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Ti20Zr20Hf20Cu20Be20高熵非晶合金應力弛豫行為研究
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中國礦業(yè)大學

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江蘇省自然科學基金項目(BK20180659);中央高?;究蒲袠I(yè)務(wù)費專項資金(2018QNA05);江蘇省雙創(chuàng)團隊、雙創(chuàng)博士項目


Mode Stress Relaxation of Ti20Zr20Hf20Cu20Be20 High-Entropy Metallic Glasses
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School of Materials Science and Physics,China University of Mining and Technology,Xuzhou

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Natural Science Foundation of Jiangsu Province (BK20180659);Fundamental Research Funds for the Central Universities (Grant No. 2018QNA05); Program for High-Level Entrepreneurial and Innovative Talents Group in Jiangsu Province; the Program for Doctor of Entrepreneurial and Innovative Talents in Jiangsu Province

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    摘要:

    高熵非晶合金力學弛豫行為的研究,對于理解玻璃轉(zhuǎn)變、塑性變形、弛豫機理等科學問題和拓展其工程應用極為關(guān)鍵。本文采用應力分析方法對Ti20Zr20Hf20Cu20Be20高熵非晶合金條帶進行了研究,旨在揭示高熵非晶合金應力弛豫行為。通過分析其在恒定應變下較寬時間窗口和溫度窗口內(nèi)的應力衰減過程,發(fā)現(xiàn)在低于Tg的玻璃態(tài)下,高熵非晶合金中存在著弛豫解耦現(xiàn)象,分別是慢弛豫和快弛豫過程。其中慢弛豫呈現(xiàn)擴展指數(shù)衰減模式,弛豫時間存在對溫度的Arrhenius動力學依賴關(guān)系,與長程原子重排運動有關(guān),快弛豫過程對應于微觀局部內(nèi)應力的逐步消散過程。不論該高熵非晶合金變形處于彈性階段還是發(fā)生了屈服,應力弛豫過程受應變的影響都較小。本研究揭示了高熵非晶合金中新的弛豫解耦現(xiàn)象和與之相關(guān)的獨特動力學機制,拓寬了我們對高熵非晶合金弛豫動力學過程以及其本征特性的認知。

    Abstract:

    Mechanical relaxation behavior of high-entropy metallic glasses is not only crucial for understanding the glass transition phenomenon, plastic deformation and relaxation mechanism but also help for extending their application in engineering. The mechanical relaxation behavior of Ti20Zr20Hf20Cu20Be20 high-entropy metallic glass (HE-MG) was investigated by static stress relaxation analysis in the current research. With a constant strain, the stress relaxation process was analyzed in a wide time window and temperature range. A decoupling of the relaxation into a two-step (slow relaxation and fast relaxation) was found in the glass state below Tg. The slow relaxation process exhibits a stretched decay and a significant Arrhenius dependence on the temperature. The relaxation time decreases sharply with the increase of temperature, which may relate to the long-range atomic rearrangements at larger scales. The fast relaxation relates to the atomic scale internal stress dissipation. In addition, the strain has no distinct influence on the stress relaxation process, whether high-entropy metallic glass is deformed at the elastic stage or yields. This study reveals the decoupling phenomenon and the related unique dynamics relaxation mechanism in high-entropy metallic glass, which will enhance our understanding of the mechanical relaxation behavior and intrinsic characteristics of high-entropy metallic glasses.

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陳長玖,許銳,張金勇,張平,何業(yè)増,沈?qū)汖? Ti20Zr20Hf20Cu20Be20高熵非晶合金應力弛豫行為研究[J].稀有金屬材料與工程,2021,50(12):4381~4387.[Chen Changjiu, Xu Rui, Zhang Jinyong, Zhang Ping, He Yezeng, Shen Baolong. Mode Stress Relaxation of Ti20Zr20Hf20Cu20Be20 High-Entropy Metallic Glasses[J]. Rare Metal Materials and Engineering,2021,50(12):4381~4387.]
DOI:10.12442/j. issn.1002-185X.20200949

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  • 收稿日期:2020-12-10
  • 最后修改日期:2021-03-08
  • 錄用日期:2021-04-15
  • 在線發(fā)布日期: 2022-01-09
  • 出版日期: 2021-12-24