oC開始收縮,115 oC開始致密化,160 oC致密度可達95%以上,200 oC度即可完成致密化。在250 ℃燒結(jié)5 min后,晶粒尺寸從初始粉體的200 nm增長到600 nm。X衍射結(jié)果表明,在液相輔助等離子燒結(jié)過程中,ZnO陶瓷中未出現(xiàn)明顯雜相,并且晶粒生長表現(xiàn)出沿外施壓力垂直的方向取向生長。通過計算發(fā)現(xiàn)液相輔助等離子體燒結(jié)ZnO陶瓷,其晶粒生長活化能僅為78.8 kJ/mol,約為傳統(tǒng)高溫燒結(jié)的三分之一。ZnO陶瓷試樣的室溫阻抗結(jié)果表明,晶界阻抗隨燒結(jié)溫度的升高而下降,從120 oC燒結(jié)試樣的9.82×106 W下降到250 oC燒結(jié)試樣的2.75×103 W。"/>

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液相對ZnO陶瓷放電等離子體燒結(jié)過程的影響
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重慶大學輸配電裝備及系統(tǒng)安全與新技術(shù)國家重點實驗室

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國家自然科學基金面上項目(51877016);重慶市自然科學基金(cstc2019jcyjxfkxX0008);霍英東教育基金(171050)


Effect of liquid phase on the spark plasma sintering process of ZnO ceramic
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State Key Laboratory of Power Transmission Equipment System Security and New Technology,Chongqing University,Shapingba District

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    本文采用放電等離子體燒結(jié)技術(shù)制備了ZnO陶瓷,主要研究了液相(醋酸溶液)的添加對燒結(jié)過程的影響。結(jié)果表明,通過對初始粉料添加微量的2 mol/L的醋酸溶液,在等離子體燒結(jié)過程中,ZnO陶瓷試樣在52 oC開始收縮,115 oC開始致密化,160 oC致密度可達95%以上,200 oC度即可完成致密化。在250 ℃燒結(jié)5 min后,晶粒尺寸從初始粉體的200 nm增長到600 nm。X衍射結(jié)果表明,在液相輔助等離子燒結(jié)過程中,ZnO陶瓷中未出現(xiàn)明顯雜相,并且晶粒生長表現(xiàn)出沿外施壓力垂直的方向取向生長。通過計算發(fā)現(xiàn)液相輔助等離子體燒結(jié)ZnO陶瓷,其晶粒生長活化能僅為78.8 kJ/mol,約為傳統(tǒng)高溫燒結(jié)的三分之一。ZnO陶瓷試樣的室溫阻抗結(jié)果表明,晶界阻抗隨燒結(jié)溫度的升高而下降,從120 oC燒結(jié)試樣的9.82×106 W下降到250 oC燒結(jié)試樣的2.75×103 W。

    Abstract:

    ZnO ceramics were fabricated via spark plasma sintering (SPS) technology. The role of acetic acid solution on the SPS was mainly investigated. The results indicated that, with the addition of liquid phase (2 mol/L acetic acid solution) during SPS, the shrinkage and densification of ZnO ceramic samples were activated at 52 oC and 115 oC, respectively. The density of ZnO ceramic samples can be achieved to the value of more than 95% and then fully densified when the sintering temperature was further increased to 160 oC and 200 oC. The grain grows from 200 nm of the raw particle to 600 nm after sintering at 250 oC for 5 min. The X-ray diffraction results show that no obvious impurity phase can be observed, and the grain growth present a clear anisotropic orientation, preferentially growing along the vertical direction of applied pressure. With assistance of liquid phase in SPS, the grain growth activation energy was determined at only 78.8 kJ/mol, a third as large as that sintered in the conventional SPS. Impedance of ZnO ceramic samples was measured at room temperature. It was found that the grain boundary resistance decreases from 9.82×106 W to 2.75×103 W with the increasing sintering temperature from 120 oC to 250 oC.

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張潔心,康晟淋,趙學童,孫健杰,梁杰,陳晗,楊麗君,廖瑞金.液相對ZnO陶瓷放電等離子體燒結(jié)過程的影響[J].稀有金屬材料與工程,2021,50(10):3634~3639.[Zhang Jiexin, Kang Shenglin, Zhao Xuetong, Sun Jianjie, Liang Jie, Chen Han, Yang Lijun, Liao Ruijin. Effect of liquid phase on the spark plasma sintering process of ZnO ceramic[J]. Rare Metal Materials and Engineering,2021,50(10):3634~3639.]
DOI:10.12442/j. issn.1002-185X.20210157

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  • 收稿日期:2021-02-26
  • 最后修改日期:2021-03-04
  • 錄用日期:2021-04-16
  • 在線發(fā)布日期: 2021-10-28
  • 出版日期: 2021-10-25