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鋯-鈦-鋼復(fù)合板界面損傷機(jī)理及表面耐腐蝕性能研究
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1.南京市鍋爐壓力容器檢驗(yàn)研究院;2.南京工業(yè)大學(xué)

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國家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Research on Interface Damage mechanism and Surface Corrosion Resistance of Zirconium-Titanium-Steel Clad Plate
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    摘要:

    本文運(yùn)用內(nèi)聚力模型研究了鋯-鈦-鋼復(fù)合板在粘結(jié)試驗(yàn)中的界面損傷過程,并利用掃描電子顯微鏡分析了界面斷裂機(jī)理。運(yùn)用正交試驗(yàn)研究了不同熱處理工藝條件下的表面耐腐蝕性能,分析了保溫溫度、保溫時(shí)間和升降溫速率對粘結(jié)性能的影響。結(jié)果表明,I型裂紋加載下,界面損傷由內(nèi)壁處開始,并逐漸發(fā)展至整個(gè)界面。界面整體屬于脆性斷裂,而波峰與波谷的過渡斜面則為混合斷裂。腐蝕試驗(yàn)的塔菲爾極化曲線研究結(jié)果表明,鋯覆層在HCl溶液中以點(diǎn)腐蝕為主,而在HAc溶液中以均勻腐蝕為主。爆炸焊接后,鋯復(fù)合板的耐點(diǎn)腐蝕性能低于純鋯材料,并且保溫溫度越高,保溫時(shí)間越長,耐腐蝕性能下降越明顯。

    Abstract:

    In this paper, the cohesive zone model is used to study the interface damage process of zirconium-titanium-steel clad plate in bonding test, and the interface fracture mode is analyzed by SEM observation. The corrosion resistance of the surface under different heat treatment conditions was studied by orthogonal test, and the effects of holding temperature, holding time and temperature rise and fall rate were analyzed. The results show that the interface damage starts from the inner wall and gradually develops to the whole interface under mode-I loading. The whole interface belongs to brittle fracture, while the transition slope of wave crest and wave trough is mixed fracture. The results of Tafel polarization curves show that the main corrosion mode of zirconium coating is spot corrosion in HCl solution and uniform corrosion in HAC solution. After explosive welding, the corrosion resistance of zirconium composite plate is lower than that of pure zirconium material, and worse corrosion-proof ability will be .obtained under higher temperature and longer holding time.

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張伯君,業(yè)成,周彬彬,方學(xué)鋒,文耀華,周昌玉.鋯-鈦-鋼復(fù)合板界面損傷機(jī)理及表面耐腐蝕性能研究[J].稀有金屬材料與工程,2021,50(3):1037~1043.[Zhang Bojun, Ye Cheng, Zhou Binbin, Fang Xuefeng, Wen Yaohua, Zhou Changyu. Research on Interface Damage mechanism and Surface Corrosion Resistance of Zirconium-Titanium-Steel Clad Plate[J]. Rare Metal Materials and Engineering,2021,50(3):1037~1043.]
DOI:10.12442/j. issn.1002-185X.20200340

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  • 收稿日期:2020-05-19
  • 最后修改日期:2020-06-22
  • 錄用日期:2020-07-01
  • 在線發(fā)布日期: 2021-04-02
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