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基于掃描Kelvin探針和FT-IR的7B04鋁合金/涂層體系絲狀腐蝕研究
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海軍航空大學青島校區(qū)

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中國博士后科學基金(項目號2019M653929)和山東省高等學校“青創(chuàng)科技計劃”資助項目(項目號2020KJA014)資助


Investigation of filiform corrosion of coated 7B04 aluminum alloy by scanning Kelvin probe and FTIR
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Naval Aviation University Qingdao Campus

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    摘要:

    對7B04鋁合金進行硫酸或鉻酸陽極氧化后再噴涂底漆或底漆+面漆,從而制備四類試樣,而后開展標準絲狀腐蝕試驗,利用掃描 Kelvin 探針(SKP)和傅里葉變換紅外光譜(FT-IR)技術對7B04鋁合金/涂層體系的腐蝕行為和機理進行研究。光學顯微鏡觀察發(fā)現(xiàn)四類試樣上腐蝕絲的數(shù)量較少,且長度不超過3 mm,表明四類試樣均具有較好的耐蝕性。SKP測試結(jié)果表明,四類試樣跨劃痕區(qū)域的伏打電位隨試驗時間的變化規(guī)律相似,劃痕處與周圍的涂層-金屬界面之間的電位差引起絲狀腐蝕的發(fā)生,腐蝕機理為陽極破壞;單個腐蝕絲的伏打電位值朝著頭部降低,朝著尾部升高,頭部和尾部之間的電位差促進腐蝕絲的傳播。FT-IR分析顯示絲狀腐蝕產(chǎn)物的成分主要為Al(OH)3 、Al2O3和AlCl3及其部分水解產(chǎn)物,發(fā)生的電化學反應類似于7B04鋁合金在氯離子作用下的點蝕過程。對比分析結(jié)果表明兩種陽極氧化方式對絲狀腐蝕的影響差異性較小。

    Abstract:

    Four types of samples were obtained by anodizing 7B04 aluminum alloy with sulfuric acid or chromic acid and then spraying primer or primer and topcoat. Then a standard filiform corrosion test was carried out and the corrosion behavior and mechanism of 7B04 aluminum alloy/coating systems were investigated by scanning Kelvin probe and Fourier transform infrared spectroscopy (FT-IR). Optical microscope observations reveal that the number of filaments on the four types of samples is small, and the length is no more than 3 mm, indicating that the four types of specimens all have good corrosion resistance. The results of SKP tests show that the variation of Volta potential of the scribe mark and adjacent area with the test time is similar among the four kinds of samples. The potential difference between the scribe mark and the adjacent coating-metal interface causes the occurrence of filiform corrosion, and the corrosion mechanism is anodic undermining. The Volta potential of a single filament decreases towards the head and increased towards the tail, and the potential difference between the head and the tail promotes the propagation of the filament. The results of FT-IR show that the main components of corrosion products at the scribe mark and under the filament are Al(OH)3, Al2O3, AlCl3,and its partially hydrolyzed products. The main chemical reactions in the filiform corrosion are similar to the pitting corrosion of 7B04 aluminum alloy under the erosion of chloride ion. Comparative analysis shows that the influence of two anodic oxidation modes on filiform corrosion is less different

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張楊廣,陳躍良,張勇,卞貴學,李軍亮,吳省均.基于掃描Kelvin探針和FT-IR的7B04鋁合金/涂層體系絲狀腐蝕研究[J].稀有金屬材料與工程,2021,50(9):3184~3193.[Yangguang Zhang, Yueliang Chen, Yong Zhang, Guixue Bian, Junliang Li, Xingjun Wu. Investigation of filiform corrosion of coated 7B04 aluminum alloy by scanning Kelvin probe and FTIR[J]. Rare Metal Materials and Engineering,2021,50(9):3184~3193.]
DOI:10.12442/j. issn.1002-185X.20200759

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  • 收稿日期:2020-09-29
  • 最后修改日期:2020-10-25
  • 錄用日期:2020-12-14
  • 在線發(fā)布日期: 2021-09-27
  • 出版日期: 2021-09-24