30) 、斷裂韌性(KIC)和抗彎強(qiáng)度(TRS)降低;1470℃燒結(jié)溫度下,(Ti,W,Mo,Nb)(C,N)-(Co,Ni)基金屬陶瓷合金的硬度(HV30) 、斷裂韌性(KIC)和抗彎強(qiáng)度(TRS)的匹配最佳,表現(xiàn)為在實(shí)際應(yīng)用工況下的綜合切削性能最優(yōu)。"/>

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燒結(jié)溫度對(Ti, W, Mo, Nb)(C, N)-(Co, Ni)金屬陶瓷組織結(jié)構(gòu)和性能的影響
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1.福州大學(xué)材料科學(xué)與工程學(xué)院;2.魯汶大學(xué)材料工程系;3.福建工程學(xué)院材料科學(xué)與工程學(xué)院

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University-Industry cooperation project of Fujian Province(2019H6022)


Effect of sintering temperature on the microstructure and machining performance of (Ti, W, Mo, Nb)(C, N)-(Co, Ni) cermets
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College of Materials Science and Engineering, Fuzhou University

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    摘要:

    本文以(Ti,W,Mo,Nb)(C,N)-(Co,Ni)基金屬陶瓷材料為研究對象,研究燒結(jié)溫度對金屬陶瓷的成分、微觀組織和力學(xué)性能的影響,初步探討成分、微觀組織與材料強(qiáng)度的關(guān)系。研究結(jié)果表明:燒結(jié)溫度對(Ti,W,Mo,Nb)(C,N)-(Co,Ni)基金屬陶瓷組織特征有顯著的影響;合金的總碳(Ct%)隨著燒結(jié)溫度的提高而降低,當(dāng)燒結(jié)溫度達(dá)到1490℃時(shí),合金總碳的急劇降低,導(dǎo)致合金組織中出現(xiàn)脫碳相(η相),從而使得合金的硬度(HV30) 、斷裂韌性(KIC)和抗彎強(qiáng)度(TRS)降低;1470℃燒結(jié)溫度下,(Ti,W,Mo,Nb)(C,N)-(Co,Ni)基金屬陶瓷合金的硬度(HV30) 、斷裂韌性(KIC)和抗彎強(qiáng)度(TRS)的匹配最佳,表現(xiàn)為在實(shí)際應(yīng)用工況下的綜合切削性能最優(yōu)。

    Abstract:

    In this study, dense Co- and Ni-bonded Ti(C0.6N0.4) matrix cermets with secondary carbides, i.e., WC, Mo2C, and NbC, were prepared using liquid phase sintering in vacuum for 60 min at temperatures ranging from 1410 to 1490°C. The detailed microstructural and phase analysis was performed using scanning electron microscopy, electron probe microanalysis, and X-ray diffraction analysis. The effect of sintering temperature on the microstructure, mechanical properties, and machining performance of cermets was investigated. The results showed that sintering temperature had a significant impact on the microstructural characteristics of (Ti, W, Mo, Nb)(C, N)-(Co, Ni) cermets. The total carbon content of cermets decreased with increase in temperature and a carbon-deficient phase (M6C) was observed in the cermet sintered at 1490°C. The cermets sintered at temperatures of up to 1470°C were composed of an fcc solid solution metal binder and two types of core-rim structured grains, i.e., cubic carbide solution and cubic Ti(C, N) solution phases. The best machining performance on continuous / interrupted turning was found in the cermet sintered at 1470°C because of an optimum combination of hardness and transverse rupture strength.

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項(xiàng)忠楠,李戰(zhàn)江,黃水根,常發(fā),戴品強(qiáng).燒結(jié)溫度對(Ti, W, Mo, Nb)(C, N)-(Co, Ni)金屬陶瓷組織結(jié)構(gòu)和性能的影響[J].稀有金屬材料與工程,2021,50(4):1179~1186.[xiang zhong nan, Li Zhan jiang, Huang Shui gen, Chang Fa, Dai Pin qiang. Effect of sintering temperature on the microstructure and machining performance of (Ti, W, Mo, Nb)(C, N)-(Co, Ni) cermets[J]. Rare Metal Materials and Engineering,2021,50(4):1179~1186.]
DOI:10.12442/j. issn.1002-185X.20200228

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  • 收稿日期:2020-04-06
  • 最后修改日期:2020-04-27
  • 錄用日期:2020-05-08
  • 在線發(fā)布日期: 2021-05-08
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