2Zr3相析出,且隨溫度的升高,析出相有增多及粗化趨勢(shì)。在490 ℃固溶8 h后,合金的組織均勻,耐蝕性相對(duì)較好,腐蝕較為均勻,失重腐蝕速率為0.472±0.048 mm/a,抗拉強(qiáng)度、屈服強(qiáng)度及延伸率分別為196.2±3.5 MPa、111.1±6.4 MPa和18.9±1.3%。試驗(yàn)研究了合金腐蝕后的力學(xué)性能,表明:490 ℃×8 h試樣在模擬體液中浸泡后,力學(xué)性能在1-7天內(nèi)急劇下降,7-14天下降較為緩慢,隨浸泡時(shí)間的延長(zhǎng)斷裂形式從準(zhǔn)解理斷裂轉(zhuǎn)變?yōu)榇嘈詳嗔选?/>

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固溶溫度對(duì)Mg-Zn-Gd-Y-Zr生物可降解合金組織及性能影響
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河南科技大學(xué)材料科學(xué)與工程學(xué)院

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中圖分類(lèi)號(hào):

146.2

基金項(xiàng)目:

河南省高校科技創(chuàng)新人才支持計(jì)劃項(xiàng)目(17HASTIT026);國(guó)家自然科學(xué)基金資助項(xiàng)目(U1804146);河南省高等學(xué)校重點(diǎn)科研項(xiàng)目(20A430010)


Effect of solution treatment on microstructure and properties of biodegradable Mg-Zn-Gd-Y-Zr magnesium alloy
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School of Materials Science and Engineering,Henan University of Science and Technology

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    摘要:

    利用OM、SEM、TEM等手段研究了固溶處理對(duì)Mg-Zn-Gd-Y-Zr合金組織的影響,并對(duì)合金的耐腐蝕性能及力學(xué)性能進(jìn)行了測(cè)試。結(jié)果表明:固溶處理有效改善鑄態(tài)合金的組織不均勻性,在460-510 ℃溫度范圍固溶處理后,合金的晶粒尺寸隨溫度升高而逐漸增大,第二相尺寸減小并趨于球形。當(dāng)固溶溫度高于490 ℃時(shí),有少量Zn2Zr3相析出,且隨溫度的升高,析出相有增多及粗化趨勢(shì)。在490 ℃固溶8 h后,合金的組織均勻,耐蝕性相對(duì)較好,腐蝕較為均勻,失重腐蝕速率為0.472±0.048 mm/a,抗拉強(qiáng)度、屈服強(qiáng)度及延伸率分別為196.2±3.5 MPa、111.1±6.4 MPa和18.9±1.3%。試驗(yàn)研究了合金腐蝕后的力學(xué)性能,表明:490 ℃×8 h試樣在模擬體液中浸泡后,力學(xué)性能在1-7天內(nèi)急劇下降,7-14天下降較為緩慢,隨浸泡時(shí)間的延長(zhǎng)斷裂形式從準(zhǔn)解理斷裂轉(zhuǎn)變?yōu)榇嘈詳嗔选?/p>

    Abstract:

    The effect of solution treatment on the microstructure of Mg-Zn-Gf-Y-Zr alloy was studied by OM, SEM and TEM, and the corrosion resistance and mechanical properties of the alloy were tested. The results show that the solution treatment can effectively improve the inhomogeneity structure of the as-cast alloy. The grain size of the alloy increases with the increase of solution treatment temperature in the range of 460-510 ℃, and the second phase dissolves and tends to be spherical. When the solution temperature is greater than 490 ℃, a small amount of Zn2Zr3 phase is precipitated and the precipitation phase tends to increase and coarsening with the increase of temperature. The T4-490 sample exhibits uniform microstructure, good corrosion resistance and mechanical properties. The corrosion rate of the weight loss test is 0.472±0.048mm /a, and the tensile strength, yield strength and elongation were 196.2±3.5 MPa, 111.1±6.4 MPa and 18.9±1.3%, respectively. The tensile properties of T4-490 sample after immersed in SBF decreased sharply within 1-7 days, and decreased more slowly within 7-14 days. With the extension of soaking time, the fracture form changes from quasi cleavage fracture to brittle fracture.

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劉 亞,文九巴,李 歡,姚 懷,賀俊光.固溶溫度對(duì)Mg-Zn-Gd-Y-Zr生物可降解合金組織及性能影響[J].稀有金屬材料與工程,2021,50(8):2850~2858.[Liu Ya, Wen Jiuba, Li Huan, Yao Huai, He Junguang. Effect of solution treatment on microstructure and properties of biodegradable Mg-Zn-Gd-Y-Zr magnesium alloy[J]. Rare Metal Materials and Engineering,2021,50(8):2850~2858.]
DOI:10.12442/j. issn.1002-185X.20200632

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  • 收稿日期:2020-08-24
  • 最后修改日期:2020-09-21
  • 錄用日期:2020-10-15
  • 在線發(fā)布日期: 2021-09-07
  • 出版日期: 2021-08-31