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Nb42Ti21Co37包共晶合金定向凝固組織演化規(guī)律研究
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桂林電子科技大學

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國家自然科學(51761009和51701048)、廣西自然科學(2020GXNSFAA159163)、桂林電子科技大學研究生教育創(chuàng)新計劃項目(2019YCXS109)和廣西信息材料重點實驗室(191021-Z)資助


Evolution law of directional solidification structure of Nb42Ti21Co37 ternary quasiperitectic alloy
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    摘要:

    包共晶轉(zhuǎn)變兼具共晶轉(zhuǎn)變和包晶轉(zhuǎn)變雙重特征,存在于眾多的工業(yè)合金中。然而,迄今為止尚未建立起相對完整的包共晶凝固理論模型,關(guān)于其凝固機理的相關(guān)研究較少?;诖?本文針對Nb42Ti21Co37包共晶合金開展了不同抽拉速度(V=1, 3, 5, 15, 30, 70 μm/s)下的定向凝固實驗,旨在研究不同抽拉速度下合金的微觀組織演化規(guī)律,并構(gòu)建相應的凝固機制。研究結(jié)果表明:Nb42Ti21Co37包共晶合金常規(guī)鑄態(tài)和定向凝固組織中均含有α-Nb、Co6Nb7和TiCo+Co6Nb7包共晶相,隨著抽拉速率的逐漸增加,初生相α-Nb依次經(jīng)歷了圓球狀→花瓣狀→團簇狀→枝晶狀的轉(zhuǎn)變;伴隨著上述過程,淬火界面經(jīng)歷了胞狀界面到胞枝晶狀界面的轉(zhuǎn)變,并且,在抽拉速率V=70 μm/s時固/液界面消失;其次,定向凝固穩(wěn)態(tài)生長區(qū)內(nèi)包共晶的組織逐漸細化,其層間距與生長速率呈指數(shù)線性關(guān)系,即λ=-1+5×e2.5;當抽拉速率低于5μm/s時,合金的定向凝固過程與平衡凝固相類似;另外,各相在穩(wěn)定生長區(qū)的生長機制為共生生長,隨著抽拉速率的增加,包共晶組織的定向排列性逐漸變差。

    Abstract:

    The quasiperitecticcoated transformation has the dual characteristics of eutectic transformation and peritectic transformation, and it exists in many industrial alloys. However, a relatively complete theoretical model of peritectic solidification has not been established so far, and there are few related studies on its solidification mechanism. Based on this, this article carried out directional solidification experiments at different drawing speeds (v=1, 3, 5, 15, 30, 70 μm/s) for the Nb42Ti21Co37 quasiperitectic alloy, aiming to study the alloy"s performance at different drawing speeds. Microstructure evolution law, and build the corresponding solidification mechanism. The research results show that the conventional as-cast and directional solidification structures of Nb42Ti21Co37 quasiperitectic alloy contain α-Nb,Co6Nb7 and TiCo+Co6Nb7 quasiperitectic phases. With the gradual increase of the drawing rate, the primary α-Nb phase undergoes a spherical shape →petal-like →cluster-like →dendrite-like transformation; along with the above process, the quenched interface has undergone the transformation from cellular interface to cellular dendrite-like interface, and at the pulling rate v=70 μm/s, solid/liquid The interface disappears; secondly, the quasiperitectic structure in the steady-state growth zone of directional solidification is gradually refined, and the interlayer spacing has an exponential linear relationship with the growth rate, that is, λ=1+5×e2.5V;when the pulling rate is lower than 5μm/s the directional solidification process of the alloy is similar to equilibrium solidification; in addition, the growth mechanism of each phase in the stable growth zone is symbiotic growth. With the increase of the pulling rate, the directional arrangement of the quasiperitectic structure gradually deteriorates.

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王金華,閆二虎,狄翀博,陳運燦,劉威,王豪,葛曉宇,程健,黃仁君,孫立賢. Nb42Ti21Co37包共晶合金定向凝固組織演化規(guī)律研究[J].稀有金屬材料與工程,2021,50(10):3577~3584.[Wang Jinhua,閆二虎,Di Chongbo, Chen Yuncan, Liu Wei, Wang Hao, Ge Xiaoyu, Cheng Jian, Huang Renjun, Sun Lixian. Evolution law of directional solidification structure of Nb42Ti21Co37 ternary quasiperitectic alloy[J]. Rare Metal Materials and Engineering,2021,50(10):3577~3584.]
DOI:10.12442/j. issn.1002-185X.20200786

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  • 收稿日期:2020-10-12
  • 最后修改日期:2020-12-11
  • 錄用日期:2020-12-22
  • 在線發(fā)布日期: 2021-10-28
  • 出版日期: 2021-10-25