稀土永磁NdFeB材料進(jìn)行包覆以提高其耐腐蝕性。對(duì)Cu-GR膜層的微觀結(jié)構(gòu)、水接觸角和表面顯微硬度等方面進(jìn)行了分析。結(jié)果表明,隨著電沉積液中石墨烯的添加量從0 g·L-1增加到0.9 g·L-1,膜層的疏水性和硬度隨之提高。通過SEM/EDS和XPS表征,驗(yàn)證了石墨烯在Cu-GR膜層中的均勻分散以及Cu-GR復(fù)合材料的組成。利用動(dòng)電位極化曲線和電化學(xué)阻抗譜(EIS)研究了Cu-GR復(fù)合鍍層的電化學(xué)性能。結(jié)果表明,石墨烯的加入使膜層的電化學(xué)性能更加穩(wěn)定、耐蝕性得到提高。當(dāng)電沉積液中石墨烯添加濃度為0.3 g·L-1時(shí),獲得的Cu-GR復(fù)合包覆層在NdFeB基體上表現(xiàn)出最優(yōu)的綜合保護(hù)效果。

    Abstract:

    Corrosion resistance of rare earth permanent magnet material NdFeB was achieved by electrodeposited Cu-graphene (Cu-GR) composite films. The impact of the films on corrosion performances was studied by examining the morphology, water contact angle, and surface microhardness. The results show that the hydrophobicity and the hardness are enhanced as the concentration of graphene in the plating solution increases from 0 g·L-1 to 0.9 g·L-1. The characterization through SEM/EDS and XPS verifies the uniform dispersion of graphene sheets in the electrodeposited coating and the composition of Cu-GR composites. The electrochemical performance of the Cu-GR composite coating was investigated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS), and it is demonstrated that the electrochemical performance becomes more stable and the corrosion resistance is improved with the addition of graphene in the composites. For the sintered NdFeB samples coated with Cu-GR composite films with different graphene concentrations the best protective effect is obtained for the film prepared from the plating solution with a graphene concentration of 0.3 g·L-1.

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陳海波,鄭精武,付永成,劉友好,衣曉飛,陳靜武,喬梁,黃秀蓮,應(yīng)耀,蔡偉,李旺昌,余靚.燒結(jié)NdFeB表面銅-石墨烯復(fù)合膜的制備與表征[J].稀有金屬材料與工程,2021,50(12):4306~4313.[Chen Haibo, Zheng Jingwu, Fu Yongcheng, Liu Youhao, Yi Xiaofei, Chen Jingwu, Qiao Liang, Huang Xiulian, Ying Yao, Cai Wei, Li Wangchang, Yu Jing. Preparation and Characterization of Copper-Graphene Com-posite Films on Sintered NdFeB Surface[J]. Rare Metal Materials and Engineering,2021,50(12):4306~4313.]
DOI:10.12442/j. issn.1002-185X.20210377

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  • 收稿日期:2021-04-28
  • 最后修改日期:2021-11-26
  • 錄用日期:2021-06-22
  • 在線發(fā)布日期: 2021-12-30
  • 出版日期: 2021-12-24