19的析出傾向,Ti和Ni能分別抑制有害相χ-D019和B2相的析出,將合金成分定為Co-9Al-3W-30Ni-2Ta-3.5Ti(at%)。計(jì)算了此合金的相轉(zhuǎn)變規(guī)律,結(jié)果表明:合金的平衡析出相為γ、γˊ、χ-D019和Co7Ta2,開始析出溫度分別為1355℃,1169℃,700℃和288℃。制定了合金的熱處理制度:1250℃/12h均勻化,1150℃/6h固溶處理,900℃/4h+750℃/16h兩步時效處理。采用真空感應(yīng)熔煉制備了合金樣品,經(jīng)上述熱處理后,DSC分析結(jié)果與計(jì)算的相轉(zhuǎn)變規(guī)律一致,SEM及XRD結(jié)果表明,合金中的平衡相為典型的γ+γˊ兩相組織。"/>

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相圖計(jì)算輔助新型Co基變形高溫合金的成分設(shè)計(jì)
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1.有研科技集團(tuán)有限公司生物冶金國家工程實(shí)驗(yàn)室 北京 有研資源環(huán)境技術(shù)研究院北京有限公司;2.中國航發(fā)北京航空材料研究院先進(jìn)高溫結(jié)構(gòu)材料重點(diǎn)實(shí)驗(yàn)室;3.福州大學(xué)材料科學(xué)與工程學(xué)院

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TG146.1+6 TG132.3+2

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Composition Optimization Design for Novel Co-based Deformed Superalloy Aided by Phase Diagram Calculation Approach
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1.National Engineering Laboratory of Biohydrometallury,GRINM Engineering Institute Co,Ltd;2.Science and Technology on Advanced High Temperature Structural Materials Laboratory;3.College of materials science and engineering, Fuzhou university

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    摘要:

    為了確定Co-Al-W-Ni-Ta-Ti體系新型γ′強(qiáng)化的Co-Al-W基變形高溫合金的成分及相應(yīng)的熱處理工藝,利用Pandat計(jì)算軟件及鈷基高溫合金熱力學(xué)數(shù)據(jù)庫,計(jì)算了合金元素對平衡相析出行為的影響,計(jì)算表明:W、Ni、Ta及Ti均能提高γˊ的穩(wěn)定性,W、Ta會增加有害相χ-D019的析出傾向,Ti和Ni能分別抑制有害相χ-D019和B2相的析出,將合金成分定為Co-9Al-3W-30Ni-2Ta-3.5Ti(at%)。計(jì)算了此合金的相轉(zhuǎn)變規(guī)律,結(jié)果表明:合金的平衡析出相為γ、γˊ、χ-D019和Co7Ta2,開始析出溫度分別為1355℃,1169℃,700℃和288℃。制定了合金的熱處理制度:1250℃/12h均勻化,1150℃/6h固溶處理,900℃/4h+750℃/16h兩步時效處理。采用真空感應(yīng)熔煉制備了合金樣品,經(jīng)上述熱處理后,DSC分析結(jié)果與計(jì)算的相轉(zhuǎn)變規(guī)律一致,SEM及XRD結(jié)果表明,合金中的平衡相為典型的γ+γˊ兩相組織。

    Abstract:

    In order to determine the composition of the novel γ′ strengthened Co-Al-W-based wrought superalloy of the Co-Al-W-Ni-Ta-Ti system and the corresponding heat treatment process, using Pandat calculation software and the thermodynamic database of cobalt-based superalloys, The influence of alloying elements on the precipitation behavior of the equilibrium phase was calculated. The calculations showed that: W, Ni, Ta, and Ti can improve the stability of γˊ, W, Ta can increase the precipitation tendency of the harmful phase χ-D019, and Ti and Ni can be suppressed the precipitation of the harmful phases χ-D019 and B2 phase respectively, the alloy composition was determined as Co-9Al-3W-30Ni-2Ta-3.5Ti (at%). The phase transition law of this alloy was calculated, and the results showed that the equilibrium precipitation phases of the alloy were γ, γˊ, χ-D019 and Co7Ta2, and the initial precipitation temperatures were 1355 °C, 1169 ° C, 700 ° C, and 288 ° C, respectively. The alloy heat treatment process was formulated: 1250℃/12h homogenization, 1150℃/6h solution treatment, 900℃/4h + 750℃/16h two-step aging treatment. The alloy samples were prepared by vacuum induction melting. After the above heat treatment, the DSC analysis results are consistent with the calculated phase transition rules. SEM and XRD results show that the equilibrium phase of the alloy is typical γ + γˊ two-phase structure.

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吳剛,王濤,沈劍韻,魏杰,吳波,黃永章,袁學(xué)韜.相圖計(jì)算輔助新型Co基變形高溫合金的成分設(shè)計(jì)[J].稀有金屬材料與工程,2021,50(1):235~241.[Wu Gang, Wang Tao, Shen Jianyun, Wei Jie, Wu Bo, Huang Yongzhang, Yuan Xuetao. Composition Optimization Design for Novel Co-based Deformed Superalloy Aided by Phase Diagram Calculation Approach[J]. Rare Metal Materials and Engineering,2021,50(1):235~241.]
DOI:10.12442/j. issn.1002-185X.20200087

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  • 收稿日期:2020-02-14
  • 最后修改日期:2020-03-06
  • 錄用日期:2020-03-19
  • 在線發(fā)布日期: 2021-02-05
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