#鋼表面制備WC添加的Ni60/WC復合定向結(jié)構(gòu)涂層,采用SEM、EDS、XRD、電化學性能測試和浸泡實驗等檢測手段分析研究了WC顆粒增強Ni60合金的定向結(jié)構(gòu)復合涂層的耐腐蝕性能及其機制。結(jié)果表明:隨著WC添加量的增加,極化電阻先增大后減小,WC添加量10%時達到最大值9710.8 Ω;腐蝕電流密度先減小后增大,WC添加量10%時最小為1.34×10-6 A/cm2。WC添加量對涂層顯微形貌、元素分布、物相均有影響,進而影響涂層耐蝕性能。"/>

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WC對定向結(jié)構(gòu)Ni60涂層耐蝕性能的影響研究
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蘭州理工大學 材料科學與工程學院

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國家自然科學基金資助(項目號51365024);浙江省自然科學基金資助(項目號LGG19E010003);


Effect of WC on corrosion resistance of directional structure Ni60 coating
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    摘要:

    為了研究WC含量對Ni60合金涂層耐腐蝕性能的影響規(guī)律及相關(guān)機制,向Ni60合金粉體中添加不同質(zhì)量分數(shù)的WC,通過高頻感應(yīng)重熔和強制冷卻技術(shù),在45#鋼表面制備WC添加的Ni60/WC復合定向結(jié)構(gòu)涂層,采用SEM、EDS、XRD、電化學性能測試和浸泡實驗等檢測手段分析研究了WC顆粒增強Ni60合金的定向結(jié)構(gòu)復合涂層的耐腐蝕性能及其機制。結(jié)果表明:隨著WC添加量的增加,極化電阻先增大后減小,WC添加量10%時達到最大值9710.8 Ω;腐蝕電流密度先減小后增大,WC添加量10%時最小為1.34×10-6 A/cm2。WC添加量對涂層顯微形貌、元素分布、物相均有影響,進而影響涂層耐蝕性能。

    Abstract:

    In order to study the influence of WC content on the corrosion resistance of Ni60 alloy coating and the related mechanism, WC with the different mass fraction was added to Ni60 self-fused alloy powder, Ni60/WC directional structure composite coatings with different WC contents were prepared on 45 steel by induction remelting and forced cooling technology. The corrosion resistance and mechanism of WC particles reinforced Ni60 alloy directional structure composite coatings were investigated by SEM, EDS, XRD, electrochemical test and immersion corrosion. Results showed that the polarization resistance of composite coatings increased first and then decreased with the increase of WC, and the maximum polarization resistance reached 9710.8 Ω when the WC addition amount was 10%. The corrosion current density of composite coatings decreased first and then increased, and the minimum current density reached 1.34×10-6 A/cm2 with 10% WC content. The WC content had the important effect on microstructures, element distribution, phases of composite coatings, and further affected the corrosion resistance.

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楊效田,李秀倩,魏亨利,李文生. WC對定向結(jié)構(gòu)Ni60涂層耐蝕性能的影響研究[J].稀有金屬材料與工程,2020,49(10):3604~3611.[yangxiaotian, Li Xiuqian, Wei Hengli, Li Wensheng. Effect of WC on corrosion resistance of directional structure Ni60 coating[J]. Rare Metal Materials and Engineering,2020,49(10):3604~3611.]
DOI:10.12442/j. issn.1002-185X.20190944

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  • 收稿日期:2019-11-11
  • 最后修改日期:2020-01-19
  • 錄用日期:2020-01-19
  • 在線發(fā)布日期: 2020-11-04
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