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孔特性可控的輕質(zhì)YSZ泡沫陶瓷制備及其力學(xué)性能研究
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1.江西科技師范大學(xué);2.中國科學(xué)院上海硅酸鹽研究所

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基金項(xiàng)目:

國家自然科學(xué)基金(51862009);江西省科技廳自然科學(xué)基金(20202BABL204016);江西省教育廳科技類重點(diǎn)項(xiàng)目(GJJ190585);校級(jí)青年拔尖人才項(xiàng)目(2018QNBJRC005); 大學(xué)生創(chuàng)新訓(xùn)練計(jì)劃項(xiàng)目(20201404089)


Research on fabrication and mechanical properties of lightweight YSZ ceramicfoams with controllable cell structure
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    摘要:

    采用顆粒穩(wěn)定泡沫的方法制備出閉孔結(jié)構(gòu)、孔徑均勻分布和輕質(zhì)的氧化釔穩(wěn)定的氧化鋯(YSZ)泡沫陶瓷。研究燒結(jié)溫度、表面活性劑種類和固含量對(duì)泡沫陶瓷骨架組成、孔特性(包括孔隙率、孔徑分布和平均孔徑)和壓縮強(qiáng)度的影響規(guī)律。結(jié)果顯示,孔隙率處于45-85 %之間時(shí),YSZ泡沫陶瓷的壓縮強(qiáng)度與孔隙率之間的關(guān)系符合Rice模型;在1450 ℃燒結(jié)溫度及固含量為32.50 vol%時(shí),采用異丁烯與馬來酸酐共聚物分子和陽離子型表面活性劑十二烷基三甲基氯化銨共穩(wěn)YSZ濕泡沫制備出的材料綜合性能最優(yōu),孔隙率為83.7±0.2 %、平均孔徑90.1±0.8 μm、壓縮強(qiáng)度45.1±1.3 MPa。在相同孔隙率的情況下,YSZ泡沫陶瓷的壓縮強(qiáng)度高于大多數(shù)已報(bào)道的結(jié)果。

    Abstract:

    The particle-stabilized foams method was successfully applied to fabricate the lightweight YSZ ceramic foams with closed pore structure and uniform pore size distribution. The microstructure of YSZ ceramic foams, including strut structure, porosity, mean pore size and pore size distribution were tailored by varying the sintering temperature, surfactant type and solid content of the initial slurries. When the sintering temperature at 1450 ℃ and solid content 32.50 vol%, YSZ ceramic foams with porosity of 83.7±0.2 %, mean pore size of 90.1±0.8 μm and compressive strength of 45.1±1.3 MPa were obtained through Isobam molecule and cationic surfactant dodecyl trimethyl ammonium chloride (DTAC) co-stabilized YSZ wet foam. The compressive strength of YSZ ceramic foams in present work was much higher than most reported results in the case of same porosity.

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艾建平,李萌,周國紅,江博帆,胡麗玲,王正娟,李文魁.孔特性可控的輕質(zhì)YSZ泡沫陶瓷制備及其力學(xué)性能研究[J].稀有金屬材料與工程,2022,51(3):1072~1080.[Ai Jianping, Li Meng, Zhou Guohong, Jiang Bofan, Hu Liling, Wang Zhengjuan, Li Wenkui. Research on fabrication and mechanical properties of lightweight YSZ ceramicfoams with controllable cell structure[J]. Rare Metal Materials and Engineering,2022,51(3):1072~1080.]
DOI:10.12442/j. issn.1002-185X.20210247

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  • 收稿日期:2021-03-23
  • 最后修改日期:2021-05-22
  • 錄用日期:2021-06-21
  • 在線發(fā)布日期: 2022-04-06
  • 出版日期: 2022-03-30