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LaNi3.70Al0.75Mn0.55合金吸氚特性
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中國原子能科學研究院

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高性能長壽命中子管研制與應用


Characteristics of tritium absorption behaviors of LaNi3.70Al0.75Mn0.55
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    摘要:

    通過研究LaNi3.70Al0.75Mn0.55合金材料在室溫下定容吸氚壓力隨時間的變化規(guī)律,分析LaNi3.70Al0.75Mn0.55合金吸氚的反應機制的影響規(guī)律。試驗結果表明,氚壓力在材料吸氚初始階段下降迅速,在15s內吸氚T/M比可達到1.5 std.cc/g,吸氚速率最快能達到0.28 std.cc·g-1·s-1,最大吸氫速率發(fā)生在α+β相區(qū)。氚在合金表面的解離和化學吸附為吸氚初期的控速步驟,當T/M>15 std.cc/g后,反應產(chǎn)生β相變,形成氚化物,吸氚過程為形核長大控速步驟。

    Abstract:

    The pressure of tritium gas vs. time curves of LaNi3.70Al0.75Mn0.55 alloy absorbing tritium in the constant volume condition at room temperature were studied. Mechanism of tritium absorption and their effect on the tritium absorption rate were analyzed. The results indicated that the pressure decreases rapidly in the initial stage of absorbing tritium, and the T/M can reach to 1.5 std.cc/g in 15 s, the highest tritium absorption rate reaches to 0.28 std.cc·g-1·s-1 maxed out at the α+β phase. The dissociation and chemical adsorption of tritium on the surface of the alloy are the speed control steps at the initial stage of tritium absorption. When the T/M > 15 std.cc/g, the reaction results in phase transition to form tritium compounds, the control steps of tritium absorption is nuclear growth.

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王瑋,丁衛(wèi)東,楊洪廣. LaNi3.70Al0.75Mn0.55合金吸氚特性[J].稀有金屬材料與工程,2021,50(2):687~692.[Wang Wei, Ding Wei-dong, Yang Hong-guang. Characteristics of tritium absorption behaviors of LaNi3.70Al0.75Mn0.55[J]. Rare Metal Materials and Engineering,2021,50(2):687~692.]
DOI:10.12442/j. issn.1002-185X.20200187

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  • 收稿日期:2020-03-20
  • 最后修改日期:2020-07-30
  • 錄用日期:2020-08-04
  • 在線發(fā)布日期: 2021-03-09
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