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定向凝固多孔鎂鋅合金的制備及氣孔結(jié)構(gòu)研究
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作者單位:

1.昆明理工大學(xué)材料學(xué)院;2.清華大學(xué)材料學(xué)院

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國(guó)家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


Fabrication and pore structure of directionally solidified porous Mg-Zn alloy
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1.Faculty of Materials Science and Engineering,Kunming University of Science and Technology;2.School of Materials Science and Engineering, Tsinghua University

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    摘要:

    采用Bridgman型定向凝固法成功制備出藕狀多孔Mg-Zn合金。研究了不同鋅含量和氫氣壓力對(duì)氣孔形貌的影響。通過(guò)理論計(jì)算對(duì)Mg-1Zn的孔隙率進(jìn)行了預(yù)測(cè)。結(jié)果表明,鋅元素的加入會(huì)對(duì)孔結(jié)構(gòu)產(chǎn)生重大影響。隨著Zn含量從0增加到2%,平均孔徑增加。隨著氫氣壓力從0.1MPa增加到0.6MPa,Mg-1Zn合金的孔隙率明顯降低?;跉錃庠诙嘟M分熔融金屬中溶解度的計(jì)算模型, Mg-1Zn合金鑄錠凝固高度為20mm的孔隙率的計(jì)算結(jié)果與模型的結(jié)果比較吻合。通過(guò)觀察組織,隨著Zn含量的增加,凝固組織由柱狀晶轉(zhuǎn)變?yōu)榈容S晶。此外,研究了在不同凝固階段的孔形成過(guò)程,可為定向凝固多孔Mg-Zn合金在生物醫(yī)用材料中的應(yīng)用提供理論依據(jù)。

    Abstract:

    Lotus-type porous Mg-Zn alloys were fabricated successfully by Bridgman-type directional solidification method. The pore structure and porosity of Mg alloys at different Zn content and hydrogen pressure were studied. The porosity of Mg-1wt.% Zn was predicted through the theoretical calculation. The results show that pore structure can be influenced by the addition of Zn element. As the content of Zn increases from 0 to 2 wt.%, average pore diameter increases. The porosity of Mg-1wt.%Zn alloy clearly decreases with the increasing of the hydrogen pressure from 0.1MPa to 0.6MPa. Based on a model for estimating the solubility of hydrogen in multi-component molten metals, the calculated results of porosity at the solidification stage (20mm height) with a changed hydrogen pressure in Mg-1wt.%Zn alloy, are in good agreement with the experimental results. Through observations on the microstructures, the column grains of Mg-Zn alloy are changed into equiaxed grains as the content of Zn increases. Also, the formation of pore at different solidification stages was studied, which can supply theoretical basis for the fabrication of Gasar Mg-Zn alloy in the biological applications.

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肖心雄,劉源,金青林,周燦旭,張華偉,李言祥,李再久.定向凝固多孔鎂鋅合金的制備及氣孔結(jié)構(gòu)研究[J].稀有金屬材料與工程,2021,50(2):497~503.[xiao xinxiong, liu yuan, jin qinglin, zhou canxu, zhang huawei, li yanxiang, li zaijiu. Fabrication and pore structure of directionally solidified porous Mg-Zn alloy[J]. Rare Metal Materials and Engineering,2021,50(2):497~503.]
DOI:10.12442/j. issn.1002-185X.20200069

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  • 收稿日期:2020-02-07
  • 最后修改日期:2020-03-04
  • 錄用日期:2020-03-05
  • 在線發(fā)布日期: 2021-03-09
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