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超瞬態(tài)凝固增材制造梯度整體渦輪葉盤用高溫合金粉末特性研究Ⅱ:葉片用合金粉末
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1.北京航空材料研究院 先進(jìn)高溫結(jié)構(gòu)材料重點(diǎn)實(shí)驗(yàn)室;2.南方科技大學(xué) 機(jī)械與能源工程系;3.湖南大學(xué) 機(jī)械與運(yùn)載工程學(xué)院

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中圖分類號(hào):

TG132.3+2;TF122; TG115

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國家自然科學(xué)基金(重大研究計(jì)劃培育項(xiàng)目,面上項(xiàng)目),國家科技重大專項(xiàng),重點(diǎn)實(shí)驗(yàn)室基金


The characteristics of Ni-based superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing Ⅱ: blade alloy powders
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1.Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials;2.Department of Mechanical and Energy Engineering, Southern University of Science and Technology;3.College of Mechanical and Vehicle Engineering,Hunan University

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    摘要:

    本文針對(duì)超瞬態(tài)凝固增材制造梯度整體渦輪葉盤高溫合金葉片用合金粉末特性開展研究。根據(jù)合金的承溫能力和JMatPro相平衡計(jì)算結(jié)果,選用DZ4125作為葉片材料,K418作為葉盤輪緣部位材料。采用真空感應(yīng)熔煉氬氣霧化制粉(VIGA)制備DZ4125高溫合金粉末,篩分至53-105μm粒度范圍,采用采用差示掃描量熱分析(DSC)、場發(fā)射掃描電鏡(FESEM)和能譜(EDS)、激光粒度儀、動(dòng)態(tài)圖像粒度粒形分析儀以及綜合粉體性能測(cè)試儀對(duì)DZ4125高溫合金粉末的相變溫度、顯微組織、析出相成分、元素偏析行為、粒度、粒形、松裝密度、振實(shí)密度和流動(dòng)性進(jìn)行系統(tǒng)表征。結(jié)果表明:DZ4125比K418合金的固液凝固溫度范圍寬,過渡區(qū)DZ4125+K418混合成分合金其液相線溫度和MC碳化物開始析出溫度介于兩種合金之間,γ′開始析出溫度與兩種合金相當(dāng)。DZ4125合金粉末形貌主要為球形和近球形,表面和截面顯微組織主要呈樹枝晶結(jié)構(gòu)。所含元素中偏析傾向較強(qiáng)的元素有Hf、Ta、Ti、Mo和W,而偏析傾向弱的元素包括Ni、Co、Cr和Al。粉末內(nèi)部枝晶間區(qū)分布有細(xì)小的MC碳化物,尺寸約為200nm。激光衍射和動(dòng)態(tài)圖像分析法測(cè)得的DZ4125粉末粒度值接近,中位徑D50分別為70.2μm和72.8μm。動(dòng)態(tài)圖像法測(cè)得DZ4125合金粉末具有較好的球形度,SPHT和b/l均值分別為0.91和0.86。所選DZ4125高溫合金粉末具有較好的松裝密度、振實(shí)密度和流動(dòng)性,其松裝和振實(shí)密度分別達(dá)到合金理論密度的52%和63%,壓縮度為17.7%,且粉末具有較好的流動(dòng)性(20.79 s?(50 g)-1)。

    Abstract:

    The characteristics of superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing are investigated. According to the temperature capacity of the alloy and the phase equilibrium diagram calculated by JMatPro, DZ4125 is selected as the blade material, whereas K418 alloys are selected as the disk rim material for integral turbine blisk. The superalloy powder are prepared by vacuum induction melting and argon gas atomization (VIGA) and sieved to the particle size range of 53-105μm. The differential scanning calorimeter (DSC), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), laser diffraction particle size analyzer, dynamic image analysis system and comprehensive powder property analyzer are used to systematically characterize the phase transformation temperatures, microstructure, precipitated phase composition, element segregation, particle size and shape, apparent density, tap density and flowability of the selected superalloy powders. The results show that DZ4125 possesses wider solid-liquid temperature range than that of K418 alloy. The liquidus temperature and MC carbide initial precipitation temperature of the transition zone DZ4125+K418 hybrid composition alloy are between that of the two alloys, and the γ" onset precipitation temperature is equivalent to the two alloys. The morphology of DZ4125 alloy powders is mainly spherical and nearly spherical. The surface and cross-section microstructures are mainly dendritic structure. For the selected alloy powders, the elements Hf,Ta, Ti, Mo and W exhibit strong segregation tendency, while the elements with weak segregation tendency include Ni, Cr, Co and Al. There are fine MC carbides distributed in the interdendritic zone of the powder, the size is about 200nm. The particle size distribution of powders measured by laser diffraction and dynamic image analysis methods are similar. The D50 value of DZ4125 powder is 70.2μm and 72.8μm. The dynamic image analysis result shows that the DZ4125 alloy powders possess good sphericity, and the SPHT and b/l values are 0.91 and 0.86, respectively. The DZ4125 superalloy powders have good apparent density, tap density and flowablity. The apparent density and tap density of the alloy powders can reach 52% and 63% of the theoretical density of the DZ4125 alloy, respectively. In addition, the DZ4125 superalloy powders possess compressibility of 17.7% and flowability of 20.79 s?(50 g)-1.

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鄭亮,劉朝陽,朱強(qiáng),宋立軍,李周,張國慶.超瞬態(tài)凝固增材制造梯度整體渦輪葉盤用高溫合金粉末特性研究Ⅱ:葉片用合金粉末[J].稀有金屬材料與工程,2021,50(11):3979~3986.[Zheng Liang, Liu Zhaoyang, Zhu Qiang, Song Lijun, Li Zhou, Zhang Guoqing. The characteristics of Ni-based superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing Ⅱ: blade alloy powders[J]. Rare Metal Materials and Engineering,2021,50(11):3979~3986.]
DOI:10.12442/j. issn.1002-185X.20210346

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  • 收稿日期:2021-04-19
  • 最后修改日期:2021-05-07
  • 錄用日期:2021-05-24
  • 在線發(fā)布日期: 2021-11-30
  • 出版日期: 2021-11-24