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BaZrO3/Y2O3復(fù)合耐火材料制備及其與TiAl合金界面反應(yīng)研究
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上海大學(xué)材料科學(xué)與工程學(xué)院

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)U1760109); 上海大學(xué)省部共建高品質(zhì)特殊鋼冶金與制備國(guó)家重點(diǎn)實(shí)驗(yàn)室自主課題(SKLASS2019-Z019)


Preparation Of BaZrO3/Y2O3 Composite Refractory And Its InteractionWith TiAl Alloy
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State Key Laboratory of Advanced Special Steel Shanghai Key Laboratory of Advanced Ferrometallurgy School of Materials Science and Engineering,Shanghai University

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    摘要:

    本文使用電熔BaZrO3耐火材料和Y2O3耐火材料復(fù)合,在1650℃保溫24h燒制成坩堝,感應(yīng)熔煉制備TiAl合金。通過(guò)X射線衍射儀(XRD)、掃描電子顯微鏡(SEM)結(jié)合能譜儀(EDS)、電感耦合等離子體原子發(fā)射光譜法(ICP-AES)和氧/氮分析儀等手段分析了復(fù)合坩堝耐火材料相結(jié)構(gòu)和顯微結(jié)構(gòu),研究了復(fù)合耐火材料坩堝與TiAl合金熔體界面反應(yīng)。結(jié)果表明,復(fù)合坩堝耐火材料由Zr固溶Y2O3和Y摻雜BaZrO3兩相組成,Y2O3的引入提高了電熔BaZrO3耐火材料穩(wěn)定性。熔解侵蝕作用是復(fù)合坩堝耐火材料與TiAl合金熔體界面作用機(jī)制,但游離Al2O3仍會(huì)與分解的BaO反應(yīng)生成BaAl2O4附著在坩堝內(nèi)壁;熔煉制備TiAl合金錠中氧含量?jī)H為0.0986wt.%, 與理論計(jì)算值相一致,且符合工業(yè)用TiAl合金鑄錠用氧含量標(biāo)準(zhǔn),表明了電熔BaZrO3/Y2O3是一種極有潛力的TiAl合金感應(yīng)熔煉制備用耐火材料。

    Abstract:

    The composite refractory crucible using the fused BaZrO3 and Y2O3 was fabricated after sintering at 1650℃ for 24h, then induction melting of TiAl alloy was carried out in the crucible. By using the X-ray diffraction, scanning electron microscope combined with the energy disperse spectroscopy, inductively coupled plasma atomic emission pectrometry and O/N analyzer, the phase composition and microstructure for the composite refractory are investigated as well as the interaction between the composite crucible and TiAl alloy melt. Results reveal that the composite crucible is consisted of Y doped BaZrO3 and Y2O3(ZrO2) phases, and the introduce of Y2O3 is help to the improvement of fused BaZrO3 refractory. Dissolution-erosion is the main responsible for the interaction between the refractory and TiAl alloy melt, however, the Al2O3 in the melt reacts with the BaO leading to the generation of reactant BaAl2O4, which attaches to the inner wall of the crucible. The oxygen concentration for the prepared TiAl alloy ingot is about 0.0986wt.%, which is consistent with the calculated value for the TiAl alloy. It is also met criteria for the industrial TiAl alloy ingot, which indicates that the BaZrO3/Y2O3 composite refractory is the candidate for induction melting of TiAl alloys.

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張胤,陳光耀,肖玉彬,馮齊勝,劉曉梅,魯雄剛,李重河. BaZrO3/Y2O3復(fù)合耐火材料制備及其與TiAl合金界面反應(yīng)研究[J].稀有金屬材料與工程,2021,50(3):988~994.[ZHANG Yin, CHEN Guangyao, XIAO Yubin, FENG Qisheng, LIU Xiaomei, LU Xionggang, LI Chonghe. Preparation Of BaZrO3/Y2O3 Composite Refractory And Its InteractionWith TiAl Alloy[J]. Rare Metal Materials and Engineering,2021,50(3):988~994.]
DOI:10.12442/j. issn.1002-185X.20200252

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  • 收稿日期:2020-04-16
  • 最后修改日期:2020-07-02
  • 錄用日期:2020-07-20
  • 在線發(fā)布日期: 2021-04-02
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