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磁控共濺射制備鐿銅及鐿銅鋁非晶合金薄膜
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包頭稀土研究院,白云鄂博稀土資源研究與綜合利用國家重點(diǎn)實(shí)驗(yàn)室

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白云鄂博稀土資源研究與綜合利用國家重點(diǎn)實(shí)驗(yàn)室自主課題(項(xiàng)目號2020Z2135)


Preparation of ytterbium-copper and ytterbium-copper-aluminum amorphous films by magnetron co-sputtering
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Baotou Rare Earth Research Institute,State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization

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    摘要:

    稀土基非晶合金是金屬玻璃的重要成員,但由于稀土元素高的活性和金屬玻璃苛刻的制備要求導(dǎo)致相關(guān)研究進(jìn)展緩慢,目前新體系非晶合金的制備仍然采用試錯的原始方法。本文基于高通量材料基因工程,通過傾斜靶和調(diào)控單金屬靶功率制備了化學(xué)組成連續(xù)變化的鐿-銅(Yb-Cu)非晶合金金屬薄膜,從而快速篩選出非晶形成范圍,并且成功制備出YbCu非晶合金薄膜,同時研究了鋁對YbCu非晶合金形成的影響,制備了YbCuAl非晶薄膜。當(dāng)Yb小于44.5~46.5 wt%時薄膜全部為非晶態(tài)。AFM結(jié)果表明YbCu非晶合金表面光滑無缺陷,高度絕對差僅為31.6 nm,薄膜呈現(xiàn)疏水性,最大疏水角為119°。YbCu和YbCuAl非晶薄膜最大方阻分別為551 mΩ □-1和1738 mΩ □-1,合金元素Al對YbCu非晶薄膜性能產(chǎn)生了顯著影響。YbCu(Al)非晶薄膜的成分篩選和制備加快了稀土基非晶新材料的開發(fā)。

    Abstract:

    Amorphous alloy is a new type of multicomponent alloy material which is different from common metal materials, in which rare earth-based amorphous alloy is an important member of metallic glass family. However, due to the high activity of rare earth elements and stringent preparation requirements of metallic glass, the related research progress is slow, and the research of new system amorphous alloy still adopts a large number of original methods of trial and error. In this paper, based on the concept of high-throughput material genetic engineering, metal thin films with continuous change of chemical composition were prepared by tilting target and adjusting single metal target power, so as to quickly screen the composition range of YbCu amorphous alloy, and successfully prepared YbCu amorphous alloy film for the first time. At the same time, the influence of aluminum on the formation of YbCu amorphous alloy was studied and prepared YbCuAl amorphous films were prepared. When the Yb is less than 44.5-46.5 wt%, the films are all amorphous. The results show that the surface of YbCu amorphous alloy is smooth without defects, and the absolute height difference is only 31.6 nm. The film is hydrophobic with a maximum hydrophobic angle of 119 °. In addition, the maximum square resistance of YbCu and YbCuAl amorphous films is 551 mΩ □-1 and 1738 mΩ □-1, respectively. The alloying element Al has a significant effect on the properties of YbCu amorphous films. Therefore, the composition screening and successful preparation of YbCu(Al) amorphous films accelerate the development of rare earth based amorphous materials.

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崔紅兵.磁控共濺射制備鐿銅及鐿銅鋁非晶合金薄膜[J].稀有金屬材料與工程,2022,51(3):1040~1046.[CUI Hong-bing. Preparation of ytterbium-copper and ytterbium-copper-aluminum amorphous films by magnetron co-sputtering[J]. Rare Metal Materials and Engineering,2022,51(3):1040~1046.]
DOI:10.12442/j. issn.1002-185X.20210138

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  • 收稿日期:2021-02-19
  • 最后修改日期:2021-04-29
  • 錄用日期:2021-05-12
  • 在線發(fā)布日期: 2022-04-06
  • 出版日期: 2022-03-30