17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金條帶,并研究了Cu元素的添加及含量變化對(duì)Al17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金耐腐蝕性能的影響。利用X射線衍射儀(XRD)、差示掃描量熱儀(DSC)、顯微硬度計(jì)分別研究了合金材料的非晶形成能力與硬度;通過(guò)極化曲線(Tafel)和Nyquist圖等電化學(xué)方法考察了高熵非晶合金室溫下在3.5 wt.% NaCl水溶液中的耐腐蝕性能。結(jié)果表明:四種(AlNiZrCo)75-xCuxY20Si5(x=0, 10, 14, 15)近等原子比高熵非晶合金均呈現(xiàn)典型的非晶態(tài)衍射峰,Cu含量對(duì)AlNiZrCoYSi高熵非晶合金的非晶形成能力影響不大,但會(huì)降低合金的抗腐蝕性能,且上述合金的維氏顯微硬度均超過(guò)470 HV0.1。其中,Al17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金的耐腐蝕性能最佳,其自腐蝕電位(Ecorr)為-0.248 V,自腐蝕電流密度(icorr)為1.63 μA/cm2,極化電阻(Rp)為24.56 kΩ.cm2,該材料在解決嚴(yán)苛海洋環(huán)境下防腐耐磨問(wèn)題具有較大的應(yīng)用潛力。"/>

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Cu含量對(duì)新型AlNiZrCoYSi高熵非晶合金非晶形成能力與耐腐蝕性能的影響
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1.浙江大學(xué) 海洋學(xué)院;2.軍事科學(xué)院 國(guó)防科技創(chuàng)新研究院

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國(guó)家重點(diǎn)研發(fā)計(jì)劃項(xiàng)目(2018YFC1902400);國(guó)家自然科學(xué)基金(51975582);北京市自然科學(xué)基金(2212055)的資助


Effect of Copper Content on Corrosion Resistance and Glass-formingAbility of Novel AlNiZrCoYSi High Entropy Amorphous Alloy
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Zhejiang University, Ocean College

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    摘要:

    采用高真空電弧熔煉噴射成形技術(shù)制備了一種新型Al17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金條帶,并研究了Cu元素的添加及含量變化對(duì)Al17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金耐腐蝕性能的影響。利用X射線衍射儀(XRD)、差示掃描量熱儀(DSC)、顯微硬度計(jì)分別研究了合金材料的非晶形成能力與硬度;通過(guò)極化曲線(Tafel)和Nyquist圖等電化學(xué)方法考察了高熵非晶合金室溫下在3.5 wt.% NaCl水溶液中的耐腐蝕性能。結(jié)果表明:四種(AlNiZrCo)75-xCuxY20Si5(x=0, 10, 14, 15)近等原子比高熵非晶合金均呈現(xiàn)典型的非晶態(tài)衍射峰,Cu含量對(duì)AlNiZrCoYSi高熵非晶合金的非晶形成能力影響不大,但會(huì)降低合金的抗腐蝕性能,且上述合金的維氏顯微硬度均超過(guò)470 HV0.1。其中,Al17.5Ni20Zr17.5Co20Y20Si5高熵非晶合金的耐腐蝕性能最佳,其自腐蝕電位(Ecorr)為-0.248 V,自腐蝕電流密度(icorr)為1.63 μA/cm2,極化電阻(Rp)為24.56 kΩ.cm2,該材料在解決嚴(yán)苛海洋環(huán)境下防腐耐磨問(wèn)題具有較大的應(yīng)用潛力。

    Abstract:

    A new type of high entropy amorphous alloy (denoted as HEAA) ribbons Al17.5Ni20Zr17.5Co20Y20Si5 was prepared by injection in copper mould with arc melting. The effect of Cu content on corrosion resistance of the Al17.5Ni20Zr17.5Co20Y20Si5 HEAA was studied mainly by adding Cu element into the alloy. The glass-forming ability and hardness of the alloy were studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and microhardness tester, respectively. The corrosion resistance of these ribbons in 3.5 wt.% NaCl corrosive solution at room temperature were investigated by potentiodynamic polarization curves (Tafel) and Nyquist plots. The results show that four kinds of (AlNiZrCo)75-xCuxY20Si5(x=0, 10, 14, 15) near equiatomic HEAA ribbons present typical amorphous diffraction peaks. The Cu content has little effect on the glass-forming ability of the AlNiZrCoYSi HEAA ribbons, but it will reduce the corrosion resistance. The Vickers microhardness of the above alloys is over 470 HV0.1. The corrosion resistance of the Al17.5Ni20Zr17.5Co20Y20Si5 HEAA ribbons is the finest. The corrosion potential (Ecorr) is -0.248 V, the corrosion-current density (icorr) is 1.63 μA / cm2, and the polarization resistance (RP) is 24.56 kΩ.cm2. This material has demanding application potential to solve the problem of anti-corrosion and wear resistance in harsh marine environment.

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張舒研,張志彬,王鑫,高洋洋,梁秀兵,王立忠. Cu含量對(duì)新型AlNiZrCoYSi高熵非晶合金非晶形成能力與耐腐蝕性能的影響[J].稀有金屬材料與工程,2021,50(12):4587~4591.[Zhang Shuyan, Zhang Zhibin, Wang Xin, Gao Yangyang, Liang Xiubing, Wang Lizhong. Effect of Copper Content on Corrosion Resistance and Glass-formingAbility of Novel AlNiZrCoYSi High Entropy Amorphous Alloy[J]. Rare Metal Materials and Engineering,2021,50(12):4587~4591.]
DOI:10.12442/j. issn.1002-185X.20210175

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  • 收稿日期:2021-03-04
  • 最后修改日期:2021-03-07
  • 錄用日期:2021-04-16
  • 在線發(fā)布日期: 2022-01-09
  • 出版日期: 2021-12-24