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SiC纖維增強高溫合金復合材料可行性分析
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北京科技大學 材料科學與工程學院

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高溫結構材料重點實驗室開放基金


THE FEASIBILITY ANALYSIS OF SIC FIBER REINFORCED SUPERALLOY-BASED COMPOSITE
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1.School of materials science and engineering,University of Science and Technology Beijing,Beijing,100083;2.China

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    摘要:

    SiC纖維增強金屬基復合材料因耐高溫、低密度等特點,在航空航天領域逐漸推廣。為進一步提高SiC纖維增強金屬基復合材料的使用溫度,國內外開始嘗試將SiC纖維與高溫合金進行復合,以期發(fā)揮兩者的優(yōu)點,獲得性能更加優(yōu)良的高溫結構材料。但SiC纖維增強高溫合金復合材料發(fā)展緩慢,諸多嘗試均未取得突破性的成功,界面問題是制約該類材料發(fā)展的“瓶頸”。雖然在克服界面反應方面也采取了諸多嘗試,但該問題并未獲得實質性的解決,因此有必要從根源入手對SiC纖維增強高溫合金復合材料這一研究方向的可行性進行探討。本文采用資料研究和實驗研究相結合的方式,從SiC纖維增強高溫合金復合材料的發(fā)展歷史、界面反應問題的解決方案、SiC與高溫合金界面反應的本質等幾個方面逐層展開、一一論述,對SiC纖維增強高溫合金復合材料的可行性進行闡述和分析。

    Abstract:

    SiC fiber reinforced metal-base composite is more and more widely used in aerospace field for the higher temperature capability, lower density. SiC fiber reinforced Ti, Al, Mg based composites have proved to be great success. But the usage temperature of these composites has been limited by the usage temperature of base metal. In order to further increase the temperature capability of SiC fiber reinforced metal-base composite and obtain high-temperature structural material with better properties, there are some attempts of SiC fiber reinforced superalloy-base composite at home and aboard. However, the development of SiC fiber reinforced superalloy-base composite is in slow development and there has not been breakthrough success. The bottleneck for the development of SiC fiber reinforced superalloy-base composite is the interface reaction between SiC fiber and superalloy base. Many attempts (such as a variety of interface coatings) have been made to conquer this challenge, however, no mature solution has been found. Hence, it is necessary to systematically analyze the feasibility of SiC fiber reinforced superalloy-based composite. In this paper, the origin and development of SiC fiber reinforced superalloy-based composites in past decades were narrated. The failure cases and reasons were summarized. Moreover, the attempts of interface coating and disadvantages of this method were analyzed. Experiments and simulations were carried out to investigate the interface reaction between SiC fiber and major superalloy elements. The results show that the reaction between SiC fiber and major superalloy elements is severe and cannot be avoided. Further analysis on the essence of severe reaction between SiC fiber and superalloy was made. The experiment and analysis show that SiC fiber and superalloy are intrinsically incompatible, and the interface reaction trend is severe. Interface coating can hinder the reaction in some extent. But the reaction trend is so severe that any minor failure of coating will result in catastrophic result. The above reasons indicate that it is difficult for SiC fiber reinforced superalloy-base composite to be used commercially in the near future.

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江河,王法,李昕,董建新. SiC纖維增強高溫合金復合材料可行性分析[J].稀有金屬材料與工程,2021,50(1):349~360.[JIANG He, WANG Fa, LI Xin, DONG Jianxin. THE FEASIBILITY ANALYSIS OF SIC FIBER REINFORCED SUPERALLOY-BASED COMPOSITE[J]. Rare Metal Materials and Engineering,2021,50(1):349~360.]
DOI:10.12442/j. issn.1002-185X.20191101

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  • 收稿日期:2019-12-28
  • 最后修改日期:2020-01-16
  • 錄用日期:2020-02-21
  • 在線發(fā)布日期: 2021-02-05
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