脈沖氙燈;鎢電極;表面成分;價態(tài)演變"/> 闡明高功率脈沖氙燈鎢電極運行過程中的演變過程及工作機理,采用金相顯微鏡、掃描電鏡(SEM)、X-射線光電子能譜(XPS)等手段研究了運行不同發(fā)次的高功率脈沖氙燈陰極表面形貌、元素的價態(tài)演變及其濃度-深度分布狀況,結(jié)果表明鎢電極工作表面出現(xiàn)大量的龜裂紋,其裂紋程度和深度、燒蝕狀況均與運行發(fā)次有關(guān),工作次數(shù)越多裂紋和燒蝕情況越嚴重;隨著運行發(fā)次增加,陰極表面元素含量向表面擴散,含量升高,最高達12%,分布更加均勻通過對Ce3+/Ce4+比例分析發(fā)現(xiàn)運行10083發(fā)次的鎢陰極表面活性處于較佳狀態(tài);運行14486發(fā)次的鎢陰極表面活性層明顯減小,僅有6.66nm,氙燈性能處于下降狀態(tài)。"/>

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高功率脈沖氙燈鈰鎢電極工作過程中表面稀土元素分布和價態(tài)演變
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中國科學(xué)院上海光學(xué)精密機械研究所

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Evolution of Surface Morphorlogy and Cerium Element distribution of the cerium–tungsten electrode in High-power Pulsed Xenon Lamp during Operation
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    摘要:

    闡明高功率脈沖氙燈鎢電極運行過程中的演變過程及工作機理,采用金相顯微鏡、掃描電鏡(SEM)、X-射線光電子能譜(XPS)等手段研究了運行不同發(fā)次的高功率脈沖氙燈陰極表面形貌、元素的價態(tài)演變及其濃度-深度分布狀況,結(jié)果表明鎢電極工作表面出現(xiàn)大量的龜裂紋,其裂紋程度和深度、燒蝕狀況均與運行發(fā)次有關(guān),工作次數(shù)越多裂紋和燒蝕情況越嚴重;隨著運行發(fā)次增加,陰極表面元素含量向表面擴散,含量升高,最高達12%,分布更加均勻;通過對Ce3+/Ce4+比例分析發(fā)現(xiàn)運行10083發(fā)次的鎢陰極表面活性處于較佳狀態(tài);運行14486發(fā)次的鎢陰極表面活性層明顯減小,僅有6.66nm,氙燈性能處于下降狀態(tài)

    Abstract:

    In order to illustrate the evolution process and working mechanism of the cerium–tungsten electrode of the high-power pulsed xenon lamp during operation, the cathode surface morphology of the high-power pulsed xenon lamp running for different times, the evolution of the valence state of cerium and its concentration–depth distribution have been studied using a metallurgical microscope, scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and other methods. The results show that a large number of cracks and ablation of different degrees appear on the working surface of the cerium–tungsten electrode; the degree and depth of the cracks and the ablation depend on the running times; and the crack and ablation are more serious with more working times. As the running time increases, the cerium on the cathode surface diffuses to the working surface of the cerium–tungsten electrode, with the content of cerium increased for a uniform distribution. Through the analysis of Ce3+/ Ce4+ ratio, it has found that the surface activity of the cerium–tungsten cathode running 6466 and 10083 times is in a better state; and the surface activity layer of the cerium–tungsten cathode running 14486 times is significantly reduced, and the electrode is approaching its service life.

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郭向朝,劉作嬌,李海兵,劉建軍,胡麗麗.高功率脈沖氙燈鈰鎢電極工作過程中表面稀土元素分布和價態(tài)演變[J].稀有金屬材料與工程,2022,51(5):1879~1886.[Guo Xiangchao,劉作嬌,Li Haibing, Liu Jiangjun, Hu Lili. Evolution of Surface Morphorlogy and Cerium Element distribution of the cerium–tungsten electrode in High-power Pulsed Xenon Lamp during Operation[J]. Rare Metal Materials and Engineering,2022,51(5):1879~1886.]
DOI:10.12442/j. issn.1002-185X.20210187

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  • 收稿日期:2021-03-08
  • 最后修改日期:2021-11-24
  • 錄用日期:2022-01-29
  • 在線發(fā)布日期: 2022-06-09
  • 出版日期: 2022-05-30