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超瞬態(tài)凝固增材制造梯度整體渦輪葉盤(pán)用高溫合金粉末特性研究I:盤(pán)體用合金粉末
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作者單位:

1.北京航空材料研究院 先進(jìn)高溫結(jié)構(gòu)材料重點(diǎn)實(shí)驗(yàn)室;2.南方科技大學(xué) 機(jī)械與能源工程系;3.湖南大學(xué) 機(jī)械與運(yùn)載工程學(xué)院

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中圖分類(lèi)號(hào):

TG132.3+2;TF122; TG115

基金項(xiàng)目:

國(guó)家自然科學(xué)基金重大研究計(jì)劃培育項(xiàng)目,國(guó)家自然科學(xué)基金面上項(xiàng)目,國(guó)家重大科技專(zhuān)項(xiàng),重點(diǎn)實(shí)驗(yàn)室基金


The characteristics of Ni-based superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing I: disk alloy powders
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1.Advanced High Temperature Structural Materials Laboratory,Beijing Institute of Aeronautical Materials;2.College of Mechanical and Vehicle Engineering,Hunan University

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    摘要:

    本文針對(duì)超瞬態(tài)凝固增材制造梯度整體渦輪葉盤(pán)用高溫合金粉末特性開(kāi)展研究。根據(jù)合金的承溫能力和JMatPro相平衡計(jì)算結(jié)果,分別選用GH4169和K418作為盤(pán)體心部和輪盤(pán)邊緣部位材料,DZ4125作為葉片材料。采用真空感應(yīng)熔煉氬氣霧化制粉(VIGA)制備高溫合金粉末,篩分至53-105μm粒度范圍,采用差示掃描量熱分析(DSC)、場(chǎng)發(fā)射掃描電鏡(FESEM)、電子探針(EPMA)、激光粒度儀、動(dòng)態(tài)圖像粒度粒形分析儀以及綜合粉體性能測(cè)試儀對(duì)高溫合金粉末的相變溫度、顯微組織、元素偏析行為、粒度、粒形、松裝密度、振實(shí)密度和流動(dòng)性進(jìn)行了系統(tǒng)表征。結(jié)果表明:K418合金固液溫度范圍比G4169合金窄,K418合金的γ′和MC碳化物的開(kāi)始析出溫度均比GH4169高,過(guò)渡區(qū)(GH4169+K418)混合成分合金主要強(qiáng)化相的析出溫度介于GH4169和K418兩種合金之間。GH4169和K418合金粉末形貌主要為球形和近球形。表面和截面顯微組織主要呈樹(shù)枝晶結(jié)構(gòu),所含元素中偏析傾向較強(qiáng)的元素有Ti、Nb、Zr和Mo,均富集分布于枝晶間,而偏析傾向弱的元素包括Ni、Cr、Fe和Al,高溫合金粉末元素偏析類(lèi)型與鑄造鎳基高溫合金相近,但粉末組織更為細(xì)小均勻。激光衍射和動(dòng)態(tài)圖像分析法測(cè)得的粉末粒度值接近,GH4169的D50分別為79.1μm和76.2μm,K418的D50分別為67.8μm和65.6μm。動(dòng)態(tài)圖像法測(cè)得2種合金均具有較好的球形度,GH4169和K418的SPHT均值分別為0.91和0.90。所選GH4169和K418高溫合金粉末具有相近的松裝密度、振實(shí)密度和流動(dòng)性,其松裝和振實(shí)密度分別達(dá)到合金理論密度的50%和60%,壓縮度在13.3~15.5%范圍,粉末具有較好的流動(dòng)性(18.5~20.4 s?(50 g)-1)。

    Abstract:

    The characteristics of superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing are investigated. According to the temperature capacity of the alloy and the phase equilibrium diagram calculated by JMatPro, GH4169 and K418 alloys are selected as the disk hub and rim materials respectively, whereas DZ4125 is selected as the blade material for integral turbine blisk. The superalloy powder are prepared by vacuum induction melting and argon gas atomization (VIGA) and sieved to the particle size range of 53-105μm. The differential scanning calorimeter (DSC), field emission scanning electron microscope (FESEM), electron probe x-ray micro-analyzer (EPMA), laser diffraction particle size analyzer, dynamic image analysis system and comprehensive powder property analyzer are used to systematically characterize the phase change temperatures, microstructure, element segregation, particle size and shape, apparent density, tap density and flowability of the selected superalloy powders. The results show that the liquidus and solidus temperature range of K418 alloy is smaller than that of the GH4169 alloy. The onset precipitated temperature of γ′and MC carbides of K418 alloy is higher than that of GH4169. The precipitation temperatures of the main strengthening phases of the (GH4169+K418) hybrid composition alloy in the transition zone are between that of the GH4169 and K418 alloys. The morphology of GH4169 and K418 alloy powders is mainly spherical and nearly spherical. The surface and cross-section microstructures are mainly dendritic structure. For the selected alloy powders, the elements Ti, Nb, Zr and Mo, which is rich in the interdendritic region, exhibit strong segregation tendency, while the elements with weak segregation tendency include Ni, Cr, Fe and Al. The element segregation type of superalloy powder is similar to the cast Ni-based superalloys, however the powders possess finer and uniform microstructure than that of the cast superalloy. The particle size distribution of powders measured by laser diffraction and dynamic image analysis methods are similar. The D50 value of GH4169 is 79.1μm and 76.2μm, and the D50 of K418 is 67.8μm and 65.6μm, respectively. The dynamic image analysis result shows that the two alloys both possess good sphericity, and the SPHT mean values of GH4169 and K418 are 0.91 and 0.90, respectively. The GH4169 and K418 superalloy powders have similar apparent density, tap density and flowablity. In addition, the apparent density and tap density of the two alloy powders can reach 50% and 60% of the theoretical density of the alloy respectively. Furthermore, the GH4169 and K418 superalloy powders both have good compressibility (13.3~15.5%) and flowability of 18.5~20.4 s?(50 g)-1.

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鄭亮,劉朝陽(yáng),朱強(qiáng),宋立軍,李周,張國(guó)慶.超瞬態(tài)凝固增材制造梯度整體渦輪葉盤(pán)用高溫合金粉末特性研究I:盤(pán)體用合金粉末[J].稀有金屬材料與工程,2021,50(10):3648~3656.[Zheng Liang, Liu Zhaoyang, Zhu Qiang, Song Lijun, Li Zhou, Zhang Guoqing. The characteristics of Ni-based superalloy powders used for the gradient integral turbine blisk by the hyper-transient solidified additive manufacturing I: disk alloy powders[J]. Rare Metal Materials and Engineering,2021,50(10):3648~3656.]
DOI:10.12442/j. issn.1002-185X.20210280

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  • 收稿日期:2021-04-01
  • 最后修改日期:2021-05-07
  • 錄用日期:2021-05-24
  • 在線發(fā)布日期: 2021-10-28
  • 出版日期: 2021-10-25