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濺射功率和氣壓對直流磁控濺射制備鎢薄膜的影響
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1北京理工大學材料學院

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The influence of sputtering power and gas pressure on the preparation of tungsten films by DC magnetron sputtering
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1.School of Materials Science and Engineering,Beijing Institute of Technology

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    摘要:

    鎢薄膜具有高熔點、高導電性、優(yōu)異的耐化學腐蝕性和強抗輻照性等特性,廣泛的應用于微電子、核能工程等領域。由于薄膜的結構和性能對沉積參數(shù)具有很強的依賴性,因此控制沉積過程的工藝參數(shù)對獲得優(yōu)異性能的鎢薄膜至關重要。采用DC磁控濺射技術在硅襯底上制備鎢薄膜,探究了濺射功率和氣壓對鎢薄膜沉積速率、電阻率和相結構的影響。采用原子力顯微鏡、XRD、輪廓儀、四探針電阻測量表征了薄膜的微觀結構和電學性能。結果表明,薄膜的沉積速率受濺射功率和氣壓共同影響,隨功率的增加呈線性增加,隨濺射氣壓的增加先達到峰值,然后下降。薄膜的電阻率和表面粗糙度的大小依賴于濺射氣壓,且隨濺射氣壓的增加而增加,薄膜電阻率的增加可能是由于表面粗糙度的增加導致的。在恒定的濺射功率下,β-W的形成主要取決于濺射氣壓,幾乎所有β-W相都在高濺射氣壓下形成,然而,當濺射功率足夠大,在較高的氣壓下也會觀察到部分α-W相的形成。鎢薄膜中特定相結構(α-W/β-W)的形成,不僅取決于沉積氣壓,還與濺射功率相關,歸根可能與入射到基片的原子能量相關。

    Abstract:

    Tungsten films have excellent characteristics such as high melting point, high conductivity,stable chemical properties, and strong radiation resistance, and are widely used in microelectronics, nuclear energy engineering and other fields. Since the structure and performance of the film have a strong dependence on the deposition parameters, it is essential to control the process parameters of the deposition process to obtain a tungsten film with excellent properties. This paper studies the effects of sputtering power and sputtering pressure on the deposition rate, microstructure, and phase structure of tungsten films. Using DC magnetron sputtering technology, a tungsten film is prepared on a Si substrate at room temperature. Atomic force microscope, XRD, four-probe resistance measurement, profiler, etc. were used to characterize the structure and electrical properties of the film. The results show that the deposition rate of the film is affected by the sputtering power and the gas pressure. The deposition rate increases linearly with the increase of the power, and first increases to a peak and then decreases with the increase of the gas pressure. The resistivity and surface roughness of the film depend on the sputtering pressure, and increase with the increase of the sputtering pressure. The increase in the resistivity of the film may be caused by the increase in the surface roughness. Under constant sputtering power, the formation of α-W mainly depends on the sputtering gas pressure. All β-W phases are formed under high pressure, but for the sputtering power is large enough, under higher pressure, the formation of some α-W phases will also be observed. The formation of the specific phase structure (α-W/β-W) in the tungsten film is not only dependent on the deposition pressure, but also related to the sputtering power, which may be related to the energy of the atoms incident on the substrate.

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邢曉帥,劉影夏,于曉東,趙修臣,聶志華,譚成文.濺射功率和氣壓對直流磁控濺射制備鎢薄膜的影響[J].稀有金屬材料與工程,2022,51(2):682~688.[Xing Xiaoshuai, Liu Yingxia, Yu Xiaodong, Zhao Xiuchen, Nie Zhihua, Tan Chengwen. The influence of sputtering power and gas pressure on the preparation of tungsten films by DC magnetron sputtering[J]. Rare Metal Materials and Engineering,2022,51(2):682~688.]
DOI:10.12442/j. issn.1002-185X.20210135

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  • 收稿日期:2021-02-19
  • 最后修改日期:2021-03-25
  • 錄用日期:2021-04-16
  • 在線發(fā)布日期: 2022-03-09
  • 出版日期: 2022-02-28