15 m-2)及顯微硬度變化率(33.3%)、鑄態(tài)斷口無解理臺(tái)階,表現(xiàn)了出最低的加工硬化率,且鑄態(tài)軸向抗拉強(qiáng)度高達(dá)384.6 MPa,可實(shí)現(xiàn)100 m以上、直徑0.05 mm超細(xì)絲高效不斷絲加工;加工態(tài)及退火態(tài)的柱狀晶Ag-28Cu-0.75Ni合金超細(xì)絲均表現(xiàn)出了較高的電阻率,經(jīng)兩次連續(xù)退火后電阻率高達(dá)3.68 μΩ.cm,與其較低的位錯(cuò)密度及加工硬化率有關(guān)。"/>

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晶粒形態(tài)、尺寸對(duì)Ag-28Cu-0.75Ni合金超細(xì)絲加工及電學(xué)性能的影響
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1.昆明理工大學(xué);2.稀貴金屬綜合利用新技術(shù)國(guó)家重點(diǎn)實(shí)驗(yàn)室

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稀貴金屬綜合利用新技術(shù)國(guó)家重點(diǎn)實(shí)驗(yàn)室開放課題(SKL-SPM-2018014);國(guó)家自然科學(xué)(51861020)


Effects of Grain Morphology and Size on Processing and Electrical Properties of Ag-28Cu-0.75Ni Alloy Ultra-fine Wire
Author:
Affiliation:

1.Kunming University of Science and Technology;2.State Key Laboratory of Advance Technologies for Comprehensive Utilization of Platinum Metals,Kunming

Fund Project:

Open subject of State Key Laboratory of Advance Technologies for Comprehensive Utilization of Platinum Metals(SKL-SPM-2018014);National Natural Science(51861020)

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    摘要:

    為詮釋柱狀晶貴金屬兼具優(yōu)良超細(xì)絲加工性能及高電阻率的原因,采用水平連鑄、水冷銅模鑄造及石墨模鑄造,分別獲得了具有20 μm×60 μm的柱狀晶、10 μm的等軸晶、以及5 μm的表面細(xì)晶+長(zhǎng)徑比約為3的柱狀晶+30 μm的芯部等軸晶三晶區(qū)的三種Ag-28Cu-0.75Ni合金棒材,研究了晶粒形態(tài)、尺寸對(duì)Ag-28Cu-0.75Ni合金棒材超細(xì)絲加工性能及電阻率的影響。結(jié)果表明:與等軸晶和三晶區(qū)Ag-28Cu-0.75Ni合金棒材相比,柱狀晶棒材由于其較低的位錯(cuò)密度(1.78×1015 m-2)及顯微硬度變化率(33.3%)、鑄態(tài)斷口無解理臺(tái)階,表現(xiàn)了出最低的加工硬化率,且鑄態(tài)軸向抗拉強(qiáng)度高達(dá)384.6 MPa,可實(shí)現(xiàn)100 m以上、直徑0.05 mm超細(xì)絲高效不斷絲加工;加工態(tài)及退火態(tài)的柱狀晶Ag-28Cu-0.75Ni合金超細(xì)絲均表現(xiàn)出了較高的電阻率,經(jīng)兩次連續(xù)退火后電阻率高達(dá)3.68 μΩ.cm,與其較低的位錯(cuò)密度及加工硬化率有關(guān)。

    Abstract:

    In order to explain the reason why the columnar crystal precious metal has excellent ultra-fine wire processing property and high resistance, three kinds of Ag-28Cu-0.75Ni alloy bars, columnar crystal of 20 μm×60 μm, equiaxed crystal of 10 μm, and tri-crystal zone with surface fine crystal of 5 μm + columnar crystal with length diameter ratio of around 3 + core equiaxed crystal of 30 μm, were obtained by horizontal continuous casting, water-cooled copper die casting, and graphite die casting, respectively. The effects of grain morphology and size on the ultra-fine wire processability and resistivity of Ag-28Cu-0.75Ni alloy bars were studied. The results show that, compared with the equiaxed crystal bar and the tri-crystal zone bar, the columnar crystal bar has the lower dislocation density (1.78×1015 m-2), the lowest ratio of micro-hardness change (33.3%), and no cleavage step after the tensile test, thus, it presents the lowest work hardening rate. Besides, the axial tensile strength of as-cast columnar crystal bar is up to 384.6 MPa. Therefore, the ultra-fine wire with the diameter of 0.05 mm and the length of 100 meters or more can be obtained by the high-efficiency continuous wire drawing of the columnar crystal bar. The resistivity of processed and annealed Ag-28Cu-0.75Ni alloy ultra-fine wires that drawn from the columnar crystal bar are higher, after two times continuous annealing, the resistivity of columnar crystal Ag-28Cu-0.75Ni alloy ultra-fine wire is up to 3.68 μΩ.cm, which is related to the lower dislocation density and work hardening rate.

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牛海東,武海軍,陳家林,左孝青,周蕓.晶粒形態(tài)、尺寸對(duì)Ag-28Cu-0.75Ni合金超細(xì)絲加工及電學(xué)性能的影響[J].稀有金屬材料與工程,2020,49(10):3590~3596.[Niu Haidong, Wu Haijun, Chen Jialin, Zuo Xiaoqing, Zhou Yun. Effects of Grain Morphology and Size on Processing and Electrical Properties of Ag-28Cu-0.75Ni Alloy Ultra-fine Wire[J]. Rare Metal Materials and Engineering,2020,49(10):3590~3596.]
DOI:10.12442/j. issn.1002-185X.20190941

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  • 收稿日期:2019-11-10
  • 最后修改日期:2020-02-17
  • 錄用日期:2020-02-20
  • 在線發(fā)布日期: 2020-11-04
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