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Mn含量對Mn基Heusler合金磁及磁熱性能影響
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常州大學(xué)材料科學(xué)與工程國家級實驗教學(xué)示范中心

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TB3;TB6;TB34

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國家自然科學(xué)(21978025);江蘇省第三期優(yōu)勢學(xué)科建設(shè)項目(PAPD);江蘇高校品牌專業(yè)建設(shè)工程資助項目(TAPP)。


The effect of Mn concentration on the magnetic and magnetocaloric properties for Mn-based Heusler alloys
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National Experimental Demonstration Center for Materials Science and Engineering,Changzhou University

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    摘要:

    選用Mn基Heusler合金為研究對象。通過電弧熔煉和熱處理制備樣品,并用甩帶法制成薄帶形狀。采用X射線衍射儀和振動樣品磁強計等分析儀器測試了樣品的晶體結(jié)構(gòu)、磁及磁熱性能,分析了Mn含量對材料晶體結(jié)構(gòu)、磁和磁熱性能的影響。研究發(fā)現(xiàn),Mn2-xSn0.5Ga0.5合金在常溫下為六方結(jié)構(gòu),在室溫附近僅發(fā)生一次二階磁性轉(zhuǎn)變,無明顯磁滯和熱滯。居里溫度和飽和磁化強度對Mn含量非常敏感,隨著Mn含量升高,居里溫度和飽和磁化強度均出現(xiàn)下降,由Mn1.2Sn0.5Ga0.5的304 K和64.1 emu/g分別降至Mn2Sn0.5Ga0.5的262 K和46.7 emu/g,這表明合金中的磁矩呈亞鐵磁形態(tài)分布。由于沒有磁滯和熱滯,室溫附近較大的工作溫度區(qū)間,因此,該材料在磁制冷領(lǐng)域具有很好的應(yīng)用前景。

    Abstract:

    Mn-based Heusler alloys were selected as testing materials in this research, and the samples were prepared by arc-melting, subsequent heat treatment, and made in ribbon form by melt-spinning. The effects of Mn concentration on the crystal structures, magnetic and magnetocaloric properties were studied. It was found that Mn2-xSn0.5Ga0.5 crystalized in hexagonal structure at the room temperature. All samples undergo only second order phase transition at their Curie temperature near room temperature with nearly zero hysteresis. The Curie temperature and the saturation magnetization of the Mn2-xSn0.5Ga0.5 are very sensitive to Mn concentration where both Curie temperature and saturation magnetization decrease with the increase of Mn concentration, from 304 K and 64.1 emu/g to 262 K and 46.7 emu/g for Mn1.2Sn0.5Ga0.5 and Mn2Sn0.5Ga0.5, respectively, which indicates the ferrimagnetic order in these materials. Mn-based Heusler alloys will have a large application prospect in the field of magnetic refrigeration because of the absence of hysteresis and thermal hysteresis and with wide operating temperature range near room temperature.

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繆小吉,孫 斐,胡 靜. Mn含量對Mn基Heusler合金磁及磁熱性能影響[J].稀有金屬材料與工程,2021,50(4):1405~1408.[Miao Xiaoji,,Jing Hu. The effect of Mn concentration on the magnetic and magnetocaloric properties for Mn-based Heusler alloys[J]. Rare Metal Materials and Engineering,2021,50(4):1405~1408.]
DOI:10.12442/j. issn.1002-185X.20200374

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  • 收稿日期:2020-05-31
  • 最后修改日期:2020-09-22
  • 錄用日期:2020-10-15
  • 在線發(fā)布日期: 2021-05-08
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