M先降低后升高,最小值200MPa在500 ℃退火后取得;殘余應變εR先升高后降低,最大值2.64%在500 ℃退火后取得。隨時效時間延長,300 ℃時效態(tài)合金的σM降低,εR始終較??;400 ℃和500 ℃時效態(tài)合金的σM降低,εR先升高后趨于穩(wěn)定。隨循環(huán)次數(shù)增加,呈SE的合金由部分非線性SE轉(zhuǎn)變?yōu)橥耆蔷€性SE,且σM和能耗△W先降低后趨于穩(wěn)定;呈SME的合金的σM和△W先降低后趨于穩(wěn)定。"/>

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熱處理和循環(huán)應變對TiNiZr合金形狀記憶行為的影響
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陜西理工大學 材料科學與工程學院

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中圖分類號:

TG113.25

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國家重點研發(fā)計劃項目(2016YFE0111400)


Effect of heat treatment and cyclic strain on shape memory behaviors of TiNiZr alloy
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School of Materials Science and Engineering,Shaanxi University of Technology

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    摘要:

    利用拉伸實驗、光學顯微鏡和透射電鏡研究了退火工藝、時效工藝和循環(huán)應變對Ti-50.8Ni-0.1Zr合金形狀記憶行為的影響。350~400 ℃和600~700 ℃退火態(tài)合金呈超彈性(SE),450~550 ℃退火態(tài)合金呈形狀記憶效應(SME);300 ℃/(1~50 h)和400 ℃/1 h時效態(tài)合金呈SE,400 ℃/(5~50 h)和500 ℃/(1~50 h)時效態(tài)合金呈SME。隨退火溫度升高,合金應力應變曲線平臺應力σM先降低后升高,最小值200MPa在500 ℃退火后取得;殘余應變εR先升高后降低,最大值2.64%在500 ℃退火后取得。隨時效時間延長,300 ℃時效態(tài)合金的σM降低,εR始終較?。?00 ℃和500 ℃時效態(tài)合金的σM降低,εR先升高后趨于穩(wěn)定。隨循環(huán)次數(shù)增加,呈SE的合金由部分非線性SE轉(zhuǎn)變?yōu)橥耆蔷€性SE,且σM和能耗△W先降低后趨于穩(wěn)定;呈SME的合金的σM和△W先降低后趨于穩(wěn)定。

    Abstract:

    The effects of annealing processes, aging processes and cyclic strain on shape memory behaviors of Ti-50.8Ni-0.1Zr alloy were investigated by tensile test, optical microscopy and TEM. The alloys annealed at 350~400 ℃ and 600~700 ℃ present superelasticity (SE), the alloys annealed at 450~550 ℃ present shape memory effect (SME), the alloys aged at 300 ℃ for 1~50 h and at 400 ℃ for 1 h present SE, and the alloys aged at 400 ℃ for 5~50 h and 500 ℃ for 1~50 h present SME. With increasing annealing temperature, the platform stress (σM) of the stress-strain curve in the alloy decreases firstly and then increases, and the minimum 200 MPa obtained in the alloy annealed at 500 ℃; the residual strain (εR) increases firstly and then decreases, and the maximum 2.64% obtained in the alloy annealed at 500 ℃. With increasing aging time, the σM decreases, and the εR is small in the alloy aged at 300 ℃; the σM decreases, and the εR increases firstly and then tends to stable in the alloy aged at 400 ℃ and 500 ℃. With increasing stress-strain cycle number, the superelasticity type alloy transforms from incompletely nonlinear superelasticity to completely nonlinear superelasticity, and the σM and energy dissipation (△W) decrease firstly and then tend to stable; the σM and △W decrease firstly and then tend to stable in shape memory effect type alloy.

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賀志榮,葉俊杰,張坤剛,杜雨青.熱處理和循環(huán)應變對TiNiZr合金形狀記憶行為的影響[J].稀有金屬材料與工程,2021,50(8):2941~2949.[HE Zhi-rong, YE Jun-jie, ZHANG Kun-gang, DU Yu-qing. Effect of heat treatment and cyclic strain on shape memory behaviors of TiNiZr alloy[J]. Rare Metal Materials and Engineering,2021,50(8):2941~2949.]
DOI:10.12442/j. issn.1002-185X.20200674

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  • 收稿日期:2020-09-06
  • 最后修改日期:2020-10-10
  • 錄用日期:2020-10-21
  • 在線發(fā)布日期: 2021-09-07
  • 出版日期: 2021-08-31