1200°C高溫蒸汽腐蝕條件下能夠有效保護(hù)鋯合金基體,是目前最有希望工程化應(yīng)用的事故容錯(cuò)涂層。同時(shí),探索適合于工程化應(yīng)用的Cr涂層制備技術(shù),解決Cr涂層的制備缺陷,提升涂層的結(jié)構(gòu)致密性以及界面性能是目前亟待解決的關(guān)鍵問題。"/>

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鋯合金耐事故燃料包殼涂層研究進(jìn)展
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作者單位:

1.西安建筑科技大學(xué)冶金工程學(xué)院;2.西北有色金屬研究院;3.中國核動(dòng)力研究設(shè)計(jì)院

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基金項(xiàng)目:

陜西省自然科學(xué)基金,2020JM-649,科技部國際合作項(xiàng)目,2014DFR50450


Research Progress in Zirconium Alloy for Accident Tolerant Fuel Cladding Coating
Author:
Affiliation:

1.School of Metallurgic Engineering,Xi′an University of Architecture and Technology,Xi′an,;2.Northwest Institute for Nonferrous Metal Research,Xi′an;3.Nuclear Power Institute of China,Chengdu

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    摘要:

    日本福島核事故后,以提升反應(yīng)堆在事故工況下的穩(wěn)定性和安全性為目的的事故容錯(cuò)燃料技術(shù)研究已成為世界范圍內(nèi)的研究熱點(diǎn)。涂層技術(shù)是事故容錯(cuò)燃料項(xiàng)目短期規(guī)劃主要的發(fā)展方向。在鋯合金燃料包殼表面制備保護(hù)性涂層能夠在不改變現(xiàn)有燃料體系結(jié)構(gòu)的前提下,提升鋯合金包殼在反應(yīng)堆失水事故條件下的事故容錯(cuò)能力。本文綜述了國內(nèi)外鋯合金包殼涂層領(lǐng)域研究成果,總結(jié)了鋯合金表面涂層的種類、性能、制備技術(shù)及應(yīng)用前景,結(jié)合涂層的制備技術(shù),綜合分析了各種制備方法的特點(diǎn)以及未來需集中要解決的問題。在此基礎(chǔ)上,提出金屬Cr涂層具有良好的耐腐蝕性能,尤其是在>1200°C高溫蒸汽腐蝕條件下能夠有效保護(hù)鋯合金基體,是目前最有希望工程化應(yīng)用的事故容錯(cuò)涂層。同時(shí),探索適合于工程化應(yīng)用的Cr涂層制備技術(shù),解決Cr涂層的制備缺陷,提升涂層的結(jié)構(gòu)致密性以及界面性能是目前亟待解決的關(guān)鍵問題。

    Abstract:

    After the Fukushima nuclear accident in Japan, the world-wide research is focused on the accident tolerant fuel (ATF) program, aimed to enhance the stability and safety of nuclear reactor under normal or off-normal conditions. In the short-term-plan of ATF program, coating technology is considered as a revolutionary approach. Synthesizing a protective coating on the surface of Zr based cladding would improve oxidation resistance obviously with minimal effect on structure of the existing fuel system and properties of the existing nuclear Zr based materials. In this study, a review of coating development status based on Zr alloy is offered, including the coating types, properties and application prospects,also the characteristics of synthesization technology. Based on these analyses, it’s believed that Cr coating could be considered as the best candidate ATF material for industrial application at present, due to its good corrosion resistance at high temperature steam, especially higher than 1200℃. At the same time, it is a key problem to explore a Cr coating synthesization technology suitable for engineering application, with none structure defects, more density and higher interface performance.

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劉家歡,李爭(zhēng)顯,王彥峰,耿娟娟,岳慧芳,高士鑫.鋯合金耐事故燃料包殼涂層研究進(jìn)展[J].稀有金屬材料與工程,2021,50(8):3003~3010.[LIU Jia-huan, Li-Zheng-xian, WANG Yan-feng, GENG Juan-juan, YUE Hui-fang, GAO Shi-xin. Research Progress in Zirconium Alloy for Accident Tolerant Fuel Cladding Coating[J]. Rare Metal Materials and Engineering,2021,50(8):3003~3010.]
DOI:10.12442/j. issn.1002-185X.20200652

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  • 收稿日期:2020-08-31
  • 最后修改日期:2020-10-12
  • 錄用日期:2020-10-21
  • 在線發(fā)布日期: 2021-09-07
  • 出版日期: 2021-08-31