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SPS制備多級(jí)孔結(jié)構(gòu)鎢骨架壓縮性能及致密化行為研究
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1.西安理工大學(xué);2.長(zhǎng)安大學(xué)

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國(guó)家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Research on the densification behavior and Compression performance of SPS prepared Tungsten skeleton with hierarchical pores structure
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    摘要:

    以粒徑分布為15-106 μm多孔球形團(tuán)聚W粉為原料,采用SPS在不同燒結(jié)溫度(1450℃、1500℃、1550℃),軸向恒壓40Mpa,保溫5min下制備出高強(qiáng)度(347.8±10.6 Mpa(1450℃)、407.4±14.2 Mpa(1500℃)、543.9±8.7 Mpa(1550℃))、多級(jí)孔結(jié)構(gòu)(3-10 μm\200-500 nm)W骨架。結(jié)合XRD、SEM、萬(wàn)能試驗(yàn)機(jī)等檢測(cè)技術(shù),對(duì)SPS燒結(jié)過(guò)程中粉末致密化行為、顯微組織變化及力學(xué)性能進(jìn)行了系統(tǒng)研究。結(jié)果表明: SPS可制得燒結(jié)前后物相無(wú)明顯變化、孔隙率介于30%-40%、燒結(jié)頸發(fā)育完全多級(jí)孔結(jié)構(gòu)鎢骨架。該多級(jí)孔W骨架SPS燒結(jié)致密化過(guò)程可分為4個(gè)階段,第一階段為升壓階段,燒結(jié)試樣相對(duì)密度隨壓力升高而迅速升高;第二階段為典型的顆粒重排階段;第三階段燒結(jié)溫度高于1000℃,燒結(jié)試樣相對(duì)密度隨溫度的升高而升高,屬于典型的燒結(jié)中期;第四階段為燒結(jié)末期,燒結(jié)體內(nèi)部高溫蠕變引起致密化程度進(jìn)一步提高。利用高溫蠕變模型研究了該多孔球形W粉的致密化機(jī)理為純擴(kuò)散致密化,通過(guò)頸長(zhǎng)方程確定該多孔球形鎢粉在整個(gè)SPS燒結(jié)過(guò)程中的致密化機(jī)理是以體積擴(kuò)散為主,晶界擴(kuò)散為輔。

    Abstract:

    W skeleton with high strength (347.8±10.6 Mpa(1450℃), 407.4±14.2 Mpa(1500℃), 543.9±8.7 Mpa(1550℃) and hierarchical pores structure (3-10 m\200-500 nm) was prepared by SPS at different sintering temperatures (1450℃, 1500℃, 1550℃) and at axial constant pressure (40Mpa) for 5 minutes by using the particle size distribution of 15-106 m porous spherical agglomerate W powder as raw material. The densification behavior, microstructure changes and mechanical properties of SPS sintering process were systematically studied by XRD、SEM and universal testing machine. The results show that SPS can produce W skeleton have developed sintered neck and hierarchical pores structure with no significant change in phase before and after sintering and porosity of 30%-40%. The sintering densification process of W skeleton with hierarchical pores structure by SPS can be divided into four stages: the first stage is the pressure increase stage, the relative density of sintered sample increases rapidly with the increase of pressure; the second stage is a typical particle rearrangement stage; the third stage is a typical sintering metaphase, the relative density of sintered sample increases with the increase of temperature, when temperature higher than 1000℃; the fourth stage is the end of sintering, and the densification degree is further improved due to high temperature creep inside the sintered body. The densification mechanism of the porous spherical W powder was determined as Pure diffusion densification by using the high temperature creep model, and further determined volume diffusion as the main mechanism and grain boundary diffusion as the auxiliary mechanism by the neck length equation.

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楊鑫,王犇,谷文萍,張兆洋,劉剛,梁淑華. SPS制備多級(jí)孔結(jié)構(gòu)鎢骨架壓縮性能及致密化行為研究[J].稀有金屬材料與工程,2021,50(8):2913~2920.[yang xin, wang ben, gu wenping, zhang zhaoyang, liu gang, liang shuhua. Research on the densification behavior and Compression performance of SPS prepared Tungsten skeleton with hierarchical pores structure[J]. Rare Metal Materials and Engineering,2021,50(8):2913~2920.]
DOI:10.12442/j. issn.1002-185X.20200662

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歷史
  • 收稿日期:2020-09-01
  • 最后修改日期:2020-09-24
  • 錄用日期:2020-10-21
  • 在線(xiàn)發(fā)布日期: 2021-09-07
  • 出版日期: 2021-08-31