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Ni–xCr粘結(jié)劑對(duì)Ti(C,N)基金屬陶瓷顯微組織和力學(xué)性能的影響
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華中科技大學(xué) 材料科學(xué)與工程學(xué)院

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TG148

基金項(xiàng)目:

湖北省技術(shù)創(chuàng)新專項(xiàng)重大項(xiàng)目(2016AAA067),華中科技大學(xué)實(shí)驗(yàn)技術(shù)項(xiàng)目


Effect of Ni–xCr binders on microstructure and mechanical properties of Ti(C,N)-based cermets
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1.State Key Lab of Materials Formation and Dies Moulds Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology;2.State Key Lab of Materials Formation and Dies Moulds Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology

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    摘要:

    采用粉末冶金工藝制備了Ni–xCr(wt%,x=0、10、20、30)粘結(jié)劑含量為18wt%和38wt%的Ti(C,N)基金屬陶瓷,以研究Ni–xCr粘結(jié)劑成分及含量對(duì)Ti(C,N)基金屬陶瓷顯微組織和力學(xué)性能的影響。除Ni–30Cr粘結(jié)劑含量為38wt%的金屬陶瓷外,在其它金屬陶瓷中僅觀察到了Ni基粘結(jié)相和Ti基碳氮化物陶瓷晶粒,而未觀察到高M(jìn)o高Cr白色組織。粘結(jié)劑中含Cr時(shí),陶瓷晶粒的黑芯中易出現(xiàn)非常細(xì)小的白色顆粒,特別是粘結(jié)劑含量為38wt%時(shí),黑芯中通常出現(xiàn)大量的白色顆粒;并且,粘結(jié)劑中Cr含量高時(shí),陶瓷晶粒的灰色外環(huán)明顯變厚。不管粘結(jié)劑含量高低,金屬陶瓷的硬度隨著粘結(jié)劑中Cr含量增加而增加,且粘結(jié)劑含量為38wt%時(shí)增幅更明顯。金屬陶瓷的橫向斷裂強(qiáng)度和斷裂韌性在粘結(jié)劑含量為18wt%時(shí)隨著粘結(jié)劑中Cr含量增加而下降,而在粘結(jié)劑含量為38wt%時(shí)隨著粘結(jié)劑中Cr含量增加先增加后下降,以Ni–10Cr作粘結(jié)劑時(shí)達(dá)到峰值。陶瓷晶粒細(xì)化致使沿晶斷裂幾率增加而穿晶斷裂幾率下降;通過(guò)陶瓷晶粒細(xì)化、裂紋偏轉(zhuǎn)、裂紋橋聯(lián)和誘發(fā)微裂紋等機(jī)制的協(xié)同作用,可顯著提高Ti(C,N)基金屬陶瓷的橫向斷裂強(qiáng)度和斷裂韌性。

    Abstract:

    Ti(C,N)-based cermets containing 18 wt% and 38 wt% Ni–xCr (wt%, x=0, 10, 20, 30) were prepared by powder metallurgy, in order to study the effect of the composition and content of Ni–xCr binders on microstructure and mechanical properties of Ti(C,N)-based cermets. Ni-based binder phase and Ti-based carbonitride ceramic grains were observed in the other cermets, except that high-Mo and high-Cr white microstructure was also observed in cermet containing 38 wt% Ni–30Cr binder. There were often very fine white speckles in black core of ceramic grains for cermets with Cr-containing binder, especially at 38 wt% binder, and grey outer rim of ceramic grains became thicker when Cr content was high in binders. Regardless of binder content, hardness of cermets increased with increasing Cr content in binders, and the increase in hardness was more obvious at 38 wt% binder. At 18 wt% binder, transverse rupture strength and fracture toughness of cermets decreased with increasing Cr content in binders, however, at 38 wt% binder, they increased and then decreased with increasing Cr content in binders, and reached the peak at Ni–10Cr binder. Ceramic grain refinement led to the increase in the probability of intergranular fracture, and the synergistic effect of ceramic grain refinement, crack deflection, crack bridging, micro-crack toughening, etc., significantly improved transverse rupture strength and fracture toughness of Ti(C,N)-based cermets.

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引用本文

楊青青,熊惟皓. Ni–xCr粘結(jié)劑對(duì)Ti(C, N)基金屬陶瓷顯微組織和力學(xué)性能的影響[J].稀有金屬材料與工程,2021,50(10):3751~3756.[Yang Qingqing, Xiong Weihao. Effect of Ni–xCr binders on microstructure and mechanical properties of Ti(C, N)-based cermets[J]. Rare Metal Materials and Engineering,2021,50(10):3751~3756.]
DOI:10.12442/j. issn.1002-185X.20200837

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  • 收稿日期:2020-10-30
  • 最后修改日期:2020-11-17
  • 錄用日期:2020-11-30
  • 在線發(fā)布日期: 2021-10-28
  • 出版日期: 2021-10-25