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等離子燒結(jié)溫度對(duì)CoCrCuFeNi高熵合金組織及性能影響
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1.東北大學(xué);2.西北有色金屬研究院;3.西安石油大學(xué);4.西安科技大學(xué);5.西安稀有金屬材料研究院有限公司

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國(guó)家自然科學(xué)基金資助(51901192),陜西省重點(diǎn)研發(fā)計(jì)劃(2019GY-164)


Spark Plasma Sintering Effect on Microstructure and Properties of CoCrCuFeNi High Entropy Alloy
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1.School of Materials Science and Engineering,Northeastern University;2.Northwest Institute for Nonferrous Metal Research,Xi’an

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    摘要:

    本文通過(guò)氬氣霧化制備CoCrCuFeNi球形粉末,隨后在900℃、1000℃、1100℃、1150℃溫度下通過(guò)放電等離子活化燒結(jié)(Spark plasma sintering,SPS),成功制備CoCrCuFeNi高熵合金塊體。結(jié)果表明:隨著燒結(jié)溫度的升高,材料室溫抗拉強(qiáng)度先降低后升高,均勻卻延伸率先大幅度提高,隨后降低;當(dāng)燒結(jié)溫度為1100℃時(shí),材料屈服強(qiáng)度和抗拉強(qiáng)度分別達(dá)到379.3MPa和655.6MPa,斷后延伸率達(dá)21.9%;當(dāng)燒結(jié)溫度超過(guò)1100℃時(shí),開(kāi)始出現(xiàn)局部熔化現(xiàn)象,材料內(nèi)部出現(xiàn)元素明顯偏析現(xiàn)象。燒結(jié)溫度為900℃時(shí),拉伸斷口沿球形粉末表面脆性斷裂,隨著燒結(jié)溫度提高,斷口轉(zhuǎn)變?yōu)榘g窩的韌性斷裂。由于高溫?zé)Y(jié)過(guò)程中基體內(nèi)發(fā)生滲碳現(xiàn)象,透射電鏡結(jié)果表明碳與基體發(fā)生反應(yīng),形成第二相碳化物。

    Abstract:

    In this paper, CoCrCuFeNi high-entropy alloy was successfully fabricated by spark plasma sintering (SPS) at 900 oC, 1000 oC, 1100 oC and 1150 oC. The tensile at room temperature results shows that the tensile strength of the CoCrCuFeNi alloy firstly decreases and then increase with the increase of sintering temperature. However, the uniform elongation firstly significantly increases and then decreases. When the sintering was carried out at 1100 oC, the yield strength and unltimate tensile strength of CoCrCuFeNi alloy reaches 379.3 MPa and 655.6 MPa, respectively, and the elongation after fracture is 21.9%. When sintering temperature above 1100 oC, the element segregation obviously appears in the material because of the local melting. Besides, the tensile fracture is brittle feature along the surface of the spherical powder at 900℃. While the fracture is a ductile fracture as the sintering temperature increases. Because of the diffusion of carbon atom during high temperature sintering, TEM results show that the carbon reacts with the matrix to form second phase carbide particles inside the matrix.

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夏洪勇,董龍龍,霍望圖,田寧,周悅,趙盤巢,周廉,張于勝.等離子燒結(jié)溫度對(duì)CoCrCuFeNi高熵合金組織及性能影響[J].稀有金屬材料與工程,2021,50(9):3327~3334.[Xia Hongyong, Dong Longlong, Huo Wangtu, Tian Ning, Zhou Yue, Zhao Panchao, Zhou Lian, Zhang Yusheng. Spark Plasma Sintering Effect on Microstructure and Properties of CoCrCuFeNi High Entropy Alloy[J]. Rare Metal Materials and Engineering,2021,50(9):3327~3334.]
DOI:10.12442/j. issn.1002-185X.20200780

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  • 收稿日期:2020-10-10
  • 最后修改日期:2020-12-18
  • 錄用日期:2020-12-22
  • 在線發(fā)布日期: 2021-09-27
  • 出版日期: 2021-09-24