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CrMn0.3FeVCu0.06高熵合金的微觀組織及抗輻照性能研究
作者:
作者單位:

1.北京機電工程總體設(shè)計部;2.北礦檢測技術(shù)有限公司

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基金項目:

國家高技術(shù)研究發(fā)展計劃(863計劃)


Microstructure and Irradiation Properties of CrMn0.3FeVCu0.06 High Entropy Alloy
Author:
Affiliation:

1.Beijing System Design Institute of Electro Mechanic Engineering;2.Bgrimm MTC Technology Co,Ltd

Fund Project:

The National High Technology Research and Development Program of China (863 Program)

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    摘要:

    本文采用粉末冶金技術(shù)制備了CrMn0.3FeVCu0.06高熵合金合金,并系統(tǒng)研究了合金的微觀組織、力學(xué)性能及抗輻照性能,結(jié)果表明,采用粉末冶金制備的CrMn0.3FeVCu0.06合金由BCC結(jié)構(gòu)的固溶體基體和FCC結(jié)構(gòu)的第二相顆粒組成,且由于合金的晶粒尺寸和第二相顆粒的尺寸較小,晶界強化和彌散強化效應(yīng)有效地提高了合金的強度和硬度,此外,由于第二相顆粒為FCC軟相,顆粒起到彌散強化的同時又不會嚴重降低合金的塑性,因此,CrMn0.3FeVCu0.06合金同時具備高強度和優(yōu)異的塑韌性。CrMn0.3FeVCu0.06合金的D等離子體輻照試驗表明,在500 K、40 eV、1×1022 m-2s-1的輻照條件下,合金內(nèi)部產(chǎn)生輻照氣泡需要的臨界輻照劑量Φcr大于2.0×1025 m-2,遠大于同等輻照條件下在多晶鎢中產(chǎn)生氣泡的臨界劑量,合金的抗輻照鼓泡性能優(yōu)于傳統(tǒng)的多晶鎢,且隨著輻照劑量的增大,合金表面的輻照氣泡尺寸逐漸增大。此外,合金的納米壓痕測試結(jié)果表明,輻照溫度和劑量對合金輻照硬化效應(yīng)的作用是相反的,合金的硬度隨著劑量的增大而升高,隨溫度的升高而降低,且由于CrMn0.3FeVCu0.06高熵合金中存在嚴重的晶格畸變和遲滯擴散效應(yīng),合金的輻照硬化效應(yīng)對溫度變化更敏感。

    Abstract:

    In this paper, a CrMn0.3FeVCu0.06 high entropy alloy was prepared by powder metallurgy technology. X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to characterize the phase formation and microstructure of the milled powders and sintered bulk CrMn0.3FeVCu0.06 HEA. It was found that the sintered bulk CrMn0.3FeVCu0.06 high-entropy alloy exhibits a dual-phase structure of BCC structured matrix and FCC particles. The bulk CrMnFeVTi HEA exhibits high values of compressive strength and ductility due to grain boundary strengthening and precipitate strengthening. In addition, effects of fluence and temperature on surface morphology and mechanical properties of the CrMn0.3FeVCu0.06 alloy, irradiated by low energy high flux deuterium(D) plasma beams, were systematically investigated. When irradiation conditions were set as 500 K, 40 eV and 1×1022 m-2s-1, the critical fluence for blistering in the CrMn0.3FeVCu0.06 alloy is higher than 2.0×1025 m-2, which is much larger than the critical fluence in polycrystalline tungsten with similar irradiation conditions. It can been seen that the CrMn0.3FeVCu0.06 alloy has better irradiation resistance than polycrystalline tungsten in terms of D retention or inhibiting blister formation. The hardness of the alloy gradually increases with the increase of deuterium fluence, but decreases with increasing irradiation temperature. Due to severe lattice-distortion and sluggish diffusion effects HEA, the irradiation hardening in CrMn0.3FeVCu0.06 HEA is more sensitive to the change of irradiation temperature.

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宋若康,張琳. CrMn0.3FeVCu0.06高熵合金的微觀組織及抗輻照性能研究[J].稀有金屬材料與工程,2021,50(11):4141~4148.[Ruokang Song, Lin Zhang. Microstructure and Irradiation Properties of CrMn0.3FeVCu0.06 High Entropy Alloy[J]. Rare Metal Materials and Engineering,2021,50(11):4141~4148.]
DOI:10.12442/j. issn.1002-185X.20200929

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  • 收稿日期:2020-12-01
  • 最后修改日期:2020-12-26
  • 錄用日期:2021-02-04
  • 在線發(fā)布日期: 2021-11-30
  • 出版日期: 2021-11-24