2+γ)片層團為主體,網絡狀B2相、細小的γ相及硼化物分布于片層團間的近片層組織。熱穩(wěn)定處理時,熱穩(wěn)定時間越長、TNM合金固/液界面越平整,界面前沿溫度場和溶質場趨向均勻,但從減少坩堝對熔體的污染的角度考慮,熱穩(wěn)定處理時間不宜過長,30~60 min的熱穩(wěn)定時間即可提供平整的定向凝固啟動界面。 熱穩(wěn)定處理影響著TNM合金固/液界面附近固液兩相中Al元素的分布,進而影響硼化物的分布。"/>

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熱穩(wěn)定處理時間對TNM合金糊狀區(qū)組織的影響
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1.哈爾濱工業(yè)大學金屬精密熱加工國家級重點實驗室;2.黑龍江工程學院材料與化學工程學院

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基金項目:

國家重點研發(fā)計劃項目(2016YFB0301201);國家自然科學(51671073);云南省重大科技專項計劃(2018ZE002);云南稀貴金屬材料基因工程一期項目(2018ZE013)


Effect of Thermal Stabilization Time on Microstructure of Mushy Zone of TNM Alloy
Author:
Affiliation:

1.National Key Laboratory for Precision Hot Processing of Metals,Harbin Institute of Technology;2.Department of Material and Chemical Engineering,Heilongjiang Institute of Technology

Fund Project:

National Key Research and Development Program of China; National Natural Science Foundation of China; Major Special Science and Technology Project of Yunnan Province; Yunnan Rare Metal Materials Genetic Engineering Project

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    摘要:

    利用真空非自耗電弧爐制備了TNM(Ti-44Al-4Nb-1Mo-0.1B at.%)合金錠,研究其鑄態(tài)組織形貌,并利用Bridgeman定向凝固裝置對TNM合金進行熱穩(wěn)定處理實驗,分析熱穩(wěn)定處理時間對合金定向凝固糊狀區(qū)的影響。實驗結果顯示,其鑄態(tài)組織是以(α2+γ)片層團為主體,網絡狀B2相、細小的γ相及硼化物分布于片層團間的近片層組織。熱穩(wěn)定處理時,熱穩(wěn)定時間越長、TNM合金固/液界面越平整,界面前沿溫度場和溶質場趨向均勻,但從減少坩堝對熔體的污染的角度考慮,熱穩(wěn)定處理時間不宜過長,30~60 min的熱穩(wěn)定時間即可提供平整的定向凝固啟動界面。 熱穩(wěn)定處理影響著TNM合金固/液界面附近固液兩相中Al元素的分布,進而影響硼化物的分布。

    Abstract:

    In this paper, the ingots of TNM alloy(Ti-44Al-4Nb-1Mo-0.1B at.%) were obtained using a non-consumable electric arc melting furnace. As-cast microstructure of TNM alloy was investigated. Liquid metal cooling Bridgman-type apparatus was employed in the heat stabilization experiment of TNM alloy and the effect of thermal stabilization time on the mushy zone of TNM alloy during directional solidification has been investigated. The results show the as-cast microstructure of TNM alloy consists of a major of (α2+γ) lamellar colonies, network-like B2 phase, small γ phase and boride located at the interface of colonies. With the thermal stabilization time increasing, the solid/liquid interface will come to a planar one and the field of temperature and solute in the melt in front of solid/liquid interface will become more homogenous in thermal stabilization test. However, overmuch thermal stabilization time will make the melt contaminated by the crucible. The study shows the thermal stabilization time of 30~60 min is sufficient to provide a planar starting interface for directional solidification. Thermal stabilization affects the distribution of Al in solid and liquid phases near the solid/liquid interface of TNM alloy, and further affects the distribution of borides.

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李志平,駱良順,孫雄凱,楊慧敏,劉桐,王亮,張東徽,蘇彥慶,郭景杰,傅恒志.熱穩(wěn)定處理時間對TNM合金糊狀區(qū)組織的影響[J].稀有金屬材料與工程,2020,49(11):3938~3942.[Li Zhiping, Luo Liangshun, Sun Xiongkai, Yang Huimin, Liu Tong, Wang Liang, Zhang Donghui, Su Yanqing, Guo Jingjie, Fu Hengzhi. Effect of Thermal Stabilization Time on Microstructure of Mushy Zone of TNM Alloy[J]. Rare Metal Materials and Engineering,2020,49(11):3938~3942.]
DOI:10.12442/j. issn.1002-185X.20191007

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  • 收稿日期:2019-11-29
  • 最后修改日期:2020-03-13
  • 錄用日期:2020-03-19
  • 在線發(fā)布日期: 2020-12-09
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